Hydrazine, 1-butyl-1-methyl-
- Formula: C5H14N2
- Molecular weight: 102.1781
- IUPAC Standard InChIKey: OEEGQMYUIKPQMM-UHFFFAOYSA-N
- CAS Registry Number: 20240-62-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 1-Butyl-1-methylhydrazine; Hydrazine, butylmethyl-; Methylbutyl hydrazine; 1-Methyl-1-n-butylhydrazine
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.82 ± 0.05 | PE | Vovna, Vilesov, et al., 1975 | LLK |
7.62 ± 0.05 | PI | Akopyan and Vilesov, 1963 | RDSH |
7.51 ± 0.02 | PI | Akopyan, Vilesov, et al., 1963 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
CH4N2+ | 9.6 ± 0.1 | ? | PI | Akopyan and Vilesov, 1963 | RDSH |
CH5N2+ | 9.0 ± 0.1 | ? | PI | Akopyan and Vilesov, 1963 | RDSH |
C2H6N2+ | 9.5 ± 0.2 | C3H8 | PI | Akopyan and Vilesov, 1963 | RDSH |
C2H7N2+ | 9.1 ± 0.1 | ? | PI | Akopyan and Vilesov, 1963 | RDSH |
C4H11N2+ | 8.0 ± 0.1 | CH3 | PI | Akopyan and Vilesov, 1963 | RDSH |
C5H12N+ | 9.0 ± 0.1 | NH2 | PI | Akopyan and Vilesov, 1963 | RDSH |
C5H12N2+ | 8.0 ± 0.2 | H2 | PI | Akopyan and Vilesov, 1963 | RDSH |
C5H13N+ | 10.5 ± 0.1 | NH | PI | Akopyan and Vilesov, 1963 | RDSH |
C5H13N2+ | 8.0 ± 0.3 | H | PI | Akopyan and Vilesov, 1963 | RDSH |
N2H2+ | 9.5 ± 0.2 | C5H12 | PI | Akopyan and Vilesov, 1963 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Vovna, Vilesov, et al., 1975
Vovna, V.I.; Vilesov, F.I.; Lopatin, S.N.,
Photoelectron spectra of hydrazine and some alkyl derivatives,
Opt. Spectrosc., 1975, 38, 143. [all data]
Akopyan and Vilesov, 1963
Akopyan, M.E.; Vilesov, F.I.,
Decay of the molecular ions formed in photoionization of hydrazine and some of its alkyl derivatives,
Kinetika i Kataliz, 1963, 4, 39, In original 32. [all data]
Akopyan, Vilesov, et al., 1963
Akopyan, M.E.; Vilesov, F.I.; Terenin, A.N.,
Mass spectrometric investigation of photoionization of molecules and dissociation of excited molecular ions,
Izv. Akad. Nauk SSSR, Ser. Fiz., 1963, 27, 1083, In original 1054. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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