Methanimidamide, N'-(2-chlorophenyl)-N,N-dimethyl-
- Formula: C9H11ClN2
- Molecular weight: 182.650
- IUPAC Standard InChI: InChI=1S/C9H11ClN2/c1-12(2)7-11-9-6-4-3-5-8(9)10/h3-7H,1-2H3
- IUPAC Standard InChIKey: APKRGIKHQYEHGV-UHFFFAOYSA-N
- CAS Registry Number: 2103-49-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Formamidine, N'-(o-chlorophenyl)-N,N-dimethyl-; N,N-Dimethyl-N'-(2-chlorophenyl)formamidine; N'-(o-Chlorophenyl)-N,N-dimethylformamidine; N'-(2-Chlorophenyl)-N,N-dimethylformamidine; N1N1-Dimethyl-N2-ortho-chlorophenylformamidine
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Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference |
|---|---|---|
| 7.3 | EI | Kuschel and Grutzmacher, 1974 |
| 7.3 ± 0.1 | EI | Kuschel and Grutzmacher, 1974, 2 |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C9H10N2Cl+ | 8.9 | H | EI | Kuschel and Grutzmacher, 1974 | |
| C9H11N2+ | 8.6 | Cl | EI | Kuschel and Grutzmacher, 1974 | |
| C9H11N2+ | 8.6 ± 0.1 | Cl | EI | Kuschel and Grutzmacher, 1974, 2 |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-30 | 240. | 1574. | Dolecka, Raczynska, et al., 1988 | He, Chromosorb W AW; Column length: 2. m |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Kuschel and Grutzmacher, 1974
Kuschel, H.; Grutzmacher, H.-F.,
Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XIII. Einfluβ der dissoziationsenergie auf intramolekulare aromatische substitutionen in den molekul- ionen von N,N-dimethyl- N'-phenylformamidinen,
Org. Mass Spectrom., 1974, 9, 408. [all data]
Kuschel and Grutzmacher, 1974, 2
Kuschel, H.; Grutzmacher, H.-F.,
Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XI. EinfluB von substituenten auf die bildung cyclischer fragment-ionen in den massenspektren von N,N-dimethyl-N'-2-chlorphenylformamidinen und 2-chlorformaniliden,
Org. Mass Spectrom., 1974, 9, 395. [all data]
Dolecka, Raczynska, et al., 1988
Dolecka, E.; Raczynska, E.D.; Drapala, T.,
Retention indices and basicity of N1N1-dimethyl-N2-phenylformamidines ortho-substituent effect,
J. Chem. Soc. Perkin Trans. 2:, 1988, 3, 257-260, https://doi.org/10.1039/p29880000257
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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