Stannane, tetrapropyl-
- Formula: C12H28Sn
- Molecular weight: 291.061
- IUPAC Standard InChIKey: OIQCWAIEHVRCCG-UHFFFAOYSA-N
- CAS Registry Number: 2176-98-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
View 3d structure (requires JavaScript / HTML 5) - Other names: Tetrapropyltin; Tetrapropylstannane; (C3H7)4Sn; tetra-n-Propyltin; Tin, tetrapropyl-
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 15.6 ± 0.60 | kcal/mol | CC-SB | Abraham and Irving, 1980 | Anoher value for the enthalpy of vaporization has been reported: 16.0 ± 0.50 kcal/mol Davies, Pope, et al., 1963.; MS |
ΔvapH° | 15.6 ± 0.60 | kcal/mol | C | Abraham and Irving, 1980, 2 | AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
13.1 ± 0.2 | 400. | N/A | Baev, 2001 | Based on data from 343. to 457. K.; AC |
14.5 | 333. to 393. | GC | Hawker, 1992 | AC |
12.5 | 376. | A | Stephenson and Malanowski, 1987 | Based on data from 361. to 470. K.; AC |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.82 | PE | Kochi, 1980 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C6H15Sn+ | 10.6 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
C9H21Sn+ | 8.8 ± 0.2 | ? | EI | Occolowitz, Lett. 1966 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J.,
J. Chem. Thermodyn., 1980, 12, 539. [all data]
Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A.,
Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin,
Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233
. [all data]
Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J.,
Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds,
The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4
. [all data]
Baev, 2001
Baev, A.K.,
Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]
Hawker, 1992
Hawker, Darryl,
Equilibrium vapour pressures of tetraorganostannanes,
Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W
. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Kochi, 1980
Kochi, J.K.,
The role of electron transfer and charge transfer in organometallic chemistry,
Pure Appl. Chem., 1980, 52, 571. [all data]
Occolowitz, Lett. 1966
Occolowitz, J.L.,
Electron impact fragmentation of some organotin compounds,
Tetrahedron, Lett. 1966, 5291. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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