Silane, methylenebis[trimethyl-

• Formula: C₇H₂₀Si₂
• Molecular weight: 160.4047
• IUPAC Standard InChI: InChI=1S/C7H20Si2/c1-8(2,3)7-9(4,5)6/h7H2,1-6H3 Copy

  
• IUPAC Standard InChIKey: GYIODRUWWNNGPI-UHFFFAOYSA-N Copy
• CAS Registry Number: 2117-28-4
• Chemical structure:
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• Other names: 2,4-Disilapentane, 2,2,4,4-tetramethyl-; Bis(trimethylsilyl)methane; Methylenebis[trimethylsilane]; Silane, methylenebis*trimethyl-
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• Information on this page:
  • Condensed phase thermochemistry data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Phase change data
  • Reaction thermochemistry data
  • Mass spectrum (electron ionization)
  • Gas Chromatography
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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of liquid

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

De-protonation reactions

C₇H₁₉Si₂^- +  =

By formula: C₇H₁₉Si₂^- + H⁺ = C₇H₂₀Si₂

References

Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Guseinov and Karasharli, 1982
Guseinov, Z.A.; Karasharli, K.A., Heat capacity and thermodynamic functions of hexamethyldisilylmethane, Azerb. Khim. Zhur., 1982, (4), 107-109. [all data]

Guseinov, Karasharli, et al., 1975
Guseinov, Z.A.; Karasharli, K.A.; Dzhafarov, O.I.; Nurullaev, G.G.; Nametkin, N.S.; Gusel'nikov, L.E.; Volnina, F.A.; Burdasov, E.N.; Vdovin, V.M., Thermodynamic parameters of some cyclic and bridging carbosilanes, Dokl.Akad. Nauk, 1975, SSSR 222, 1369-1372. [all data]

Hosomi and Traylor, 1975
Hosomi, A.; Traylor, T.G., Studies of interactions of adjacent carbon-metal σ bonds by photoelectron spectroscopy, J. Am. Chem. Soc., 1975, 97, 3682. [all data]

Romer, Gatev, et al., 1998
Romer, B.; Gatev, G.G.; Zhong, M.; Brauman, J.I., Alpha-Stabilization by Silyl and Phosphino Substitution, J. Am. Chem. Soc., 1998, 120, 12, 2919, https://doi.org/10.1021/ja970279s . [all data]

Brinkman, Berger, et al., 1994
Brinkman, E.A.; Berger, S.; Brauman, J.I., alpha-Silyl-substituent stabilization of carbanions and silyl anions, J. Am. Chem. Soc., 1994, 116, 18, 8304, https://doi.org/10.1021/ja00097a042 . [all data]

Notes

Go To: Top, Condensed phase thermochemistry data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  Cp,liquid	Constant pressure heat capacity of liquid
  S°liquid	Entropy of liquid at standard conditions
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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