Germane, ethyl-
- Formula: C2H8Ge
- Molecular weight: 104.72
- IUPAC Standard InChI: InChI=1S/C2H8Ge/c1-2-3/h2H2,1,3H3
- IUPAC Standard InChIKey: SHRMMCOTNQGWJS-UHFFFAOYSA-N
- CAS Registry Number: 1747-99-5
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.4 | PE | Beltram, Fehlner, et al., 1980 | Vertical value; LLK |
De-protonation reactions
C2H7Ge- + =
By formula: C2H7Ge- + H+ = C2H8Ge
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔrH° | 1532. ± 12. | kJ/mol | G+TS | Gal, Decouzon, et al., 2001 | gas phase; B |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔrG° | 1500. ± 11. | kJ/mol | IMRE | Gal, Decouzon, et al., 2001 | gas phase; B |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K.,
UV photoelectron spectra of group IV alkyl hydrides,
J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]
Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C.,
Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes,
J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j
. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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