Thiazyl fluoride
- Formula: FNS
- Molecular weight: 65.070
- IUPAC Standard InChI: InChI=1S/C3H2FNS/c4-3-5-1-2-6-3/h1-2H
- IUPAC Standard InChIKey: KQTIMOAWZBAJLH-UHFFFAOYSA-N
- CAS Registry Number: 18820-63-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to FNS+ (ion structure unspecified)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 11.51 ± 0.04 | eV | N/A | N/A | L |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.49 ± 0.02 | PE | Dixon, Duxbury, et al., 1972 | LLK |
| 11.54 ± 0.01 | PE | DeKock, Lloyd, et al., 1972 | LLK |
| 11.36 ± 0.03 | EI | Glemser, Muller, et al., 1968 | RDSH |
| 11.82 | PE | Cowan, Gleiter, et al., 1972 | Vertical value; LLK |
| 11.82 | PE | Cowan, Gleiter, et al., 1971 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FS+ | 15.5 ± 0.1 | N | EI | Glemser, Muller, et al., 1968 | RDSH |
| NS+ | 11.80 ± 0.05 | F | EI | Glemser, Muller, et al., 1968 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dixon, Duxbury, et al., 1972
Dixon, R.N.; Duxbury, G.; Fleming, G.R.; Hugo, J.M.V.,
The photoelectron spectrum of thiazyl fluoride,
Chem. Phys. Lett., 1972, 14, 60. [all data]
DeKock, Lloyd, et al., 1972
DeKock, R.L.; Lloyd, D.R.; Breeze, A.; Collins, G.A.D.; Cruickshank, D.W.J.; Lempka, H.J.,
Photoelectron spectroscopy and ab initio LCAO MO SCF calculations on thiazyl fluoride,
Chem. Phys. Lett., 1972, 14, 525. [all data]
Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B.,
Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien,
Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]
Cowan, Gleiter, et al., 1972
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.,
The photoelectron spectra of NSCl, NSF NSF3,
Helv. Chim. Acta, 1972, 55, 2418. [all data]
Cowan, Gleiter, et al., 1971
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.; Schaublin, J.,
The photoelectron spectrum of thiazyl fluoride (NSF),
Helv. Chim. Acta, 1971, 54, 1559. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.