Scandium,tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-
- Formula: C15H3F18O6Sc
- Molecular weight: 666.1079
- CAS Registry Number: 18990-42-6
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
| ΔsubH (kJ/mol) | Temperature (K) | Method | Reference |
|---|---|---|---|
| 55.0 | 333. to 363. | TGA | Fahlman and Barron, 2000 |
| 60.2 ± 1.2 | 313. to 348. | I | Komissarova, Gurevich, et al., 1978 |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 2.78 ± 0.13 | IMRB | Sharpe, Eyler, et al., 1990 | EA given is actually -ΔGea(350 K). Between fluoranil, Cr(CF3COCHCOCF3)3; B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.43 ± 0.05 | EI | Westmore, Reimer, et al., 1981 | LLK |
| 9.6 ± 0.2 | PE | Westmore, Reimer, et al., 1981 | LLK |
| 10.13 ± 0.07 | PE | Evans, Hamnett, et al., 1972 | Vertical value; LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R.,
Substituent effects on the volatility of metal ?-diketonates,
Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M
. [all data]
Komissarova, Gurevich, et al., 1978
Komissarova, L.N.; Gurevich, M.Z.; Sas, T.S.; Stepin, B.D.,
Zh. Neorg. Khim., 1978, 23, 3145. [all data]
Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E.,
Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis,
Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014
. [all data]
Westmore, Reimer, et al., 1981
Westmore, J.B.; Reimer, M.L.J.; Reichert, C.,
Ionization energies of metal chelates. Acetylacetonates, trifluoroacetylacetonates, and hexafluoroacetylacetonates of trivalent metals of the first transition series,
Can. J. Chem., 1981, 59, 1797. [all data]
Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R.,
Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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