Hydrazine, 1-butyl-1-methyl-

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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
7.82 ± 0.05PEVovna, Vilesov, et al., 1975LLK
7.62 ± 0.05PIAkopyan and Vilesov, 1963RDSH
7.51 ± 0.02PIAkopyan, Vilesov, et al., 1963RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
CH4N2+9.6 ± 0.1?PIAkopyan and Vilesov, 1963RDSH
CH5N2+9.0 ± 0.1?PIAkopyan and Vilesov, 1963RDSH
C2H6N2+9.5 ± 0.2C3H8PIAkopyan and Vilesov, 1963RDSH
C2H7N2+9.1 ± 0.1?PIAkopyan and Vilesov, 1963RDSH
C4H11N2+8.0 ± 0.1CH3PIAkopyan and Vilesov, 1963RDSH
C5H12N+9.0 ± 0.1NH2PIAkopyan and Vilesov, 1963RDSH
C5H12N2+8.0 ± 0.2H2PIAkopyan and Vilesov, 1963RDSH
C5H13N+10.5 ± 0.1NHPIAkopyan and Vilesov, 1963RDSH
C5H13N2+8.0 ± 0.3HPIAkopyan and Vilesov, 1963RDSH
N2H2+9.5 ± 0.2C5H12PIAkopyan and Vilesov, 1963RDSH

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin ATLAS OF MASS SPECTRA OF ORGANIC COMPOUNDS, V. A. KOPTYUG, ED.
NIST MS number 64427

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Gas Chromatography

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryOV-101798.Zenkevich, 200525. m/0.20 mm/0.10 μm, N2/He, 6. K/min; Tstart: 50. C; Tend: 250. C

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Vovna, Vilesov, et al., 1975
Vovna, V.I.; Vilesov, F.I.; Lopatin, S.N., Photoelectron spectra of hydrazine and some alkyl derivatives, Opt. Spectrosc., 1975, 38, 143. [all data]

Akopyan and Vilesov, 1963
Akopyan, M.E.; Vilesov, F.I., Decay of the molecular ions formed in photoionization of hydrazine and some of its alkyl derivatives, Kinetika i Kataliz, 1963, 4, 39, In original 32. [all data]

Akopyan, Vilesov, et al., 1963
Akopyan, M.E.; Vilesov, F.I.; Terenin, A.N., Mass spectrometric investigation of photoionization of molecules and dissociation of excited molecular ions, Izv. Akad. Nauk SSSR, Ser. Fiz., 1963, 27, 1083, In original 1054. [all data]

Zenkevich, 2005
Zenkevich, I.G., Experimentally measured retention indices., 2005. [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References