2,8,9-Trioxa-5-aza-1-silabicyclo[3.3.3]undecane, 1-methyl-

• Formula: C₇H₁₅NO₃Si
• Molecular weight: 189.2844
• IUPAC Standard InChI: InChI=1S/C7H15NO3Si/c1-12-9-5-2-8(3-6-10-12)4-7-11-12/h2-7H2,1H3 Copy

  
• IUPAC Standard InChIKey: DZLQWMNVOBAZGC-UHFFFAOYSA-N Copy
• CAS Registry Number: 2288-13-3
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: 1-Methylsilatrane; Methylsilatrane; Methylsilatran; 1-Methyl-2,8,9-trioxa-5-aza-1-silabicyclo(3.3.3)undecane
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• Information on this page:
  • Gas phase ion energetics data
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Mass spectrum (electron ionization)
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Kovats' RI, polar column, isothermal

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References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brodskaya, Voronkov, et al., 1987
Brodskaya, E.I.; Voronkov, M.G.; Toryashinova, D.D.; Baryshok, V.P.; Ratovski, G.V.; Chuvashev, D.D.; Efremov, V.G., Intramolecular interactions in compounds bearing Si-O-C-C-N or C-O-C-C-N fragments, J. Organomet. Chem., 1987, 336, 49. [all data]

Peel and Dianxum, 1988
Peel, J.B.; Dianxum, W., Photoelectron spectroscopic studies of the electronic structures of some silatranes, J. Chem. Soc. Dalton Trans., 1988, 1963. [all data]

Cradock, Ebsworth, et al., 1975
Cradock, S.; Ebsworth, E.A.V.; Muiry, I.B., Photoelectron spectra and bonding of (N-B) -2,8,9-trioxa-5-aza-1-bora-bicyclo[3.3.3]undecane (boratran) and some 2,8,9-trioxa-5-aza-1-sila- bicyclo[3.3.3]undecanes (silatrans), J. Chem. Soc. Dalton Trans., 1975, 25. [all data]

Shatz, Belikov, et al., 1979
Shatz, V.D.; Belikov, V.A.; Zelchan, G.I.; Solomennikova, I.I.; Lukevics, E., Chromatography of organometallic and organometalloidal derivatives of amino alcohols. I. Retention indices of silatranes, J. Chromatogr., 1979, 174, 1, 83-95, https://doi.org/10.1016/S0021-9673(00)87039-9 . [all data]

Notes

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• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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