Decaborane(14)
- Formula: B10H14
- Molecular weight: 122.221
- IUPAC Standard InChI: InChI=1S/B10H14/c11-5-1-2-3(1,5)7(2,9(3,5,11)13-7)8(2)4(1,2)6(1,5)10(4,8,12-6)14-8/h1-10H
- IUPAC Standard InChIKey: XAMMYYSPUSIWAS-UHFFFAOYSA-N
- CAS Registry Number: 17702-41-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Boron hydride (B10H14); Decaborane; Boron hydride; Decaborane (B10H14); Tetradecahydrodecaborane; B10H14; nido-Decaborane(14)
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 9.88 ± 0.03 | PE | Lloyd, Lynaugh, et al., 1975 | LLK |
| 10.3 ± 0.5 | EI | Kaufman, Koski, et al., 1962 | RDSH |
| 11.0 ± 0.5 | EI | Margrave, 1960 | RDSH |
| 10.15 | PE | Roberts, 1974 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| Bl0H7+ | 12.5 ± 0.5 | 3H2+H | EI | Kaufman, Koski, et al., 1962 | RDSH |
| B10H6+ | 13.1 ± 0.3 | 4H2 | EI | Kaufman, Koski, et al., 1962 | RDSH |
| B10H8+ | 12.7 ± 0.3 | 3H2 | EI | Kaufman, Koski, et al., 1962 | RDSH |
| B10H10+ | 11.6 ± 0.2 | 2H2 | EI | Kaufman, Koski, et al., 1962 | RDSH |
| B10H11+ | 10.8 ± 0.5 | H2+H | EI | Kaufman, Koski, et al., 1962 | RDSH |
| B10H12+ | 10.9 ± 0.2 | H2 | EI | Kaufman, Koski, et al., 1962 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Lloyd, Lynaugh, et al., 1975
Lloyd, D.R.; Lynaugh, N.; Roberts, P.J.; Guest, M.F.,
Photoelectron studies of boron and compounds, Part 5. -Higher boron hydrides B4H10, B5H9, B10H14,
J. Chem. Soc. Faraday Trans. 2, 1975, 71, 1382. [all data]
Kaufman, Koski, et al., 1962
Kaufman, J.J.; Koski, W.S.; Kuhns, L.J.; Law, R.W.,
Appearance and ionization potentials of selected fragments from decaborane, 11B10H14,
J. Am. Chem. Soc., 1962, 84, 4198. [all data]
Margrave, 1960
Margrave, J.L.,
Ionization potentials of B5H9, B5H8I, B10H14, and B10H13C2H5 from electron impact studies,
J. Chem. Phys., 1960, 32, 1889. [all data]
Roberts, 1974
Roberts, P.,
Title unavailable, Thesis, University of Birmingham, 1974. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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