Molybdenum trifluoride
- Formula: F3Mo
- Molecular weight: 152.96
- CAS Registry Number: 20193-58-2
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | -607.10 | kJ/mol | Review | Chase, 1998 | Data last reviewed in December, 1978 |
| Quantity | Value | Units | Method | Reference | Comment |
| S°gas,1 bar | 295.87 | J/mol*K | Review | Chase, 1998 | Data last reviewed in December, 1978 |
Gas Phase Heat Capacity (Shomate Equation)
Cp° = A + B*t + C*t2 + D*t3 +
E/t2
H° − H°298.15= A*t + B*t2/2 +
C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 −
E/(2*t2) + G
Cp = heat capacity (J/mol*K)
H° = standard enthalpy (kJ/mol)
S° = standard entropy (J/mol*K)
t = temperature (K) / 1000.
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| Temperature (K) | 298. to 6000. |
|---|---|
| A | 78.39268 |
| B | 5.871533 |
| C | -0.745275 |
| D | 0.018224 |
| E | -1.184867 |
| F | -634.7044 |
| G | 382.3594 |
| H | -607.0984 |
| Reference | Chase, 1998 |
| Comment | Data last reviewed in December, 1978 |
Gas phase ion energetics data
Go To: Top, Gas phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to F3Mo+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.2 ± 0.5 | EI | Alikhanyan, Steblevskii, et al., 1978 | LLK |
| 9.88 ± 0.10 | EI | Hildenbrand, 1976 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| F2Mo+ | 14.3 ± 1.0 | F | EI | Alikhanyan, Steblevskii, et al., 1978 | LLK |
References
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Chase, 1998
Chase, M.W., Jr.,
NIST-JANAF Themochemical Tables, Fourth Edition,
J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]
Alikhanyan, Steblevskii, et al., 1978
Alikhanyan, A.S.; Steblevskii, A.V.; Malkerova, I.P.; Pervov, V.S.; Butskii, V.D.; Gorgoraki, V.I.,
Mass spectrometric study of the sublimation of molybdenum trifluoride,
Russ. J. Inorg. Chem., 1978, 23, 814. [all data]
Hildenbrand, 1976
Hildenbrand, D.L.,
Thermochemical studies of the gaseous lower valent fluorides of molybdenum,
J. Chem. Phys., 1976, 65, 614. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy S°gas,1 bar Entropy of gas at standard conditions (1 bar) ΔfH°gas Enthalpy of formation of gas at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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