Stannane, tetrapropyl-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-34.2 ± 1.4kcal/molReviewMartinho SimõesSelected data.
Δfgas-31.0 ± 1.6kcal/molReviewMartinho Simões 
Δfgas-44.46kcal/molReviewMartinho Simões 

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfliquid-49.8 ± 1.3kcal/molReviewMartinho SimõesSelected data.
Δfliquid-46.7 ± 1.5kcal/molReviewMartinho Simões 
Δfliquid-60.09kcal/molReviewMartinho Simões 
Quantity Value Units Method Reference Comment
Δcliquid-2173.3 ± 1.2kcal/molCC-SBDavies, Pope, et al., 1963Please also see Pedley and Rylance, 1977 and Cox and Pilcher, 1970.
Δcliquid-2176.4 ± 1.4kcal/molCC-SBLautsch, Tröber, et al., 1963Please also see Cox and Pilcher, 1970.
Δcliquid-2163.0kcal/molCC-SBJones, Evans, et al., 1935 

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap15.6 ± 0.60kcal/molCC-SBAbraham and Irving, 1980Anoher value for the enthalpy of vaporization has been reported: 16.0 ± 0.50 kcal/mol Davies, Pope, et al., 1963.; MS
Δvap15.6 ± 0.60kcal/molCAbraham and Irving, 1980, 2AC

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
13.1 ± 0.2400.N/ABaev, 2001Based on data from 343. to 457. K.; AC
14.5333. to 393.GCHawker, 1992AC
12.5376.AStephenson and Malanowski, 1987Based on data from 361. to 470. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
8.82PEKochi, 1980Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H15Sn+10.6 ± 0.2?EIOccolowitz, Lett. 1966RDSH
C9H21Sn+8.8 ± 0.2?EIOccolowitz, Lett. 1966RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin M.GEILEN UNIVERSITE LIBRE DE BRUXELLES, BELGIUM
NIST MS number 14033

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References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Davies, Pope, et al., 1963
Davies, J.V.; Pope, A.E.; Skinner, H.A., Thermochemistry of metallic alkyls. Part 10.?Heats of combustion of some tetra-alkyls of tin, Trans. Faraday Soc., 1963, 59, 2233, https://doi.org/10.1039/tf9635902233 . [all data]

Pedley and Rylance, 1977
Pedley, J.B.; Rylance, J., Computer Analysed Thermochemical Data: Organic and Organometallic Compounds, University of Sussex, Brigton, 1977. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds in Academic Press, New York, 1970. [all data]

Lautsch, Tröber, et al., 1963
Lautsch, W.F.; Tröber, A.; Zimmer, W.; Mehner, L.; Linck, W.; Lehmann, H.M.; Brandenberger, H.; Korner, H.; Metschker, H.-J.; Wagner, K.; Kaden, R., Z. Chem., 1963, 3, 415. [all data]

Jones, Evans, et al., 1935
Jones, W.J.; Evans, D.P.; Gulwell, T.; Griffiths, D.C., J. Chem. Soc., 1935, 39.. [all data]

Abraham and Irving, 1980
Abraham, M.H.; Irving, R.J., J. Chem. Thermodyn., 1980, 12, 539. [all data]

Abraham and Irving, 1980, 2
Abraham, M.H.; Irving, R.J., Enthalpies of vaporization of tetramethyltin, tetraethyltin, tetra-n-propyltin, and tetraethyl-lead, and a survey of the Group IV tetramethyl and tetraethyl compounds, The Journal of Chemical Thermodynamics, 1980, 12, 6, 539-544, https://doi.org/10.1016/0021-9614(80)90183-4 . [all data]

Baev, 2001
Baev, A.K., Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 2001, 44, 1, 3. [all data]

Hawker, 1992
Hawker, Darryl, Equilibrium vapour pressures of tetraorganostannanes, Chemosphere, 1992, 25, 4, 427-436, https://doi.org/10.1016/0045-6535(92)90276-W . [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Kochi, 1980
Kochi, J.K., The role of electron transfer and charge transfer in organometallic chemistry, Pure Appl. Chem., 1980, 52, 571. [all data]

Occolowitz, Lett. 1966
Occolowitz, J.L., Electron impact fragmentation of some organotin compounds, Tetrahedron, Lett. 1966, 5291. [all data]


Notes

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