(CH3)2NCH2Si(CH3)3

• Formula: C₆H₁₇NSi
• Molecular weight: 131.2914
• IUPAC Standard InChI: InChI=1S/C6H17NSi/c1-7(2)6-8(3,4)5/h6H2,1-5H3 Copy

  
• IUPAC Standard InChIKey: OUSBZHYDUVVKHE-UHFFFAOYSA-N Copy
• CAS Registry Number: 18182-40-6
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Dimethyl(trimethylsilylmethyl)amine; N,N-Dimethylamino(trimethylsilyl)methane
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Loguinov, Takhistov, et al., 1981
Loguinov, Y.; Takhistov, V.V.; Vatlina, L.P., Photoionization studies of substituted trimethylamines, Org. Mass Spectrom., 1981, 16, 239. [all data]

Akopyan, Vilesov, et al., 1975
Akopyan, M.E.; Vilesov, F.I.; Loginov, Y.V., Photoionization of amines and the monomolecular decomposition of excited molecular ions, Khim. Vys. Energ., 1975, 9, 327. [all data]

Akopyan and Loginov, 1974
Akopyan, M.E.; Loginov, Yu.V., Photoelectron spectra of trimethylamine derivatives, Opt. Spectrosc., 1974, 37, 250, In original 442. [all data]

Bock, Kaim, et al., 1979
Bock, H.; Kaim, W.; Kira, M.; Osawa, H.; Sakurai, H., Radical ions XXVIII. Tris(trimethylsilylmethyl)aminium, ⁺N(CH₂Si(CH₃)₃)₃: A stable fluxional aminium radical cation, J. Organomet. Chem., 1979, 164, 295. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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