di-μ-carbonyldecacarbonyl-triangulo-triiron
- Formula: C12Fe3O12
- Molecular weight: 503.656
- CAS Registry Number: 17685-52-8
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Reaction thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
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Individual Reactions
C12Fe3O12 (cr) = 12 (g) + 3
(cr)
By formula: C12Fe3O12 (cr) = 12CO (g) + 3Fe (cr)
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 123.2 ± 2.8 | kcal/mol | TD-HFC | Connor, Skinner, et al., 1973 | |
| ΔrH° | 125.7 ± 3.0 | kcal/mol | HAL-HFC | Connor, Skinner, et al., 1973 |
Gas phase ion energetics data
Go To: Top, Reaction thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.44 | PE | DeKock, Wong, et al., 1982 | LBLHLM |
| 7.8 | PE | Wong, Dutta, et al., 1981 | LLK |
References
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Connor, Skinner, et al., 1973
Connor, J.A.; Skinner, H.A.; Virmani, Y.,
High temperature microcalorimetric studies of the thermal decomposition and iodination of polynuclear carbonyls of Fe, Co, Ru, Rh, Re, Os and Ir,
Faraday Symp. Chem. Soc., 1973, 8, 18, https://doi.org/10.1039/fs9730800018
. [all data]
DeKock, Wong, et al., 1982
DeKock, R.L.; Wong, K.S.; Fehlner, T.P.,
Effects of bridging hydrogens on metal-netal bonds. 2. UV photoelectron and UV-visible spectra and quantum chemical calculations for Fe3(μ-H)3(CO)9(μ3-CCH3) and Co3(CO)9(μ3-CCH3),
Inorg. Chem., 1982, 21, 3203. [all data]
Wong, Dutta, et al., 1981
Wong, K.S.; Dutta, T.L.; Fehlner, T.P.,
The proton as a probe of cluster bonding. The UV photoelectron spectra of two hydrido transition metal clusters,
J. Organomet. Chem., 1981, 215, 48. [all data]
Notes
Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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