Molybdenum tetrafluoride
- Formula: F4Mo
- Molecular weight: 171.95
- CAS Registry Number: 23412-45-5
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
View reactions leading to F4Mo+ (ion structure unspecified)
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| <2.28095 | TDEq | Borshchevskii, Boltalina, et al., 1988 | B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.7 ± 0.2 | EI | Alikhanyan, Steblevskii, et al., 1978 | LLK |
| 10.11 ± 0.10 | EI | Hildenbrand, 1976 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| F2Mo+ | 19.0 ± 1.0 | ? | EI | Alikhanyan, Steblevskii, et al., 1978 | LLK |
| F3Mo+ | 14.0 ± 0.5 | F | EI | Alikhanyan, Steblevskii, et al., 1978 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Borshchevskii, Boltalina, et al., 1988
Borshchevskii, A.Ya.; Boltalina, O.V.; Sorokin, I.D.; Sidorov, L.N.,
Thermochemical Quantities for Gas Phase Iron, Uranium, and Molybdenum Fluorides, and Their Negative Ions.,
J. Chem. Thermodyn., 1988, 20, 5, 523, https://doi.org/10.1016/0021-9614(88)90080-8
. [all data]
Alikhanyan, Steblevskii, et al., 1978
Alikhanyan, A.S.; Steblevskii, A.V.; Malkerova, I.P.; Pervov, V.S.; Butskii, V.D.; Gorgoraki, V.I.,
Mass spectrometric study of the sublimation of molybdenum trifluoride,
Russ. J. Inorg. Chem., 1978, 23, 814. [all data]
Hildenbrand, 1976
Hildenbrand, D.L.,
Thermochemical studies of the gaseous lower valent fluorides of molybdenum,
J. Chem. Phys., 1976, 65, 614. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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