Germane, ethyl-


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Individual Reactions

C2H7Ge- + Hydrogen cation = Germane, ethyl-

By formula: C2H7Ge- + H+ = C2H8Ge

Quantity Value Units Method Reference Comment
Δr1532. ± 12.kJ/molG+TSGal, Decouzon, et al., 2001gas phase
Quantity Value Units Method Reference Comment
Δr1500. ± 11.kJ/molIMREGal, Decouzon, et al., 2001gas phase

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.4PEBeltram, Fehlner, et al., 1980Vertical value; LLK

De-protonation reactions

C2H7Ge- + Hydrogen cation = Germane, ethyl-

By formula: C2H7Ge- + H+ = C2H8Ge

Quantity Value Units Method Reference Comment
Δr1532. ± 12.kJ/molG+TSGal, Decouzon, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr1500. ± 11.kJ/molIMREGal, Decouzon, et al., 2001gas phase; B

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Mass spectrum
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Additional Data

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Owner NIST Mass Spectrometry Data Center
Collection (C) 2014 copyright by the U.S. Secretary of Commerce
on behalf of the United States of America. All rights reserved.
Origin J.W.PINSON UNIV. OF S. MISSISSIPPI, HATTIESBURG, MISS., USA
NIST MS number 67217

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References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Gal, Decouzon, et al., 2001
Gal, J.F.; Decouzon, M.; Maria, P.C.; Gonzalez, A.I.; Mo, O.; Yanez, M.; El Chaouch, S.; Guillemin, J.C., Acidity trends in alpha,beta-unsaturated alkanes, silanes, germanes, and stannanes, J. Am. Chem. Soc., 2001, 123, 26, 6353-6359, https://doi.org/10.1021/ja004079j . [all data]

Beltram, Fehlner, et al., 1980
Beltram, G.; Fehlner, T.P.; Mochida, K.; Kochi, J.K., UV photoelectron spectra of group IV alkyl hydrides, J. Electron Spectrosc. Relat. Phenom., 1980, 18, 153. [all data]


Notes

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