Home Symbol which looks like a small house Up Solid circle with an upward pointer in it

Titanium, tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-


Gas phase ion energetics data

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
2.99 ± 0.13IMRBSharpe, Eyler, et al., 1990EA given is actually -«DELTA»Gea(350 K). Between Cr(CF3COCHCOCF3)3, V(CF3COCHCOCF3)3; B

Ionization energy determinations

IE (eV) Method Reference Comment
7.98PEEvans, Hamnett, et al., 1972Vertical value; LLK
7.94 ± 0.07PEEvans, Hamnett, et al., 1972, 2Vertical value; LLK

References

Go To: Top, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E., Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis, Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014 . [all data]

Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F., The relative orbital energies of metal ligand electrons in some tris(hexafluoroacetylacetonato) transition-metal complexes, J. Coord. Chem., 1972, 2, 57. [all data]

Evans, Hamnett, et al., 1972, 2
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R., Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]


Notes

Go To: Top, Gas phase ion energetics data, References