Chloromethylmethyl sulfide
- Formula: C2H5ClS
- Molecular weight: 96.579
- IUPAC Standard InChI: InChI=1S/C2H5ClS/c1-4-2-3/h2H2,1H3
- IUPAC Standard InChIKey: JWMLCCRPDOIBAV-UHFFFAOYSA-N
- CAS Registry Number: 2373-51-5
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: CH3SCH2Cl; Methane, chloro(methylthio)-; α-Chlorodimethyl sulfide; Chlorodimethyl thioether; Chloromethyl methyl thioether; Methylthiomethyl chloride; Monochlorodimethyl sulfide; Sulfide, chloromethyl methyl; Chlorodimethyl sulfide; Clorodimetilsolfuro; Chloro(methylthio)methane; NSC 63205; chloromethyl methyl sulphide
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Vibrational and/or electronic energy levels
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
| Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
|---|---|---|---|---|---|---|---|
| Tx = 35500 | Ar | Maier, Flogel, et al., 1991 | |||||
State: X
| Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
|---|---|---|---|---|---|---|---|
| 3026.8 | w | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 1423.3 | m | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 1415.5 | m | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 1386.1 | s | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 1039.0 | s | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 993.7 | m | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 965.2 | m | Ar | IR | Maier, Flogel, et al., 1991 | |||
| 747.8 | vs | Ar | IR | Maier, Flogel, et al., 1991 | |||
Additional references: Jacox, 1994, page 418
Notes
| w | Weak |
| m | Medium |
| s | Strong |
| vs | Very strong |
| x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
Gas Chromatography
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | OV-101 | 713. | Zenkevich, 2005 | 25. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C |
References
Go To: Top, Vibrational and/or electronic energy levels, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Maier, Flogel, et al., 1991
Maier, G.; Flogel, U.; Reisenauer, H.P.; Hess, B.A., Jr.; Schaad, L.J.,
Photoisomerisierung von Halogendimethylsulfiden,
Chem. Ber., 1991, 124, 11, 2603, https://doi.org/10.1002/cber.19911241133
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Zenkevich, 2005
Zenkevich, I.G.,
Experimentally measured retention indices., 2005. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, Gas Chromatography, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.