vinylimine


Gas phase ion energetics data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

View reactions leading to C3H5N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)218.0kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity210.3kcal/molN/AHunter and Lias, 1998 

Vibrational and/or electronic energy levels

Go To: Top, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 4 CH2 s-stretch 2955 gas IR Hamada, Tsuboi, et al., 1984
5 CH stretch 2885 T gas IR Hamada, Tsuboi, et al., 1984
6 C=N stretch 1651 gas IR Hamada, Tsuboi, et al., 1984
7 C=C stretch 1600 gas IR Hamada, Tsuboi, et al., 1984
8 CH2 scissors 1416 T gas IR Hamada, Tsuboi, et al., 1984
9 CH bend 1368 gas IR Hamada, Tsuboi, et al., 1984
10 CH bend 1260 gas IR Hamada, Tsuboi, et al., 1984
11 CNH bend 1251 gas IR Hamada, Tsuboi, et al., 1984
12 CH2 rock 1089 gas IR Hamada, Tsuboi, et al., 1984
13 C-C stretch 855 T gas IR Hamada, Tsuboi, et al., 1984
a 16 C=N torsion 1096 gas IR Hamada, Tsuboi, et al., 1984
17 CH OPLA 991 gas IR Hamada, Tsuboi, et al., 1984
18 CH2 OPLA 979 gas IR Hamada, Tsuboi, et al., 1984
19 CH OPLA 839 gas IR Hamada, Tsuboi, et al., 1984
20 C=C torsion 568 gas IR Hamada, Tsuboi, et al., 1984

Additional references: Jacox, 1994, page 408; Penn, 1978

Notes

TTentative assignment or approximate value

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Hamada, Tsuboi, et al., 1984
Hamada, Y.; Tsuboi, M.; Matsuzawa, T.; Yamanouchi, K.; Kuchitsu, K.; Koga, Y.; Kondo, S., Pyrolysis of amines: Infrared spectrum of allylimine, J. Mol. Spectrosc., 1984, 105, 2, 453, https://doi.org/10.1016/0022-2852(84)90233-9 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Penn, 1978
Penn, R.E., Microwave spectrum of 2-propene-1-imine, CH2«58875»CHCH«58875»NH, J. Mol. Spectrosc., 1978, 69, 3, 373, https://doi.org/10.1016/0022-2852(78)90230-8 . [all data]


Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References