Methanimidamide, N,N-dimethyl-N'-phenyl-

• Formula: C₉H₁₂N₂
• Molecular weight: 148.2050
• IUPAC Standard InChI: InChI=1S/C9H12N2/c1-11(2)8-10-9-6-4-3-5-7-9/h3-8H,1-2H3 Copy

  
• IUPAC Standard InChIKey: SRPCLECGIYMIMN-UHFFFAOYSA-N Copy
• CAS Registry Number: 1783-25-1
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Stereoisomers:
  • (CH3)2N-CH=N-phenyl
• Other names: Formamidine, N,N-dimethyl-N'-phenyl-; N,N-Dimethyl-N'-phenylformamidine; N'-Phenyl-N,N-dimethylformamidine; Formamidine, 3,3-dimethyl-1-phenyl; N1N1-dimethyl-N2-phenylformamidine
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• Information on this page:
  • Gas phase ion energetics data
  • IR Spectrum
  • Mass spectrum (electron ionization)
  • UV/Visible spectrum
  • Gas Chromatography
  • References
  • Notes
• Other data available:
  • Phase change data
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Appearance energy determinations

IR Spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Gas Phase Spectrum

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Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.

Additional Data

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

UV/Visible spectrum

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Victor Talrose, Alexander N. Yermakov, Alexy A. Usov, Antonina A. Goncharova, Axlexander N. Leskin, Natalia A. Messineva, Natalia V. Trusova, Margarita V. Efimkina

Spectrum

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Additional Data

Gas Chromatography

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Kovats' RI, non-polar column, isothermal

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References

Go To: Top, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), UV/Visible spectrum, Gas Chromatography, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kuschel and Grutzmacher, 1974
Kuschel, H.; Grutzmacher, H.-F., Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XIII. Einfluβ der dissoziationsenergie auf intramolekulare aromatische substitutionen in den molekul- ionen von N,N-dimethyl- N'-phenylformamidinen, Org. Mass Spectrom., 1974, 9, 408. [all data]

Kuschel and Grutzmacher, 1974, 2
Kuschel, H.; Grutzmacher, H.-F., Zum mechanismus massenspektrometrischer fragmentierungsreaktionen. XI. EinfluB von substituenten auf die bildung cyclischer fragment-ionen in den massenspektren von N,N-dimethyl-N'-2-chlorphenylformamidinen und 2-chlorformaniliden, Org. Mass Spectrom., 1974, 9, 395. [all data]

Kiro and Stepanov, 1972
Kiro, Z.B.; Stepanov, B.I., Zhur. Organ Khim. (Eng. Trans.), 1972, 8, 2448. [all data]

Dolecka, Raczynska, et al., 1988
Dolecka, E.; Raczynska, E.D.; Drapala, T., Retention indices and basicity of N¹N¹-dimethyl-N²-phenylformamidines ortho-substituent effect, J. Chem. Soc. Perkin Trans. 2:, 1988, 3, 257-260, https://doi.org/10.1039/p29880000257 . [all data]

Osek, Oszczapowicz, et al., 1986
Osek, J.; Oszczapowicz, J.; Drzewinski, W., Prediction of Retention Indices of N¹,N¹-Dialkylformamidines on a Non-Polar Column, J. Chromatogr., 1986, 351, 177-182, https://doi.org/10.1016/S0021-9673(01)83486-5 . [all data]

Oszczapowicz, Osek, et al., 1984
Oszczapowicz, J.; Osek, J.; Dolecka, E., Retention indices of dimethylformamidines, dimethylacetamidines and tetramethylguanidines on a non-polar column, J. Chromatogr., 1984, 315, 95-100, https://doi.org/10.1016/S0021-9673(01)90727-7 . [all data]

Notes

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• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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