Cyclodecene, (E)-

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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

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Individual Reactions

Hydrogen + Cyclodecene, (E)- = Cyclodecane

By formula: H2 + C10H18 = C10H20

Quantity Value Units Method Reference Comment
Δr-24.0 ± 0.9kcal/molChydTurner and Meador, 1957liquid phase; solvent: Acetic acid

Cyclodecene, (E)- = Cyclodecene, (Z)-

By formula: C10H18 = C10H18

Quantity Value Units Method Reference Comment
Δr-3.56 ± 0.07kcal/molEqkTaskinen, 1980liquid phase; solvent: Acetic acid

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.91 ± 0.15EIRemane, Graefe, et al., 1972LLK
8.80PEBischof and Heilbronner, 1970RDSH

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Turner and Meador, 1957
Turner, R.B.; Meador, W.R., Heats of hydrogenation. IV. Hydrogenation of some cis- and trans-cycloolefins, J. Am. Chem. Soc., 1957, 79, 4133-4136. [all data]

Taskinen, 1980
Taskinen, E., Thermodynamics of vinyl ethers. XXVI. Relative stabilities of the geometrical isomers of 8- to 15-membered 1-methoxycycloalkenes, Acta Chem. Scand., Ser. B, 1980, 643-646. [all data]

Remane, Graefe, et al., 1972
Remane, H.; Graefe, J.; Herzschuh, R., Ionisationspotentiale von cis- und trans-Cycloalkenen, Z. Chem., 1972, 12, 194. [all data]

Bischof and Heilbronner, 1970
Bischof, P.; Heilbronner, E., Photoelektron-Spektren von Cycloalkenen und Cycloalkadienen, Helv. Chim. Acta, 1970, 53, 1677. [all data]


Notes

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