tert-Butyltrichlorosilane

• Formula: C₄H₉Cl₃Si
• Molecular weight: 191.559
• IUPAC Standard InChI: InChI=1S/C4H9Cl3Si/c1-4(2,3)8(5,6)7/h1-3H3 Copy

  
• IUPAC Standard InChIKey: MOOUPSHQAMJMSL-UHFFFAOYSA-N Copy
• CAS Registry Number: 18171-74-9
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: t-Butyltrichlorosilane; Silane, trichloro(1,1-dimethylethyl)-; Silane, tert-butyltrichloro-; tert-Butylsilicon trichloride
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of fusion

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Bräuninger, Dou, et al., 2010
Bräuninger, Sigmar; Dou, Shi-Qi; Fuess, Hartmut; Schmahl, Wolfgang; Strauß, Roman; Weiss, Alarich, Orientational disorder in solids composed of the ellipsoid-shaped molecules trichloromethyltrimethylsilane, Cl3CSi(CH3)3, t-Butyltrichlorosilane, (CH3)3CSiCl3, and t-Butyldimethylchlorosilane, (CH3)3CSi(CH3)2Cl, Berichte der Bunsengesellschaft für physikalische Chemie, 2010, 98, 8, 1096-1099, https://doi.org/10.1002/bbpc.19940980817 . [all data]

Potzinger, Ritter, et al., 1975
Potzinger, P.; Ritter, A.; Krause, J., Massenspektrometrische Bestimmung von Bindungsenergien in siliciumorganischen Verbindungen, Z. Naturforsch. A:, 1975, 30, 347. [all data]

Steele, Nichols, et al., 1962
Steele, W.C.; Nichols, L.D.; Stone, F.G.A., The determination of silicon-carbon and silicon-hydrogen bond dissociation energies by electron impact, J. Am. Chem. Soc., 1962, 84, 4441. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔfusH	Enthalpy of fusion

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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