H3S+

• Formula: H₃S⁺
• Molecular weight: 35.088
• CAS Registry Number: 18155-21-0
• Information on this page:
  • Reaction thermochemistry data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Ion clustering data
• Options:
  • Switch to SI units

Reaction thermochemistry data

Go To: Top, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

H₃S⁺ +  = (H₃S⁺ • )

By formula: H₃S⁺ + H₂S = (H₃S⁺ • H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • 3) +  = (H₃S⁺ • 4)

By formula: (H₃S⁺ • 3H₂S) + H₂S = (H₃S⁺ • 4H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • 2) +  = (H₃S⁺ • 3)

By formula: (H₃S⁺ • 2H₂S) + H₂S = (H₃S⁺ • 3H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • ) +  = (H₃S⁺ •  • )

By formula: (H₃S⁺ • H₂S) + H₂O = (H₃S⁺ • H₂O • H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • ) +  = (H₃S⁺ • 2)

By formula: (H₃S⁺ • H₂S) + H₂S = (H₃S⁺ • 2H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • ) +  = (H₃S⁺ • 2)

By formula: (H₃S⁺ • H₂O) + H₂O = (H₃S⁺ • 2H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

H₃S⁺ +  = (H₃S⁺ • )

By formula: H₃S⁺ + H₂O = (H₃S⁺ • H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

(H₃S⁺ • 4) +  = (H₃S⁺ • 5)

By formula: (H₃S⁺ • 4H₂S) + H₂S = (H₃S⁺ • 5H₂S)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

H₃S⁺ +  = (H₃S⁺ • )

By formula: H₃S⁺ + CH₄ = (H₃S⁺ • CH₄)

(H₃S⁺ • 2) +  = (H₃S⁺ • 3)

By formula: (H₃S⁺ • 2H₂O) + H₂O = (H₃S⁺ • 3H₂O)

Bond type: Hydrogen bond (positive ion to hydride)

Vibrational and/or electronic energy levels

Go To: Top, Reaction thermochemistry data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X

Additional references: Jacox, 1994, page 130; Jacox, 1998, page 217; Jacox, 2003, page 160; Lee, Ozeki, et al., 1994; Xia, Sanz, et al., 1998; Araki, Ozeki, et al., 1998; Dore, Degli Esposti, et al., 1999

References

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hiraoka and Kebarle, 1977
Hiraoka, K.; Kebarle, P., Gas Phase Ion Equilibria Studies of the Proton in Hydrogen Sulfide and Hydrogen Sulfide - Water Mixtures. Stabilities of the Hydrogen Bonded Complexes H+(H2S)x(H2O)y, Can. J. Chem., 1977, 55, 1, 24, https://doi.org/10.1139/v77-005 . [all data]

Walters and Blais, 1984
Walters, E.A.; Blais, N.C., Molecular beam photoionization and fragmentation of D₂S, (H₂S)₂, (D₂S)₂, and H₂S.H₂O, J. Chem. Phys., 1984, 80, 3501. [all data]

Prest, Tzeng, et al., 1983
Prest, H.F.; Tzeng, W.-B.; Brom, J.M., Jr.; Ng, C.Y., Photoionization study of (H₂S)₂ and (H₂S)₃, J. Am. Chem. Soc., 1983, 105, 7531. [all data]

Meot-Ner (Mautner) and Field, 1977
Meot-Ner (Mautner), M.; Field, F.H., Stability, Association and Dissociation in the Cluster Ions H3S+.nH2S, H3O+.nH2O and H3O+.H2O, J. Am. Chem. Soc., 1977, 99, 4, 998, https://doi.org/10.1021/ja00446a004 . [all data]

Cunningham, Payzant, et al., 1972
Cunningham, A.J.; Payzant, J.D.; Kebarle, P., A Kinetic Study of the Proton Hydrate H+(H2O)n Equilibria in the Gas Phase, J. Am. Chem. Soc., 1972, 94, 22, 7627, https://doi.org/10.1021/ja00777a003 . [all data]

Lias, Liebman, et al., 1984
Lias, S.G.; Liebman, J.F.; Levin, R.D., Evaluated gas phase basicities and proton affinities of molecules heats of formation of protonated molecules, J. Phys. Chem. Ref. Data, 1984, 13, 695. [all data]

Yamdagni and Kebarle, 1976
Yamdagni, R.; Kebarle, P., Gas Phase Basicities and Proton Affinities of Compounds Between Water Ammonia and Substituted Benzenes from a Continuous Ladder of Proton Transfer Equilibrium Measurements, J. Am. Chem. Soc., 1976, 98, 6, 1320, https://doi.org/10.1021/ja00422a005 . [all data]

Bennet and Field, 1972
Bennet, S.L.; Field, F.H., Reversible Reactions of Gaseous Ions. VI. The NH3 - CH4, H2S - CH4 and CF4 - CH4 Systems at Low Temperatures, J. Am. Chem. Soc., 1972, 94, 18, 6305, https://doi.org/10.1021/ja00773a009 . [all data]

Nakanaga and Amano, 1989
Nakanaga, T.; Amano, T., Difference frequency laser spectroscopy of SH3+: A simultaneous analysis of the ν1 and ν3 fundamental bands, J. Mol. Spectrosc., 1989, 133, 1, 201, https://doi.org/10.1016/0022-2852(89)90254-3 . [all data]

Amano, Kawaguchi, et al., 1987
Amano, T.; Kawaguchi, K.; Hirota, E., Infrared diode laser spectroscopy of the ν2 fundamental band of SH3+, J. Mol. Spectrosc., 1987, 126, 1, 177, https://doi.org/10.1016/0022-2852(87)90088-9 . [all data]

Nakanaga and Amano, 1987
Nakanaga, T.; Amano, T., The observation of the high-resolution infrared spectrum of SH+3, Chem. Phys. Lett., 1987, 134, 2, 195, https://doi.org/10.1016/0009-2614(87)87120-8 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Lee, Ozeki, et al., 1994
Lee, S.K.; Ozeki, H.; Saito, S.; Yamamoto, S., Submillimeter wave spectrum of the SH+3 ion. J = 2-1, K = 0 and 1 transitions, Chem. Phys. Lett., 1994, 224, 1-2, 21, https://doi.org/10.1016/0009-2614(94)00519-2 . [all data]

Xia, Sanz, et al., 1998
Xia, C.; Sanz, M.M.; Foster, S.C., Diode Laser Spectroscopy of the ν1and ν3Bands of SD+3, J. Mol. Spectrosc., 1998, 188, 2, 175, https://doi.org/10.1006/jmsp.1997.7513 . [all data]

Araki, Ozeki, et al., 1998
Araki, M.; Ozeki, H.; Saito, S., Microwave Spectrum of the SD+3Ion: Molecular Structure, J. Mol. Spectrosc., 1998, 192, 1, 228, https://doi.org/10.1006/jmsp.1998.7691 . [all data]

Dore, Degli Esposti, et al., 1999
Dore, L.; Degli Esposti, C.; Mazzavillani, A.; Cazzoli, G., Pure rotational spectra of and, Chem. Phys. Lett., 1999, 300, 3-4, 489, https://doi.org/10.1016/S0009-2614(98)01403-1 . [all data]

Notes

Go To: Top, Reaction thermochemistry data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  T	Temperature
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions
  ΔrS°	Entropy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.