1-Decanamine
- Formula: C10H23N
- Molecular weight: 157.2963
- IUPAC Standard InChI: InChI=1S/C10H23N/c1-2-3-4-5-6-7-8-9-10-11/h2-11H2,1H3
- IUPAC Standard InChIKey: MHZGKXUYDGKKIU-UHFFFAOYSA-N
- CAS Registry Number: 2016-57-1
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: n-Decylamine; Decylamine; Decanamine; 1-Aminodecane; 1-Decylamine; n-C10H21NH2; normal-Decylamine; Amine 10; Kemamine P 190D
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Gas phase ion energetics data
Go To: Top, Gas Chromatography, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| Proton affinity (review) | 222.4 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
| Quantity | Value | Units | Method | Reference | Comment |
| Gas basicity | 214.3 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Gas basicity at 298K
| Gas basicity (review) (kcal/mol) | Reference | Comment |
|---|---|---|
| 210.2 ± 2.2 | Gross, Rodriguez-Cruz, et al., 1995 | T = 300K; 3-Fluoropyridine; i-Propylamine. Reference GBs readjusted to Hunter and Lias, 1998. Cited uncertainty is half of the ΔGB between the bracketing bases; MM |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.5 | PE | Aue and Bowers, 1979 | LLK |
| 8.63 ± 0.05 | PI | Iskakov and Potapov, 1971 | LLK |
Gas Chromatography
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Kovats' RI, non-polar column, isothermal
| Column type | Active phase | Temperature (C) | I | Reference | Comment |
|---|---|---|---|---|---|
| Packed | SE-30 | 180. | 1241. | Oszczapowicz, Osek, et al., 1985 | N2, Chromosorb A AW; Column length: 3. m |
Van Den Dool and Kratz RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | SE-54 | 1249. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1252. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1252. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1254. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1254. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1255. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1256. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1256. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1256. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1259. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
| Capillary | SE-54 | 1265. | Woolley, Markides, et al., 1986 | 20. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C |
Van Den Dool and Kratz RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-1 | 1236. | Peng, 2000 | 15. m/0.53 mm/1. μm, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min) |
| Capillary | Methyl Silicone | 1237. | Peng, Yang, et al., 1991 | Program: not specified |
| Packed | SE-30 | 1240. | Peng, Ding, et al., 1988 | Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min) |
Van Den Dool and Kratz RI, polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | HP-Wax | 1517. | Peng, 2000 | 15. m/0.53 mm/1. μm, He, 40. C @ 3. min, 5. K/min, 220. C @ 30. min |
Normal alkane RI, non-polar column, temperature ramp
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Ultra-1 | 1232. | Okumura, 1991 | 25. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 80. C; Tend: 260. C |
Normal alkane RI, non-polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | Solgel-1 (SGE) | 1239. | SGE Co., 2008 | 30. m/0.25 mm/0.25 μm; Program: not specified |
| Capillary | Solgel-1 (SGE) | 1240. | SGE Co., 2008 | 30. m/0.25 mm/0.25 μm; Program: not specified |
| Capillary | Solgel-1 (SGE) | 1241. | SGE Co., 2008 | 30. m/0.25 mm/0.25 μm; Program: not specified |
Normal alkane RI, polar column, custom temperature program
| Column type | Active phase | I | Reference | Comment |
|---|---|---|---|---|
| Capillary | DB-Wax | 1522. | Peng, Yang, et al., 1991, 2 | Program: not specified |
References
Go To: Top, Gas phase ion energetics data, Gas Chromatography, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Gross, Rodriguez-Cruz, et al., 1995
Gross, D.S.; Rodriguez-Cruz, S.E.; Bock, S.; Williams, E.R.,
Measurement of the Coulomb Energy and Dielectric Polarizability of Gas-Phase Diprotonated Diaminoalkanes,
J. Phys. Chem., 1995, 99, 4034. [all data]
Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T.,
Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements
in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]
Iskakov and Potapov, 1971
Iskakov, L.I.; Potapov, V.K.,
Dissociative photoionization of n-alkylamines,
Khim. Vys. Energ., 1971, 5, 534. [all data]
Oszczapowicz, Osek, et al., 1985
Oszczapowicz, J.; Osek, J.; Ciszkowski, K.; Krawczyk, W.; Ostrowski, M.,
Retention Indices of Dimethylbenzamidines and Benzylideneamines on a Non-Polar Column,
J. Chromatogr., 1985, 330, 79-85, https://doi.org/10.1016/S0021-9673(01)81964-6
. [all data]
Woolley, Markides, et al., 1986
Woolley, C.L.; Markides, K.E.; Lee, M.L.; Bartle, K.D.,
Deactivation of small diameter fused silica capillary columns with organosilicon hydrides,
J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 9, 506-514, https://doi.org/10.1002/jhrc.1240090904
. [all data]
Peng, 2000
Peng, C.T.,
Prediction of retention indices. V. Influence of electronic effects and column polarity on retention index,
J. Chromatogr. A, 2000, 903, 1-2, 117-143, https://doi.org/10.1016/S0021-9673(00)00901-8
. [all data]
Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Maltby, D.,
Prediction of retention indexes. III. Silylated derivatives of polar compounds,
J. Chromatogr., 1991, 586, 1, 113-129, https://doi.org/10.1016/0021-9673(91)80029-G
. [all data]
Peng, Ding, et al., 1988
Peng, C.T.; Ding, S.F.; Hua, R.L.; Yang, Z.C.,
Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns,
J. Chromatogr., 1988, 436, 137-172, https://doi.org/10.1016/S0021-9673(00)94575-8
. [all data]
Okumura, 1991
Okumura, T.,
retention indices of environmental chemicals on methyl silicone capillary column,
Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333
. [all data]
SGE Co., 2008
SGE Co.,
The Importance of Low Bleed Columns for GC-MS; Technical Article, The Importance of Low Bleed Columns for GC-MS, SGE Co., 2008, 2, retrieved from http://www.sge-com. [all data]
Peng, Yang, et al., 1991, 2
Peng, C.T.; Yang, Z.C.; Ding, S.F.,
Prediction of rentention idexes. II. Structure-retention index relationship on polar columns,
J. Chromatogr., 1991, 586, 1, 85-112, https://doi.org/10.1016/0021-9673(91)80028-F
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Gas Chromatography, References
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