1-Decanamine

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Gas phase ion energetics data

Go To: Top, Mass spectrum (electron ionization), Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Quantity Value Units Method Reference Comment
Proton affinity (review)930.4kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity896.5kJ/molN/AHunter and Lias, 1998HL

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
879.5 ± 9.2Gross, Rodriguez-Cruz, et al., 1995T = 300K; 3-Fluoropyridine; i-Propylamine. Reference GBs readjusted to Hunter and Lias, 1998. Cited uncertainty is half of the ΔGB between the bracketing bases; MM

Ionization energy determinations

IE (eV) Method Reference Comment
8.5PEAue and Bowers, 1979LLK
8.63 ± 0.05PIIskakov and Potapov, 1971LLK

Mass spectrum (electron ionization)

Go To: Top, Gas phase ion energetics data, Gas Chromatography, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin Japan AIST/NIMC Database- Spectrum MS-NW-3942
NIST MS number 232416

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Gas Chromatography

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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Column type Active phase Temperature (C) I Reference Comment
PackedSE-30180.1241.Oszczapowicz, Osek, et al., 1985N2, Chromosorb A AW; Column length: 3. m

Van Den Dool and Kratz RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillarySE-541249.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541252.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541252.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541254.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541254.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541255.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541256.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541259.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C
CapillarySE-541265.Woolley, Markides, et al., 198620. m/0.05 mm/0.25 μm, He, 40. C @ 2. min, 4. K/min; Tend: 180. C

Van Den Dool and Kratz RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-11236.Peng, 200015. m/0.53 mm/1. μm, He; Program: 40C(3min) => 8C/min => 200(1min) => 5C/min => 300C(25min)
CapillaryMethyl Silicone1237.Peng, Yang, et al., 1991Program: not specified
PackedSE-301240.Peng, Ding, et al., 1988Supelcoport; Chromosorb; Column length: 3.05 m; Program: 40C(5min) => 10C/min => 200C or 250C (60min)

Van Den Dool and Kratz RI, polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryHP-Wax1517.Peng, 200015. m/0.53 mm/1. μm, He, 40. C @ 3. min, 5. K/min, 220. C @ 30. min

Normal alkane RI, non-polar column, temperature ramp

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Column type Active phase I Reference Comment
CapillaryUltra-11232.Okumura, 199125. m/0.32 mm/0.25 μm, He, 3. K/min; Tstart: 80. C; Tend: 260. C

Normal alkane RI, non-polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillarySolgel-1 (SGE)1239.SGE Co., 200830. m/0.25 mm/0.25 μm; Program: not specified
CapillarySolgel-1 (SGE)1240.SGE Co., 200830. m/0.25 mm/0.25 μm; Program: not specified
CapillarySolgel-1 (SGE)1241.SGE Co., 200830. m/0.25 mm/0.25 μm; Program: not specified

Normal alkane RI, polar column, custom temperature program

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Column type Active phase I Reference Comment
CapillaryDB-Wax1522.Peng, Yang, et al., 1991, 2Program: not specified

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Gross, Rodriguez-Cruz, et al., 1995
Gross, D.S.; Rodriguez-Cruz, S.E.; Bock, S.; Williams, E.R., Measurement of the Coulomb Energy and Dielectric Polarizability of Gas-Phase Diprotonated Diaminoalkanes, J. Phys. Chem., 1995, 99, 4034. [all data]

Aue and Bowers, 1979
Aue, D.H.; Bowers, M.T., Chapter 9. Stabilities of positive ions from equilibrium gas phase basicity measurements in Ions Chemistry,, ed. M.T. Bowers, 1979. [all data]

Iskakov and Potapov, 1971
Iskakov, L.I.; Potapov, V.K., Dissociative photoionization of n-alkylamines, Khim. Vys. Energ., 1971, 5, 534. [all data]

Oszczapowicz, Osek, et al., 1985
Oszczapowicz, J.; Osek, J.; Ciszkowski, K.; Krawczyk, W.; Ostrowski, M., Retention Indices of Dimethylbenzamidines and Benzylideneamines on a Non-Polar Column, J. Chromatogr., 1985, 330, 79-85, https://doi.org/10.1016/S0021-9673(01)81964-6 . [all data]

Woolley, Markides, et al., 1986
Woolley, C.L.; Markides, K.E.; Lee, M.L.; Bartle, K.D., Deactivation of small diameter fused silica capillary columns with organosilicon hydrides, J. Hi. Res. Chromatogr. Chromatogr. Comm., 1986, 9, 9, 506-514, https://doi.org/10.1002/jhrc.1240090904 . [all data]

Peng, 2000
Peng, C.T., Prediction of retention indices. V. Influence of electronic effects and column polarity on retention index, J. Chromatogr. A, 2000, 903, 1-2, 117-143, https://doi.org/10.1016/S0021-9673(00)00901-8 . [all data]

Peng, Yang, et al., 1991
Peng, C.T.; Yang, Z.C.; Maltby, D., Prediction of retention indexes. III. Silylated derivatives of polar compounds, J. Chromatogr., 1991, 586, 1, 113-129, https://doi.org/10.1016/0021-9673(91)80029-G . [all data]

Peng, Ding, et al., 1988
Peng, C.T.; Ding, S.F.; Hua, R.L.; Yang, Z.C., Prediction of Retention Indexes I. Structure-Retention Index Relationship on Apolar Columns, J. Chromatogr., 1988, 436, 137-172, https://doi.org/10.1016/S0021-9673(00)94575-8 . [all data]

Okumura, 1991
Okumura, T., retention indices of environmental chemicals on methyl silicone capillary column, Journal of Environmental Chemistry (Japan), 1991, 1, 2, 333-358, https://doi.org/10.5985/jec.1.333 . [all data]

SGE Co., 2008
SGE Co., The Importance of Low Bleed Columns for GC-MS; Technical Article, The Importance of Low Bleed Columns for GC-MS, SGE Co., 2008, 2, retrieved from http://www.sge-com. [all data]

Peng, Yang, et al., 1991, 2
Peng, C.T.; Yang, Z.C.; Ding, S.F., Prediction of rentention idexes. II. Structure-retention index relationship on polar columns, J. Chromatogr., 1991, 586, 1, 85-112, https://doi.org/10.1016/0021-9673(91)80028-F . [all data]


Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Gas Chromatography, References