Methyl vinyl sulfide
- Formula: C3H6S
- Molecular weight: 74.145
- IUPAC Standard InChIKey: AMBKPYJJYUKNFI-UHFFFAOYSA-N
- CAS Registry Number: 1822-74-8
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C3H6S+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Proton affinity (review) | 205.1 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 198.2 | kcal/mol | N/A | Hunter and Lias, 1998 | HL |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.45 | PE | Muller, Schafer, et al., 1976 | Vertical value; LLK |
8.44 | PE | Planckaert, Doucet, et al., 1974 | Vertical value; LLK |
8.45 | PE | Bock, Wagner, et al., 1974 | Vertical value; LLK |
8.45 | PE | Bock, Wagner, et al., 1972 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G.,
Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update,
J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018
. [all data]
Muller, Schafer, et al., 1976
Muller, C.; Schafer, W.; Schweig, A.; Thon, N.; Vermeer, H.,
Detection of rotational isomers by variable temperature photoelectron spectroscopy. A new technique in the realm of molecular conformational analysis,
J. Am. Chem. Soc., 1976, 98, 5440. [all data]
Planckaert, Doucet, et al., 1974
Planckaert, A.A.; Doucet, J.; Sandorfy, C.,
Comparative study of the vacuum ultraviolet absorption and photoelectron spectra of some simple ethers and thioethers,
J. Chem. Phys., 1974, 60, 4846. [all data]
Bock, Wagner, et al., 1974
Bock, H.; Wagner, G.; Wittel, K.; Sauer, J.; Seebach, D.,
Photoelektronenspektren und molekuleigenschaften. XXXII. n/π-konjugation in heterosubstituierten athylenen,
Chem. Ber., 1974, 107, 1869. [all data]
Bock, Wagner, et al., 1972
Bock, H.; Wagner, G.; Kroner, J.,
Photoelektronenspektren und molekuleigenschaften, XIV. Die delokalisation des schwefel-elektronenpaar in CH3S-substituierten aromaten,
Chem. Ber., 1972, 105, 3850. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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