Cobalt, tricarbonylhydro(phosphorus trifluoride)-

Formula: C₃HCoF₃O₃P
Molecular weight: 231.9404
IUPAC Standard InChI: InChI=1S/3CO.Co.F3P.H/c3*1-2;;1-4(2)3;
IUPAC Standard InChIKey: BDCMIOYDUUNVBP-UHFFFAOYSA-N
CAS Registry Number: 21329-74-8
Chemical structure:
This structure is also available as a 2d Mol file
Other names: (Phosphorus trifluoride)cobalt tricarbonyl hydride
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Other data available:
- Mass spectrum (electron ionization)
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Gas phase ion energetics data

Data compiled by: Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

IE (eV)	Method	Reference
9.8 ± 0.2	EI	Saalfeld, McDowell, et al., 1968

Ion	AE (eV)	Other Products	Method	Reference
COF₃PCo⁺	14.3 ± 0.3	?	EI	Saalfeld, McDowell, et al., 1968
CoCO⁺	15.5 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
CHOF₃PCo⁺	12.5 ± 0.3	2CO	EI	Saalfeld, McDowell, et al., 1968
CHOCo⁺	12.1 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
CoC₂O₂⁺	14.0 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
C₂HO₂F₃PCo⁺	10.3 ± 0.3	CO	EI	Saalfeld, McDowell, et al., 1968
C₂HO₂Co⁺	12.4 ± 0.3	?	EI	Saalfeld, McDowell, et al., 1968
CoC₃O₃⁺	12.1 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
C₃HO₃Co⁺	9.9 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
Co⁺	17.8 ± 0.3	?	EI	Saalfeld, McDowell, et al., 1968
CoHPF₃⁺	13.8 ± 0.2	3CO	EI	Saalfeld, McDowell, et al., 1968
CoPF₃⁺	15.7 ± 0.2	?	EI	Saalfeld, McDowell, et al., 1968
CoH⁺	14.6 ± 0.3	?	EI	Saalfeld, McDowell, et al., 1968

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Saalfeld, McDowell, et al., 1968
Saalfeld, F.E.; McDowell, M.V.; Gondal, S.K.; MacDiarmid, A.G., The mass spectra of trifluorophosphinecarbonylcobalt hydrides, J. Am. Chem. Soc., 1968, 90, 3684. [all data]

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Symbols used in this document:

AE Appearance energy
Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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