Methyl vinyl sulfide

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Phase change data

Go To: Top, Gas phase ion energetics data, UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil342.7KN/AWeast and Grasselli, 1989BS
Tboil343.15KN/AKatritzky, Pinzelli, et al., 1970Uncertainty assigned by TRC = 2. K; TRC
Tboil339.75KN/APrice and Zomlefer, 1950Uncertainty assigned by TRC = 0.6 K; TRC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Gas phase ion energetics data

Go To: Top, Phase change data, UV/Visible spectrum, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

View reactions leading to C3H6S+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)205.1kcal/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity198.2kcal/molN/AHunter and Lias, 1998HL

Ionization energy determinations

IE (eV) Method Reference Comment
8.45PEMuller, Schafer, et al., 1976Vertical value; LLK
8.44PEPlanckaert, Doucet, et al., 1974Vertical value; LLK
8.45PEBock, Wagner, et al., 1974Vertical value; LLK
8.45PEBock, Wagner, et al., 1972Vertical value; LLK

UV/Visible spectrum

Go To: Top, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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UVVis spectrum
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Additional Data

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Source Price and Zomlefer, 1950
Owner INEP CP RAS, NIST OSRD
Collection (C) 2007 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS
Source reference RAS UV No. 10383
Instrument Beckman quartz spectrophotometer
Boiling point 69.5

References

Go To: Top, Phase change data, Gas phase ion energetics data, UV/Visible spectrum, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Katritzky, Pinzelli, et al., 1970
Katritzky, A.R.; Pinzelli, R.F.; Sinnot, M.V.; Topsom, R.D., Infrared INtensities as a Quantitative Measure of Intramoelcular Inter- actions XV. Monosubstituted Ethylenes, J. Am. Chem. Soc., 1970, 92, 6861. [all data]

Price and Zomlefer, 1950
Price, C.C.; Zomlefer, J., J. Am Chem. Soc., 1950, 72, 14. [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Muller, Schafer, et al., 1976
Muller, C.; Schafer, W.; Schweig, A.; Thon, N.; Vermeer, H., Detection of rotational isomers by variable temperature photoelectron spectroscopy. A new technique in the realm of molecular conformational analysis, J. Am. Chem. Soc., 1976, 98, 5440. [all data]

Planckaert, Doucet, et al., 1974
Planckaert, A.A.; Doucet, J.; Sandorfy, C., Comparative study of the vacuum ultraviolet absorption and photoelectron spectra of some simple ethers and thioethers, J. Chem. Phys., 1974, 60, 4846. [all data]

Bock, Wagner, et al., 1974
Bock, H.; Wagner, G.; Wittel, K.; Sauer, J.; Seebach, D., Photoelektronenspektren und molekuleigenschaften. XXXII. n/π-konjugation in heterosubstituierten athylenen, Chem. Ber., 1974, 107, 1869. [all data]

Bock, Wagner, et al., 1972
Bock, H.; Wagner, G.; Kroner, J., Photoelektronenspektren und molekuleigenschaften, XIV. Die delokalisation des schwefel-elektronenpaar in CH3S-substituierten aromaten, Chem. Ber., 1972, 105, 3850. [all data]


Notes

Go To: Top, Phase change data, Gas phase ion energetics data, UV/Visible spectrum, References