Iodide
- Formula: I-
- Molecular weight: 126.90502
- IUPAC Standard InChI:
- InChI=1S/HI/h1H/p-1
- Download the identifier in a file.
- IUPAC Standard InChIKey: XMBWDFGMSWQBCA-UHFFFAOYSA-M
- CAS Registry Number: 20461-54-5
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Iodized Oil; Iodine anion
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Gas phase thermochemistry data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150
- Gas phase ion energetics data
- Options:
Ion clustering data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
= BrI2-
By formula: I- = BrI2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 141.8 ± 0.96 | kJ/mol | PDis | Crider, Harrison, et al., 2011 | gas phase; B |
![]() | 149.4 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 107.9 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF2-(q); ; «DELTA»S(EA)=4.5; B |
= CH3ClI-
By formula: I- = CH3ClI-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 33.8 ± 0.96 | kJ/mol | N/A | Van Duzor, Wei, et al., 2010 | gas phase; B |
By formula: I- = C6H5INO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.4 ± 8.4 | kJ/mol | N/A | Piani, Becucci, et al., 2008 | gas phase; Stated electron affinity is the Vertical Detachment Energy; B |
= HIS-
By formula: I- = HIS-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 76.15 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; H-; ; «DELTA»S(acid)=20.9; «DELTA»S(EA)=6.4; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.07 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; H-; ; «DELTA»S(acid)=20.9; «DELTA»S(EA)=6.4; B |
= IRb-
By formula: I- = IRb-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 95.0 ± 4.2 | kJ/mol | Ther | Miller, Leopold, et al., 1986 | gas phase; Extrapolated by polarizability and radius from experimental data.; B |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.5 | kJ/mol | Ther | Zhao, Yourshaw, et al., 1994 | gas phase; B |
By formula: I- + CHCl3 = (I- CHCl3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + CHF3 = (I- CHF3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + CHN = (I- CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.3 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.5 ± 6.7 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- CHN) + CHN = (I-
2CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 55.2 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.7 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 30.1 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 2CHN) + CHN = (I-
3CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.9 ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.9 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.5 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 3CHN) + CHN = (I-
4CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 84.9 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.4 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 4CHN) + CHN = (I-
5CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 95.8 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.53 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 5CHN) + CHN = (I-
6CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.28 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 6CHN) + CHN = (I-
7CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.28 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: (I- 7CHN) + CHN = (I-
8CHN)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28. ± 4.2 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88.7 | J/mol*K | PHPMS | Meot-ner, Cybulski, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 2.1 | kJ/mol | TDAs | Meot-ner, Cybulski, et al., 1988 | gas phase; B |
By formula: I- + CH2O2 = (I- CH2O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.1 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
![]() | 54.0 ± 8.8 | kJ/mol | CIDT | Walker and Sunderlin, 1999 | gas phase; Authors suggest real value somewhere between this and Caldwell and Kebarle, 1984; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 86.6 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 53.1 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
By formula: I- + CH3Br = (I- CH3Br)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 34.7 ± 0.84 | kJ/mol | N/A | Van Duzor, Wei, et al., 2010 | gas phase; B |
![]() | 34.7 ± 2.1 | kJ/mol | PDis | Cyr, Bishea, et al., 1992 | gas phase; B |
By formula: I- + CH3I = (I- CH3I)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35.7 ± 0.84 | kJ/mol | N/A | Van Duzor, Wei, et al., 2010 | gas phase; B |
![]() | 32.6 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
![]() | 35.1 ± 2.1 | kJ/mol | N/A | Arnold, Neumark, et al., 1995 | gas phase; ZEKE data, shift relative to bare I-; B |
![]() | 34.7 ± 2.1 | kJ/mol | PDis | Cyr, Bishea, et al., 1992 | gas phase; B |
![]() | 38. ± 8.4 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 68.6 | J/mol*K | HPMS | Dougherty and Roberts, 1974 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 11.4 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
![]() | 17.2 ± 1.3 | kJ/mol | TDAs | Dougherty and Roberts, 1974 | gas phase; B |
By formula: I- + CH3NO2 = (I- CH3NO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 51.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + CH4O = (I- CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.79 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 47.3 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
![]() | 46.9 | kJ/mol | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
![]() | 46. | kJ/mol | PHPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 71.5 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
![]() | 74.5 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 25. ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
![]() | 24. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B |
By formula: (I- CH4O) + CH4O = (I-
2CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39.7 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 46.4 ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.6 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17.8 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 18. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 2CH4O) + CH4O = (I-
3CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.2 ± 2.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 93.7 | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 13. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 3CH4O) + CH4O = (I-
4CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 104. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 9.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 4CH4O) + CH4O = (I-
5CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 113. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.3 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 5CH4O) + CH4O = (I-
6CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 40. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 115. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.9 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 6CH4O) + CH4O = (I-
7CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 117. | J/mol*K | PHPMS | Hiraoka and Yamabe, 1991 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 4.6 ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; B |
By formula: (I- 7CH4O) + CH4O = (I-
8CH4O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38. ± 4.2 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | N/A | Hiraoka and Yamabe, 1991 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3. ± 8.4 | kJ/mol | TDAs | Hiraoka and Yamabe, 1991 | gas phase; Entropy estimated.; B |
+
= CH4I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10.9 | kJ/mol | N/A | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -11.6 | kJ/mol | TDAs | Hiraoka, Mizuno, et al., 2001 | gas phase; B |
By formula: I- + CO2 = (I- CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 7.5 | kJ/mol | N/A | Piani, Becucci, et al., 2008 | gas phase; Stated electron affinity is the Vertical Detachment Energy; B |
![]() | 17. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 20. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
![]() | 13.4 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
![]() | 23.4 ± 0.42 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 56.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
![]() | 76.1 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
![]() | 3.3 ± 0.42 | kJ/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B,M |
![]() | 1.7 ± 0.42 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: (I- CO2) + CO2 = (I-
2CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 20. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
![]() | 10.9 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 72.4 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 3. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- 2CO2) + CO2 = (I-
3CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.20 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 19. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -3. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- 3CO2) + CO2 = (I-
4CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.53 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
![]() | 15. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 19. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -4.2 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- 4CO2) + CO2 = (I-
5CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.11 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
![]() | 13. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 18. ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.5 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -5.9 ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987 | gas phase; B |
By formula: (I- 5CO2) + CO2 = (I-
6CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 7.53 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
![]() | 18. | kJ/mol | PHPMS | Hiraoka, Mizuse, et al., 1987 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79. | J/mol*K | N/A | Hiraoka, Mizuse, et al., 1987 | gas phase; Entropy change calculated or estimated; M |
By formula: (I- 6CO2) + CO2 = (I-
7CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 7.95 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
By formula: (I- 7CO2) + CO2 = (I-
8CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 7.95 | kJ/mol | N/A | Gomez, Taylor, et al., 2002 | gas phase; EA=Vertical Detachment Energy. Affinity is stepwise difference in EAs.; B |
By formula: (I- 8CO2) + CO2 = (I-
9CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 9CO2) + CO2 = (I-
10CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 10CO2) + CO2 = (I-
11CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.2 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 11CO2) + CO2 = (I-
12CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.7 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 12CO2) + CO2 = (I-
13CO2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.6 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: I- + CS2 = (I- CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31.0 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 69.9 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 10. ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: (I- CS2) + CS2 = (I-
2CS2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 28.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | PHPMS | Hiraoka, Fujimaki, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 0.8 ± 4.2 | kJ/mol | TDAs | Hiraoka, Fujimaki, et al., 1993 | gas phase; B |
By formula: I- + C2H3F3O = (I- C2H3F3O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 84.1 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C2H3N = (I- C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 49.8 ± 8.4 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
![]() | 46.4 ± 1.7 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 46.4 ± 4.6 | kJ/mol | LPES | Dessent, Bailey, et al., 1995 | gas phase; B |
![]() | 46.02 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 50. | kJ/mol | PHPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 57.7 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 76.1 | J/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 27. ± 8.4 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
![]() | 28. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B |
![]() | 28.9 ± 2.1 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (I- C2H3N) + C2H3N = (I-
2C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.51 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 46.4 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 46.4 ± 1.7 | kJ/mol | N/A | Dessent, Bailey, et al., 1995 | gas phase; Vertical Detachment Energy: 2.25±0.08 eV.; B |
![]() | 43.93 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 77.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 87.0 | J/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 20.5 ± 3.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 18.0 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (I- 2C2H3N) + C2H3N = (I-
3C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 40.6 ± 2.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
![]() | 38.9 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.3 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 92.5 | J/mol*K | PHPMS | Yamdagni and Kebarle, 1972 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 13.4 ± 3.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 11.3 | kJ/mol | TDAs | Yamdagni and Kebarle, 1972 | gas phase; B |
By formula: (I- 3C2H3N) + C2H3N = (I-
4C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.6 ± 0.42 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 31.0 ± 3.3 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 80.8 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.4 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (I- 4C2H3N) + C2H3N = (I-
5C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.7 ± 1.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 44.4 ± 3.8 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.1 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.9 ± 5.9 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
By formula: (I- 5C2H3N) + C2H3N = (I-
6C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -10. ± 4.2 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 6C2H3N) + C2H3N = (I-
7C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 15. ± 4.6 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 7C2H3N) + C2H3N = (I-
8C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 13. ± 5.0 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 8C2H3N) + C2H3N = (I-
9C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 5.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 9C2H3N) + C2H3N = (I-
10C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 6.3 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 10C2H3N) + C2H3N = (I-
11C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.8 ± 6.7 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 11C2H3N) + C2H3N = (I-
12C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.8 ± 7.1 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: (I- 13C2H3N) + C2H3N = (I-
14C2H3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | -4. ± 7.9 | kJ/mol | N/A | Markovich, Perera, et al., 1996 | gas phase; B |
By formula: I- + C2H4F3N = (I- C2H4F3N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C2H4O2 = (I- C2H4O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 70.7 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 89.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.9 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
By formula: I- + C2H6OS = (I- C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 65.69 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B,M |
![]() | 67. | kJ/mol | PHPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38.5 | kJ/mol | TDAs | Magnera, Caldwell, et al., 1984 | gas phase; B |
By formula: (I- C2H6OS) + C2H6OS = (I-
2C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 53.6 | kJ/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 92.0 | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: (I- 2C2H6OS) + C2H6OS = (I-
3C2H6OS)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 48.5 | kJ/mol | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 105. | J/mol*K | PHPMS | Magnera, Caldwell, et al., 1984 | gas phase; M |
By formula: I- + C2H6O = (I- C2H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.39 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 50.6 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.1 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.6 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 27. ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
![]() | 25. ± 8.4 | kJ/mol | IMRE | Tanabe, Morgon, et al., 1996 | gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B |
+ 2
= C4H12IO2-
By formula: I- + 2C2H6O = C4H12IO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.93 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+ 3
= C6H18IO3-
By formula: I- + 3C2H6O = C6H18IO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 35.1 ± 2.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14.7 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+
= C3F6I-
By formula: I- + C3F6 = C3F6I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 36.0 ± 1.3 | kJ/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.0 ± 1.3 | kJ/mol | TDAs | Hiraoka, Takao, et al., 2002 | gas phase; B |
By formula: I- + C3H2F6O = (I- C3H2F6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C3H2N2 = (I- C3H2N2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 79.1 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C3H6O = (I- C3H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 50.2 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C3H6O2 = (I- C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 69.5 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.9 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
By formula: I- + C3H6O2 = (I- C3H6O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 69.5 | kJ/mol | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
By formula: I- + C3H8O = (I- C3H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.81 ± 0.84 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 51.0 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 79.9 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 26.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 27. ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
+ 2
= C6H16IO2-
By formula: I- + 2C3H8O = C6H16IO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 ± 1.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 19.5 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+ 3
= C9H24IO3-
By formula: I- + 3C3H8O = C9H24IO3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 39.7 ± 2.9 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 14.8 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
By formula: I- + C4HF9O = (I- C4HF9O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.1 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C4H8O2 = (I- C4H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 69.9 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.8 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.4 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
By formula: I- + C4H10O = (I- C4H10O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.8 ± 1.3 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 50.6 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 78.2 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 25.7 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
![]() | 27. ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
+ 2
= C8H20IO2-
By formula: I- + 2C4H10O = C8H20IO2-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 47.3 ± 1.7 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 18.1 | kJ/mol | TDAs | Bogdanov, Peschke, et al., 1999 | gas phase; B |
+
= C5F8I-
By formula: I- + C5F8 = C5F8I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.84 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 16.9 ± 0.84 | kJ/mol | TDAs | Hiraoka, Fujita, et al., 1905 | gas phase; B |
By formula: I- + C5H8O2 = (I- C5H8O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 63.2 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C5H10O2 = (I- C5H10O2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 64.4 ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.8 | J/mol*K | PHPMS | Caldwell and Kebarle, 1984 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 37. ± 4.2 | kJ/mol | TDAs | Caldwell and Kebarle, 1984 | gas phase; B |
By formula: I- + C6F6 = (I- C6F6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 ± 4.2 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 72.4 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 24. ± 6.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; B |
By formula: (I- C6F6) + C6F6 = (I-
2C6F6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43.5 | kJ/mol | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1987, 2 | gas phase; M |
By formula: I- + C6H5ClO = (I- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 85.8 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 48.5 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
48.5 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H5ClO = (I- C6H5ClO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 88.3 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 51.0 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
51.0 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H5FO = (I- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.0 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 44.8 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
43.9 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H5FO = (I- C6H5FO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 81.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43.9 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
44.8 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H5NO3 = (I- C6H5NO3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 97.1 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 59.8 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.8 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H6O = (I- C6H6O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 72.4 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 35. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
35. | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C6H6 = (I- C6H6)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 26. ± 8.4 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B,M |
![]() | 38. ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 59.4 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8. ± 11. | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988, 2 | gas phase; B |
By formula: I- + C6H7N = (I- C6H7N)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + C7H5NO = (I- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 99.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 62.3 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
62.3 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C7H5NO = (I- C7H5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 96.2 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 59.0 ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
59.0 | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C7H8O = (I- C7H8O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 68.6 ± 7.5 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 88. | J/mol*K | N/A | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 31. ± 4.2 | kJ/mol | IMRE | Paul and Kebarle, 1990 | gas phase; «DELTA»Gaff at 423 K; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
31. | 423. | PHPMS | Paul and Kebarle, 1990 | gas phase; Entropy change calculated or estimated; M |
By formula: I- + C7H8 = (I- C7H8)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 46.0 ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + CeI3 = (I- CeI3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 280. ± 33. | kJ/mol | TDEq | Chantry, 1976 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 120. | J/mol*K | MS | Chantry, 1976 | gas phase; heated collision chamber; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 250. ± 42. | kJ/mol | TDEq | Chantry, 1976 | gas phase; B |
By formula: I- + CsI = (I- CsI)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 141.00 ± 0.21 | kJ/mol | N/A | Wang, Wang, et al., 2010 | gas phase; B |
![]() | 151. ± 5.4 | kJ/mol | N/A | Gusarov, Gorokhov, et al., 1979 | gas phase; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: I- + CsI2 = (I- CsI2)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 115. ± 13. | kJ/mol | N/A | Gusarov, Gorokhov, et al., 1979 | gas phase; value altered from reference due to conversion from electron convention to ion convention; B |
By formula: I- + DyI3 = (I- DyI3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 279. ± 8.4 | kJ/mol | TDAs | Lelik, Korobov, et al., 1984 | gas phase; anion heat reworked from reference due to better dHf(DyI3); value altered from reference due to conversion from electron convention to ion convention; B |
By formula: I- + HBr = (I- HBr)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 67.4 ± 8.4 | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 82.0 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(I-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 43. ± 11. | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
42.7 | 300. | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(I-)SO2; M |
By formula: I- + HCl = (I- HCl)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 61.9 ± 8.4 | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
![]() | 59.4 | kJ/mol | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 83.7 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
![]() | 95.0 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 37. ± 11. | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 62.8 ± 8.4 | kJ/mol | Est | Larson and McMahon, 1984 | gas phase; Extrapolated from other bihalide data; B |
![]() | 63. | kJ/mol | PHPMS | Caldwell, Masucci, et al., 1989 | gas phase; M |
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 71.1 ± 8.4 | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 102. | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(I-)SO2; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 41. ± 11. | kJ/mol | TDEq | Caldwell and Kebarle, 1985 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
41. | 300. | PHPMS | Caldwell and Kebarle, 1985 | gas phase; switching reaction(I-)SO2; M |
By formula: I- + H2O = (I- H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 43. ± 3. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 64.0 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 80.8 | J/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 68.2 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 23. ± 1. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
22. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (I- H2O) + H2O = (I-
2H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 41.4 ± 0.84 | kJ/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B,M |
![]() | 39.7 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 39.7 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 41. ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 41. ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.6 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 84.9 | J/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 79.5 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 17. ± 2. | kJ/mol | AVG | N/A | Average of 6 values; Individual data points |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
17. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (I- 2H2O) + H2O = (I-
3H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.9 ± 1.3 | kJ/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B,M |
![]() | 36. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
![]() | 38.5 ± 0.84 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 39. ± 4.2 | kJ/mol | TDAs | Payzant, Yamdagni, et al., 1971 | gas phase; B |
![]() | 39. ± 4.2 | kJ/mol | TDAs | Arshadi, Yamdagni, et al., 1970 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 85.4 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
![]() | 87.9 | J/mol*K | HPMS | Keesee and Castleman, 1980 | gas phase; M |
![]() | 89.1 | J/mol*K | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 12.6 | kJ/mol | TDAs | Keesee and Castleman, 1980 | gas phase; B |
![]() | 13.0 ± 3.3 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 14. ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (I- 3H2O) + H2O = (I-
4H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.5 ± 1.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B,M |
![]() | 29. ± 9.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 98.7 | J/mol*K | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 8.8 ± 6.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; B |
![]() | 9.2 ± 8.4 | kJ/mol | TDAs | Kebarle, Arshadi, et al., 1968 | gas phase; B,M |
By formula: (I- 4H2O) + H2O = (I-
5H2O)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37.7 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B,M |
![]() | 17.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 100. | J/mol*K | N/A | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 6.28 | kJ/mol | TDAs | Hiraoka, Mizuse, et al., 1988 | gas phase; Entropy estimated; B |
By formula: (I- 5H2O) + H2O = (I-
6H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 32.6 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 6H2O) + H2O = (I-
7H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.53 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 7H2O) + H2O = (I-
8H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.9 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 8H2O) + H2O = (I-
9H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 16.3 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 9H2O) + H2O = (I-
10H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.86 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 10H2O) + H2O = (I-
11H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 2.9 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 11H2O) + H2O = (I-
12H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.86 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 12H2O) + H2O = (I-
13H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.53 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 13H2O) + H2O = (I-
14H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 0.84 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 14H2O) + H2O = (I-
15H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.02 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- 15H2O) + H2O = (I-
16H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.02 | kJ/mol | N/A | Markovich, Pollack, et al., 1994 | gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B |
By formula: (I- H2O) + O2S = (I-
O2S
H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37.7 ± 0.42 | kJ/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
30. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: I- + H2S = (I- H2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 37. ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
By formula: I- + H3N = (I- H3N)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 31.0 ± 1.3 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B,M |
![]() | 31. ± 4.2 | kJ/mol | TDAs | Caldwell, Masucci, et al., 1989 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 87.4 | J/mol*K | HPMS | Evans, Keesee, et al., 1987 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 5.0 ± 2.5 | kJ/mol | TDAs | Evans, Keesee, et al., 1987 | gas phase; B |
By formula: I- + HoI3 = (I- HoI3)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 288.7 | kJ/mol | TDAs | Bencze, Kaposi, et al., 1988 | gas phase; Data at 0 K. See also Pramann and Rademann, 1999; value altered from reference due to conversion from electron convention to ion convention; B |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 163. ± 8.8 | kJ/mol | N/A | Burdukovskaya, Kudin, et al., 1984 | gas phase; value altered from reference due to conversion from electron convention to ion convention; B |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 100. | kJ/mol | N/A | Downs and Adams, 1973 | gas phase; from «DELTA»rH(f); M |
+
= I3-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 136. ± 10. | kJ/mol | N/A | Taylor, Asmis, et al., 1999 | gas phase; B |
![]() | 126. ± 5.9 | kJ/mol | CIDT | Do, Klein, et al., 1997 | gas phase; B |
![]() | 356.1 | kJ/mol | Ther | Finch, Gates, et al., 1977 | gas phase; This value is far more bound than expected from other studies; B |
![]() | 136.4 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 94.14 | kJ/mol | N/A | Check, Faust, et al., 2001 | gas phase; FeF3-(t); ; «DELTA»S(EA)=2.8; B |
+
= I4P-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 54.0 ± 7.9 | kJ/mol | CIDT | Heil, Check, et al., 2002 | gas phase; B |
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.18 | kJ/mol | Ther | Zhao, Yourshaw, et al., 1994 | gas phase; B |
By formula: I- + N2O = (I- N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 16. ± 1. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 59.0 | J/mol*K | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
By formula: (I- N2O) + N2O = (I-
2N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 14. ± 1. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 59.4 | J/mol*K | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; M |
By formula: (I- 2N2O) + N2O = (I-
3N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
![]() | 13. | kJ/mol | PHPMS | Hiraoka, Aruga, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 63. | J/mol*K | N/A | Hiraoka, Aruga, et al., 1993 | gas phase; Entropy change calculated or estimated; M |
By formula: (I- 3N2O) + N2O = (I-
4N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 12. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 4N2O) + N2O = (I-
5N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 11. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 5N2O) + N2O = (I-
6N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.6 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 6N2O) + N2O = (I-
7N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 9.2 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 7N2O) + N2O = (I-
8N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 8.8 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 8N2O) + N2O = (I-
9N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 10. ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 9N2O) + N2O = (I-
10N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 7.5 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 10N2O) + N2O = (I-
11N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 4.2 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 11N2O) + N2O = (I-
12N2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 5.4 ± 8.4 | kJ/mol | PDis | Arnold, Bradforth, et al., 1995 | gas phase; EA given is Vertical Detachment Energy. Affinity: difference between successive EAs in (Y); B |
By formula: (I- 4294967295Na) + Na = I-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 82.0 ± 9.6 | kJ/mol | N/A | Miller, Leopold, et al., 1986 | gas phase; B |
By formula: I- + O2S = (I- O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 59.8 ± 8.4 | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B,M |
![]() | 53.97 ± 0.42 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 73.6 | J/mol*K | PHPMS | Caldwell and Kebarle, 1985 | gas phase; M |
![]() | 84.5 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 38. ± 11. | kJ/mol | TDAs | Caldwell and Kebarle, 1985 | gas phase; B |
![]() | 7.11 ± 0.42 | kJ/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B |
![]() | 28.5 ± 0.84 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
38. | 301. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (I- O2S) + H2O = (I-
H2O
O2S)
Bond type: Hydrogen bond (negative ion to hydride)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 14.6 ± 0.42 | kJ/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B |
Free energy of reaction
![]() |
T (K) | Method | Reference | Comment |
---|---|---|---|---|
15. | 300. | HPMS | Banic and Iribarne, 1985 | gas phase; electric fields; M |
By formula: (I- O2S
H2O) + O2S = (I-
2O2S
H2O)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 29.7 ± 0.42 | kJ/mol | TDAs | Banic and Iribarne, 1985 | gas phase; B |
By formula: (I- O2S) + O2S = (I-
2O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 42.26 ± 0.42 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 90.4 | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 15.1 ± 1.3 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
By formula: (I- 2O2S) + O2S = (I-
3O2S)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 38.5 ± 0.84 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B,M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 103. | J/mol*K | HPMS | Keesee, Lee, et al., 1980 | gas phase; M |
Quantity | Value | Units | Method | Reference | Comment |
![]() | 7.5 ± 2.5 | kJ/mol | TDAs | Keesee, Lee, et al., 1980 | gas phase; B |
+
= IO3S-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 161. ± 8.8 | kJ/mol | CIDT | Hao, Gilbert, et al., 2006 | gas phase; B |
+
= IXe-
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
![]() | 6.69 | kJ/mol | N/A | Lenzer, Furlanetto, et al., 1998 | gas phase; B |
![]() | 11.7 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; Entropy estimated; B |
Quantity | Value | Units | Method | Reference | Comment |
![]() | -8.24 | kJ/mol | TDAs | Wada, Kikkawa, et al., 2007 | gas phase; Entropy estimated; B |
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Go To: Top, Ion clustering data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Notes
Go To: Top, Ion clustering data, References
- Symbols used in this document:
T Temperature rG°
Free energy of reaction at standard conditions rH°
Enthalpy of reaction at standard conditions rS°
Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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