Zirconium, tetrakis(dimethylamino)-


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfgas-292. ± 19.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1796. ± 15. kJ/mol for the enthalpy of formation of Zr(O-i-Pr)4(cr)

Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δfsolid-363. ± 17.kJ/molReviewMartinho SimõesThe enthalpy of formation relies on -1796. ± 15. kJ/mol for the enthalpy of formation of Zr(O-i-Pr)4(cr)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Quantity Value Units Method Reference Comment
Δsub71.1 ± 8.4kJ/molRSCLappert, Patil, et al., 1975 

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
7.23PEGibbins, Lappert, et al., 1975Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Lappert, Patil, et al., 1975
Lappert, M.F.; Patil, D.S.; Pedley, J.B., J. Chem. Soc., Chem. Commun., 1975, 830.. [all data]

Gibbins, Lappert, et al., 1975
Gibbins, S.G.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J., Bonding studies of transition-metal complexes. Part II. Helium-I photoelectron spectra of homoleptic d0, d1, and d10 tetrakis(dialkylamides) of transition group 4B metals tungsten hexakis(dimethylamide), J. Chem. Soc. Dalton Trans., 1975, 72. [all data]


Notes

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