tert-Butyltrichlorosilane
- Formula: C4H9Cl3Si
- Molecular weight: 191.559
- IUPAC Standard InChI: InChI=1S/C4H9Cl3Si/c1-4(2,3)8(5,6)7/h1-3H3
- IUPAC Standard InChIKey: MOOUPSHQAMJMSL-UHFFFAOYSA-N
- CAS Registry Number: 18171-74-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: t-Butyltrichlorosilane; Silane, trichloro(1,1-dimethylethyl)-; Silane, tert-butyltrichloro-; tert-Butylsilicon trichloride
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C4H9+ | 10.7 ± 0.1 | SiCl3 | EI | Potzinger, Ritter, et al., 1975 | LLK |
| C4H9+ | 10.7 ± 0.1 | ? | EI | Steele, Nichols, et al., 1962 | RDSH |
| SiCl3+ | 13.0 ± 0.1 | ? | EI | Steele, Nichols, et al., 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J.,
Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen,
Z. Naturforsch. A:, 1975, 30, 347. [all data]
Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A.,
The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact,
J. Am. Chem. Soc., 1962, 84, 4441. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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