Lithium ion (1+)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RCD - Robert C. Dunbar
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Lithium ion (1+) + Argon = (Lithium ion (1+) bullet Argon)

By formula: Li+ + Ar = (Li+ bullet Ar)

Quantity Value Units Method Reference Comment
DeltarH°30. ± 4.kJ/molAVGN/AAverage of 4 out of 6 values; Individual data points
Quantity Value Units Method Reference Comment
DeltarS°30.J/mol*KDTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
5.9294.IMobCassidy and Elford, 1985gas phase; M
7.9319.DTKeller, Beyer, et al., 1973gas phase; LOW E/N; M
11.215.DTMcKnight and Sawina, 1973gas phase; «DELTA»rS approximate; M

Lithium ion (1+) + Hydrogen cyanide = (Lithium ion (1+) bullet Hydrogen cyanide)

By formula: Li+ + CHN = (Li+ bullet CHN)

Quantity Value Units Method Reference Comment
DeltarH°152.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
DeltarH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°100.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarG°120.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylene chloride = (Lithium ion (1+) bullet Methylene chloride)

By formula: Li+ + CH2Cl2 = (Li+ bullet CH2Cl2)

Quantity Value Units Method Reference Comment
DeltarH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Difluoromethane = (Lithium ion (1+) bullet Difluoromethane)

By formula: Li+ + CH2F2 = (Li+ bullet CH2F2)

Quantity Value Units Method Reference Comment
DeltarH°111.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 2H-Tetrazole = (Lithium ion (1+) bullet 2H-Tetrazole)

By formula: Li+ + CH2N4 = (Li+ bullet CH2N4)

Quantity Value Units Method Reference Comment
DeltarH°151. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Formaldehyde = (Lithium ion (1+) bullet Formaldehyde)

By formula: Li+ + CH2O = (Li+ bullet CH2O)

Quantity Value Units Method Reference Comment
DeltarH°151.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
DeltarH°150.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarG°118.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Chloromethane = (Lithium ion (1+) bullet Chloromethane)

By formula: Li+ + CH3Cl = (Li+ bullet CH3Cl)

Quantity Value Units Method Reference Comment
DeltarH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methyl fluoride = (Lithium ion (1+) bullet Methyl fluoride)

By formula: Li+ + CH3F = (Li+ bullet CH3F)

Quantity Value Units Method Reference Comment
DeltarH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Formamide = (Lithium ion (1+) bullet Formamide)

By formula: Li+ + CH3NO = (Li+ bullet CH3NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
157.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Methane, nitro- = (Lithium ion (1+) bullet Methane, nitro-)

By formula: Li+ + CH3NO2 = (Li+ bullet CH3NO2)

Quantity Value Units Method Reference Comment
DeltarH°165.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M

Lithium ion (1+) + Methyl Alcohol = (Lithium ion (1+) bullet Methyl Alcohol)

By formula: Li+ + CH4O = (Li+ bullet CH4O)

Quantity Value Units Method Reference Comment
DeltarH°154. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
DeltarH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarG°127.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Methylamine = (Lithium ion (1+) bullet Methylamine)

By formula: Li+ + CH5N = (Li+ bullet CH5N)

Quantity Value Units Method Reference Comment
DeltarH°172.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarG°139.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Carbon monoxide = (Lithium ion (1+) bullet Carbon monoxide)

By formula: Li+ + CO = (Li+ bullet CO)

Quantity Value Units Method Reference Comment
DeltarH°55. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°55. ± 12.kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 2Carbon monoxide)

By formula: (Li+ bullet CO) + CO = (Li+ bullet 2CO)

Quantity Value Units Method Reference Comment
DeltarH°36. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°36. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

(Lithium ion (1+) bullet 2Carbon monoxide) + Carbon monoxide = (Lithium ion (1+) bullet 3Carbon monoxide)

By formula: (Li+ bullet 2CO) + CO = (Li+ bullet 3CO)

Quantity Value Units Method Reference Comment
DeltarH°35. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°35. ± 4.2kJ/molCIDTWalter, Sievers, et al., 1998RCD

Lithium ion (1+) + Acetonitrile = (Lithium ion (1+) bullet Acetonitrile)

By formula: Li+ + C2H3N = (Li+ bullet C2H3N)

Quantity Value Units Method Reference Comment
DeltarH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + C2H3N3 = (Lithium ion (1+) bullet C2H3N3)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
DeltarH°136. ± 7.1kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1H-1,2,4-Triazole = (Lithium ion (1+) bullet 1H-1,2,4-Triazole)

By formula: Li+ + C2H3N3 = (Li+ bullet C2H3N3)

Quantity Value Units Method Reference Comment
DeltarH°191. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Acetaldehyde = (Lithium ion (1+) bullet Acetaldehyde)

By formula: Li+ + C2H4O = (Li+ bullet C2H4O)

Quantity Value Units Method Reference Comment
DeltarH°173.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, Keesee and Castleman, 1986 from Berman and Beauchamp, 1986; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + Acetic acid = (Lithium ion (1+) bullet Acetic acid)

By formula: Li+ + C2H4O2 = (Li+ bullet C2H4O2)

Quantity Value Units Method Reference Comment
DeltarH°174.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 interpolated; M

Lithium ion (1+) + 1,3,2-Dioxathiolane, 2-oxide = (Lithium ion (1+) bullet 1,3,2-Dioxathiolane, 2-oxide)

By formula: Li+ + C2H4O3S = (Li+ bullet C2H4O3S)

Quantity Value Units Method Reference Comment
DeltarH°199.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Ethane, fluoro- = (Lithium ion (1+) bullet Ethane, fluoro-)

By formula: Li+ + C2H5F = (Li+ bullet C2H5F)

Quantity Value Units Method Reference Comment
DeltarH°140.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N-methyl- = (Lithium ion (1+) bullet Formamide, N-methyl-)

By formula: Li+ + C2H5NO = (Li+ bullet C2H5NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
166.373.CIDCHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Ethanol = (Lithium ion (1+) bullet Ethanol)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°164. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Dimethyl ether = (Lithium ion (1+) bullet Dimethyl ether)

By formula: Li+ + C2H6O = (Li+ bullet C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°165. ± 11.kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°165.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
DeltarH°160.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarG°131.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
165. (+10.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 2Dimethyl ether)

By formula: (Li+ bullet C2H6O) + C2H6O = (Li+ bullet 2C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°121. ± 5.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
130. (+4.,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 2Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 3Dimethyl ether)

By formula: (Li+ bullet 2C2H6O) + C2H6O = (Li+ bullet 3C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°89.1 ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
110. (+5.9,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

(Lithium ion (1+) bullet 3Dimethyl ether) + Dimethyl ether = (Lithium ion (1+) bullet 4Dimethyl ether)

By formula: (Li+ bullet 3C2H6O) + C2H6O = (Li+ bullet 4C2H6O)

Quantity Value Units Method Reference Comment
DeltarH°68. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
95.4 (+6.7,-0.) CIDMore, Gledening, et al., 1996gas phase; guided ion beam CID; M

Lithium ion (1+) + Dimethyl sulfone = (Lithium ion (1+) bullet Dimethyl sulfone)

By formula: Li+ + C2H6O2S = (Li+ bullet C2H6O2S)

Quantity Value Units Method Reference Comment
DeltarH°203.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Dimethyl sulfide = (Lithium ion (1+) bullet Dimethyl sulfide)

By formula: Li+ + C2H6S = (Li+ bullet C2H6S)

Quantity Value Units Method Reference Comment
DeltarH°137.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Dimethylamine = (Lithium ion (1+) bullet Dimethylamine)

By formula: Li+ + C2H7N = (Li+ bullet C2H7N)

Quantity Value Units Method Reference Comment
DeltarH°177.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°110.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarG°143.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1,3,5-Triazine = (Lithium ion (1+) bullet 1,3,5-Triazine)

By formula: Li+ + C3H3N3 = (Li+ bullet C3H3N3)

Quantity Value Units Method Reference Comment
DeltarH°127. ± 13.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + 1H-Pyrazole = (Lithium ion (1+) bullet 1H-Pyrazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
DeltarH°187. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole = (Lithium ion (1+) bullet 1H-Imidazole)

By formula: Li+ + C3H4N2 = (Li+ bullet C3H4N2)

Quantity Value Units Method Reference Comment
DeltarH°211. ± 9.6kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Propyne = (Lithium ion (1+) bullet Propyne)

By formula: Li+ + C3H4 = (Li+ bullet C3H4)

Quantity Value Units Method Reference Comment
DeltarH°119.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetone = (Lithium ion (1+) bullet Acetone)

By formula: Li+ + C3H6O = (Li+ bullet C3H6O)

Quantity Value Units Method Reference Comment
DeltarH°186.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetic acid, methyl ester = (Lithium ion (1+) bullet Acetic acid, methyl ester)

By formula: Li+ + C3H6O2 = (Li+ bullet C3H6O2)

Quantity Value Units Method Reference Comment
DeltarH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propene = (Lithium ion (1+) bullet Propene)

By formula: Li+ + C3H6 = (Li+ bullet C3H6)

Quantity Value Units Method Reference Comment
DeltarH°96.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-bromo- = (Lithium ion (1+) bullet Propane, 2-bromo-)

By formula: Li+ + C3H7Br = (Li+ bullet C3H7Br)

Quantity Value Units Method Reference Comment
DeltarH°128.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-chloro- = (Lithium ion (1+) bullet Propane, 2-chloro-)

By formula: Li+ + C3H7Cl = (Li+ bullet C3H7Cl)

Quantity Value Units Method Reference Comment
DeltarH°130.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-fluoro- = (Lithium ion (1+) bullet Propane, 2-fluoro-)

By formula: Li+ + C3H7F = (Li+ bullet C3H7F)

Quantity Value Units Method Reference Comment
DeltarH°149.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Propane, 2-iodo- = (Lithium ion (1+) bullet Propane, 2-iodo-)

By formula: Li+ + C3H7I = (Li+ bullet C3H7I)

Quantity Value Units Method Reference Comment
DeltarH°123.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Formamide, N,N-dimethyl- = (Lithium ion (1+) bullet Formamide, N,N-dimethyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Quantity Value Units Method Reference Comment
DeltarH°210.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Acetamide, N-methyl- = (Lithium ion (1+) bullet Acetamide, N-methyl-)

By formula: Li+ + C3H7NO = (Li+ bullet C3H7NO)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
173.373.CIDT,ICRHerreros, Gal, et al., 1999RCD

Lithium ion (1+) + Isopropyl Alcohol = (Lithium ion (1+) bullet Isopropyl Alcohol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
DeltarH°173. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol = (Lithium ion (1+) bullet 1-Propanol)

By formula: Li+ + C3H8O = (Li+ bullet C3H8O)

Quantity Value Units Method Reference Comment
DeltarH°171. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Methylamine, N,N-dimethyl- = (Lithium ion (1+) bullet Methylamine, N,N-dimethyl-)

By formula: Li+ + C3H9N = (Li+ bullet C3H9N)

Quantity Value Units Method Reference Comment
DeltarH°176.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
DeltarH°170.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970; M
Quantity Value Units Method Reference Comment
DeltarS°120.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarG°140.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Pyrazine = (Lithium ion (1+) bullet Pyrazine)

By formula: Li+ + C4H4N2 = (Li+ bullet C4H4N2)

Quantity Value Units Method Reference Comment
DeltarH°149. ± 14.kJ/molCIDTAmunugama and Rodgers, 2000RCD

Lithium ion (1+) + Pyrrole = (Lithium ion (1+) bullet Pyrrole)

By formula: Li+ + C4H5N = (Li+ bullet C4H5N)

Quantity Value Units Method Reference Comment
DeltarH°177. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Imidazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Imidazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
DeltarH°242. ± 21.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1H-Pyrazole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrazole, 1-methyl-)

By formula: Li+ + C4H6N2 = (Li+ bullet C4H6N2)

Quantity Value Units Method Reference Comment
DeltarH°207. ± 19.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + 1-Propene, 2-methyl- = (Lithium ion (1+) bullet 1-Propene, 2-methyl-)

By formula: Li+ + C4H8 = (Li+ bullet C4H8)

Quantity Value Units Method Reference Comment
DeltarH°120.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 1-Butanol = (Lithium ion (1+) bullet 1-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
DeltarH°178. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Propanol, 2-methyl- = (Lithium ion (1+) bullet 2-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
DeltarH°178. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 1-Propanol, 2-methyl- = (Lithium ion (1+) bullet 1-Propanol, 2-methyl-)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
DeltarH°169. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + 2-Butanol = (Lithium ion (1+) bullet 2-Butanol)

By formula: Li+ + C4H10O = (Li+ bullet C4H10O)

Quantity Value Units Method Reference Comment
DeltarH°174. ± 9.2kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-)

By formula: Li+ + C4H10O2 = (Li+ bullet C4H10O2)

Quantity Value Units Method Reference Comment
DeltarH°158. ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD

(Lithium ion (1+) bullet Ethane, 1,2-dimethoxy-) + Ethane, 1,2-dimethoxy- = (Lithium ion (1+) bullet 2Ethane, 1,2-dimethoxy-)

By formula: (Li+ bullet C4H10O2) + C4H10O2 = (Li+ bullet 2C4H10O2)

Quantity Value Units Method Reference Comment
DeltarH°139. ± 12.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine = (Lithium ion (1+) bullet Pyridine)

By formula: Li+ + C5H5N = (Li+ bullet C5H5N)

Quantity Value Units Method Reference Comment
DeltarH°181. ± 15.kJ/molCIDTAmunugama and Rodgers, 2000RCD
DeltarH°180.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + 3-Aminopyridine = (Lithium ion (1+) bullet 3-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
DeltarH°202. ± 10.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 4-Aminopyridine = (Lithium ion (1+) bullet 4-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
DeltarH°217. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 2-Aminopyridine = (Lithium ion (1+) bullet 2-Aminopyridine)

By formula: Li+ + C5H6N2 = (Li+ bullet C5H6N2)

Quantity Value Units Method Reference Comment
DeltarH°238. ± 21.kJ/molCIDTRodgers, 2001RCD

Lithium ion (1+) + 1H-Pyrrole, 1-methyl- = (Lithium ion (1+) bullet 1H-Pyrrole, 1-methyl-)

By formula: Li+ + C5H7N = (Li+ bullet C5H7N)

Quantity Value Units Method Reference Comment
DeltarH°186. ± 17.kJ/molCIDTHuang and Rodgers, 2002RCD

Lithium ion (1+) + Benzene, fluoro- = (Lithium ion (1+) bullet Benzene, fluoro-)

By formula: Li+ + C6H5F = (Li+ bullet C6H5F)

Quantity Value Units Method Reference Comment
DeltarH°147. ± 21.kJ/molCIDTAmunugama and Rodgers, 2002RCD

(Lithium ion (1+) bullet Benzene, fluoro-) + Benzene, fluoro- = (Lithium ion (1+) bullet 2Benzene, fluoro-)

By formula: (Li+ bullet C6H5F) + C6H5F = (Li+ bullet 2C6H5F)

Quantity Value Units Method Reference Comment
DeltarH°95. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002RCD

Lithium ion (1+) + Phenol = (Lithium ion (1+) bullet Phenol)

By formula: Li+ + C6H6O = (Li+ bullet C6H6O)

Quantity Value Units Method Reference Comment
DeltarH°178. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

(Lithium ion (1+) bullet Phenol) + Phenol = (Lithium ion (1+) bullet 2Phenol)

By formula: (Li+ bullet C6H6O) + C6H6O = (Li+ bullet 2C6H6O)

Quantity Value Units Method Reference Comment
DeltarH°115. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 2RCD

Lithium ion (1+) + Benzene = (Lithium ion (1+) bullet Benzene)

By formula: Li+ + C6H6 = (Li+ bullet C6H6)

Quantity Value Units Method Reference Comment
DeltarH°161. ± 13.kJ/molCIDTAmicangelo and Armentrout, 2000RCD
DeltarH°159.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
DeltarH°153.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°115.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarG°124.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 extrapolated; M

(Lithium ion (1+) bullet Benzene) + Benzene = (Lithium ion (1+) bullet 2Benzene)

By formula: (Li+ bullet C6H6) + C6H6 = (Li+ bullet 2C6H6)

Quantity Value Units Method Reference Comment
DeltarH°104. ± 7.1kJ/molCIDTAmicangelo and Armentrout, 2000RCD

Lithium ion (1+) + Pyridine, 4-methyl- = (Lithium ion (1+) bullet Pyridine, 4-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
DeltarH°196. ± 14.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 3-methyl- = (Lithium ion (1+) bullet Pyridine, 3-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
DeltarH°197. ± 15.kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Pyridine, 2-methyl- = (Lithium ion (1+) bullet Pyridine, 2-methyl-)

By formula: Li+ + C6H7N = (Li+ bullet C6H7N)

Quantity Value Units Method Reference Comment
DeltarH°194. ± 6.7kJ/molCIDTRodgers, 2001, 2RCD

Lithium ion (1+) + Cyclohexane = (Lithium ion (1+) bullet Cyclohexane)

By formula: Li+ + C6H12 = (Li+ bullet C6H12)

Quantity Value Units Method Reference Comment
DeltarH°100.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M

Lithium ion (1+) + Methyl 4-nitrophenyl sulfone = (Lithium ion (1+) bullet Methyl 4-nitrophenyl sulfone)

By formula: Li+ + C7H8NO4S = (Li+ bullet C7H8NO4S)

Quantity Value Units Method Reference Comment
DeltarH°198.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Benzene, (methylsulfinyl)- = (Lithium ion (1+) bullet Benzene, (methylsulfinyl)-)

By formula: Li+ + C7H8OS = (Li+ bullet C7H8OS)

Quantity Value Units Method Reference Comment
DeltarH°230.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Anisole = (Lithium ion (1+) bullet Anisole)

By formula: Li+ + C7H8O = (Li+ bullet C7H8O)

Quantity Value Units Method Reference Comment
DeltarH°185. ± 19.kJ/molCIDTAmunugama and Rodgers, 2003RCD

(Lithium ion (1+) bullet Anisole) + Anisole = (Lithium ion (1+) bullet 2Anisole)

By formula: (Li+ bullet C7H8O) + C7H8O = (Li+ bullet 2C7H8O)

Quantity Value Units Method Reference Comment
DeltarH°121. ± 4.kJ/molCIDTAmunugama and Rodgers, 2003RCD

Lithium ion (1+) + Sulfone, methyl phenyl = (Lithium ion (1+) bullet Sulfone, methyl phenyl)

By formula: Li+ + C7H8O2S = (Li+ bullet C7H8O2S)

Quantity Value Units Method Reference Comment
DeltarH°213.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + C7H8O3S = (Lithium ion (1+) bullet C7H8O3S)

By formula: Li+ + C7H8O3S = (Li+ bullet C7H8O3S)

Quantity Value Units Method Reference Comment
DeltarH°206.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Toluene = (Lithium ion (1+) bullet Toluene)

By formula: Li+ + C7H8 = (Li+ bullet C7H8)

Quantity Value Units Method Reference Comment
DeltarH°183. ± 17.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

(Lithium ion (1+) bullet Toluene) + Toluene = (Lithium ion (1+) bullet 2Toluene)

By formula: (Li+ bullet C7H8) + C7H8 = (Li+ bullet 2C7H8)

Quantity Value Units Method Reference Comment
DeltarH°116. ± 3.kJ/molCIDTAmunugama and Rodgers, 2002, 3RCD

Lithium ion (1+) + Benzene, 1-methyl-4-(methylsulfonyl)- = (Lithium ion (1+) bullet Benzene, 1-methyl-4-(methylsulfonyl)-)

By formula: Li+ + C8H10O2S = (Li+ bullet C8H10O2S)

Quantity Value Units Method Reference Comment
DeltarH°216.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + 12-Crown-4 = (Lithium ion (1+) bullet 12-Crown-4)

By formula: Li+ + C8H16O4 = (Li+ bullet C8H16O4)

Quantity Value Units Method Reference Comment
DeltarH°252. ± 13.kJ/molCIDTRodgers and Armentrout, 2000RCD

Lithium ion (1+) + Diphenyl sulfoxide = (Lithium ion (1+) bullet Diphenyl sulfoxide)

By formula: Li+ + C12H10OS = (Li+ bullet C12H10OS)

Quantity Value Units Method Reference Comment
DeltarH°234.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Diphenyl sulfone = (Lithium ion (1+) bullet Diphenyl sulfone)

By formula: Li+ + C12H10O2S = (Li+ bullet C12H10O2S)

Quantity Value Units Method Reference Comment
DeltarH°218.kJ/molCIDCBuncel, Decouzon, et al., 1997RCD

Lithium ion (1+) + Water = (Lithium ion (1+) bullet Water)

By formula: Li+ + H2O = (Li+ bullet H2O)

Quantity Value Units Method Reference Comment
DeltarH°135. ± 7.9kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°140.kJ/molHPMSDzidic and Kebarle, 1970gas phase; interpolated; M
Quantity Value Units Method Reference Comment
DeltarS°96.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; interpolated; M

(Lithium ion (1+) bullet Water) + Water = (Lithium ion (1+) bullet 2Water)

By formula: (Li+ bullet H2O) + H2O = (Li+ bullet 2H2O)

Quantity Value Units Method Reference Comment
DeltarH°113. ± 10.kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°108.kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°88.3J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

(Lithium ion (1+) bullet 2Water) + Water = (Lithium ion (1+) bullet 3Water)

By formula: (Li+ bullet 2H2O) + H2O = (Li+ bullet 3H2O)

Quantity Value Units Method Reference Comment
DeltarH°94.1 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°70. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
DeltarH°86.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°96.J/mol*KHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M
DeltarS°104.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.8300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray; M

(Lithium ion (1+) bullet 3Water) + Water = (Lithium ion (1+) bullet 4Water)

By formula: (Li+ bullet 3H2O) + H2O = (Li+ bullet 4H2O)

Quantity Value Units Method Reference Comment
DeltarH°69.9 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°68.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
DeltarH°60. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
DeltarS°125.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
DeltarS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electrospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 4Water) + Water = (Lithium ion (1+) bullet 5Water)

By formula: (Li+ bullet 4H2O) + H2O = (Li+ bullet 5H2O)

Quantity Value Units Method Reference Comment
DeltarH°56.9 ± 4.2kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°58.2kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
DeltarH°50. ± 10.kJ/molHPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
DeltarS°131.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M
DeltarS°96.J/mol*KN/ABlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.300.HPMSBlades, Jayaweera, et al., 1990gas phase; electospray, Entropy change calculated or estimated; M

(Lithium ion (1+) bullet 5Water) + Water = (Lithium ion (1+) bullet 6Water)

By formula: (Li+ bullet 5H2O) + H2O = (Li+ bullet 6H2O)

Quantity Value Units Method Reference Comment
DeltarH°59.8 ± 5.0kJ/molCIDTRodgers and Armentrout, 2000RCD
DeltarH°50.6kJ/molHPMSDzidic and Kebarle, 1970gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°134.J/mol*KHPMSDzidic and Kebarle, 1970gas phase; M

Lithium ion (1+) + Hydrogen = (Lithium ion (1+) bullet Hydrogen)

By formula: Li+ + H2 = (Li+ bullet H2)

Quantity Value Units Method Reference Comment
DeltarH°27. ± 19.kJ/molEIWu, 1979gas phase; M

Lithium ion (1+) + Ammonia = (Lithium ion (1+) bullet Ammonia)

By formula: Li+ + H3N = (Li+ bullet H3N)

Quantity Value Units Method Reference Comment
DeltarH°164.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
DeltarH°161.kJ/molICRStaley and Beauchamp, 1975gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity Value Units Method Reference Comment
DeltarS°96.J/mol*KN/AWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity Value Units Method Reference Comment
DeltarG°134.kJ/molICRWoodin and Beauchamp, 1978gas phase; switching reaction(Li+)H2O, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

(Lithium ion (1+) bullet Ammonia) + Ammonia = (Lithium ion (1+) bullet 2Ammonia)

By formula: (Li+ bullet H3N) + H3N = (Li+ bullet 2H3N)

Quantity Value Units Method Reference Comment
DeltarH°138.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°124.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 2Ammonia) + Ammonia = (Lithium ion (1+) bullet 3Ammonia)

By formula: (Li+ bullet 2H3N) + H3N = (Li+ bullet 3H3N)

Quantity Value Units Method Reference Comment
DeltarH°87.9kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 3Ammonia) + Ammonia = (Lithium ion (1+) bullet 4Ammonia)

By formula: (Li+ bullet 3H3N) + H3N = (Li+ bullet 4H3N)

Quantity Value Units Method Reference Comment
DeltarH°69.0kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°136.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 4Ammonia) + Ammonia = (Lithium ion (1+) bullet 5Ammonia)

By formula: (Li+ bullet 4H3N) + H3N = (Li+ bullet 5H3N)

Quantity Value Units Method Reference Comment
DeltarH°46.4kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°117.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

(Lithium ion (1+) bullet 5Ammonia) + Ammonia = (Lithium ion (1+) bullet 6Ammonia)

By formula: (Li+ bullet 5H3N) + H3N = (Li+ bullet 6H3N)

Quantity Value Units Method Reference Comment
DeltarH°39.kJ/molHPMSCastleman, Holland, et al., 1978gas phase; M
Quantity Value Units Method Reference Comment
DeltarS°106.J/mol*KHPMSCastleman, Holland, et al., 1978gas phase; M

Lithium ion (1+) + helium = (Lithium ion (1+) bullet helium)

By formula: Li+ + He = (Li+ bullet He)

Quantity Value Units Method Reference Comment
DeltarH°7.15kJ/molIMobGatland, 1984gas phase; M
DeltarH°6.86kJ/molSCATTERINGGislason, 1984gas phase; M
DeltarH°7.07kJ/molIMobViehland, 1984gas phase; M
DeltarH°4.56kJ/molIMobMason and Sharp, 1958gas phase; M
DeltarH°13.2kJ/molIMobTakebe, 1983gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
-15.309.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Krypton = (Lithium ion (1+) bullet Krypton)

By formula: Li+ + Kr = (Li+ bullet Kr)

Quantity Value Units Method Reference Comment
DeltarH°44.4kJ/molSCATTERINGGislason, 1984gas phase; M
DeltarH°38.kJ/molIMobViehland, 1984gas phase; M
DeltarH°68.6kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Nitrogen = (Lithium ion (1+) bullet Nitrogen)

By formula: Li+ + N2 = (Li+ bullet N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

(Lithium ion (1+) bullet Nitrogen) + Nitrogen = (Lithium ion (1+) bullet 2Nitrogen)

By formula: (Li+ bullet N2) + N2 = (Li+ bullet 2N2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.318.DTGatland, Colonna-Romano, et al., 1975gas phase; low E/N; M

Lithium ion (1+) + neon = (Lithium ion (1+) bullet neon)

By formula: Li+ + Ne = (Li+ bullet Ne)

Quantity Value Units Method Reference Comment
DeltarH°11.0kJ/molSCATTERINGGislason, 1984gas phase; M
DeltarH°11.9kJ/molIMobViehland, 1984gas phase; M
DeltarH°14.0kJ/molIMobTakebe, 1983gas phase; M

Lithium ion (1+) + Oxygen = (Lithium ion (1+) bullet Oxygen)

By formula: Li+ + O2 = (Li+ bullet O2)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.319.DTColonna-Romano and Keller, 1976gas phase; low E/N; M

Lithium ion (1+) + Xenon = (Lithium ion (1+) bullet Xenon)

By formula: Li+ + Xe = (Li+ bullet Xe)

Quantity Value Units Method Reference Comment
DeltarH°51.5kJ/molSCATTERINGGislason, 1984gas phase; M
DeltarH°52.7kJ/molIMobViehland, 1984gas phase; M
DeltarH°87.0kJ/molIMobTakebe, 1983gas phase; M

References

Go To: Top, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

McKnight and Sawina, 1973
McKnight, L.G.; Sawina, J.M., Equilibrium Constants and Binding Energies of Alkali Metal Ions with Inert Gases, Bull. Am. Phys. Soc., 1973, 18, 804. [all data]

Cassidy and Elford, 1985
Cassidy, R.A.; Elford, M.T., The Mobility of Li+ Ions in Helium and Argon, Aust. J. Phys., 1985, 38, 4, 587, https://doi.org/10.1071/PH850587 . [all data]

Keller, Beyer, et al., 1973
Keller, C.E.; Beyer, R.A.; Colonna-Romano, L.M., Clustering of Ar to Li+ and a Comparison of Drift - Tube Models, Phys. Rev. A, 1973, 8, 3, 1446, https://doi.org/10.1103/PhysRevA.8.1446 . [all data]

Woodin and Beauchamp, 1978
Woodin, R.L.; Beauchamp, J.L., Bonding of Li+ to Lewis Bases in the Gas Phase. Reversals in Methyl Substituent Effects for Different Reference Acids, J. Am. Chem. Soc., 1978, 100, 2, 501, https://doi.org/10.1021/ja00470a024 . [all data]

Dzidic and Kebarle, 1970
Dzidic, I.; Kebarle, P., Hydration of the Alkali Ions in the Gas Phase. Enthalpies and Entropies of Reactions M+(H2O)n-1 + H2O = M+(H2O)n, J. Phys. Chem., 1970, 74, 7, 1466, https://doi.org/10.1021/j100702a013 . [all data]

Staley and Beauchamp, 1975
Staley, R.H.; Beauchamp, J.L., Intrinsic Acid - Base Properties of Molecules. Binding Energies of Li+ to pi - and n - Donor Bases, J. Am. Chem. Soc., 1975, 97, 20, 5920, https://doi.org/10.1021/ja00853a050 . [all data]

Rodgers and Armentrout, 2000
Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

Herreros, Gal, et al., 1999
Herreros, M.; Gal, J.-F.; Maria, P.-C.; Decouzon, M., Gas-Phase Basicity of Simple Amides Toward Proton and Lithium Cation: An Experimental and Theoretical Study, Eur. J. Mass Spectrom., 1999, 5, 1, 259, https://doi.org/10.1255/ejms.282 . [all data]

Walter, Sievers, et al., 1998
Walter, D.; Sievers, M.R.; Armentrout, P.B., Alkali Ion Carbonyls: Sequential Bond Energies of Li+(CO)x (x=1-3), Na+(CO)x (x=1, 2), and K+(CO), Int. J. Mass Spectrom., 1998, 175, 1-2, 93, https://doi.org/10.1016/S0168-1176(98)00109-8 . [all data]

Keesee and Castleman, 1986
Keesee, R.G.; Castleman, A.W., Jr., Thermochemical data on Ggs-phase ion-molecule association and clustering reactions, J. Phys. Chem. Ref. Data, 1986, 15, 1011. [all data]

Berman and Beauchamp, 1986
Berman, D.W.; Beauchamp, J.L., Quoted in Keesee and Castleman, 1986, 1986. [all data]

Buncel, Decouzon, et al., 1997
Buncel, E.; Decouzon, M.; Formento, A.; Gal, J.-F.; Herreros, M.; Li, L.; Maria, P.-C., Lithium-Cation and Proton Affinities of Sulfoxides and Sulfones: A Fourier Transform Ion Cyclotron Resonance Study, J. Am. Soc. Mass Spectrom., 1997, 8, 3, 262, https://doi.org/10.1016/S1044-0305(96)00255-3 . [all data]

More, Gledening, et al., 1996
More, M.B.; Gledening, E.D.; Ray, D.; Feller, D.; Armentrout, P.B., Cation-Ether Complexes in the Gas Phase: Bond Dissociation Energies and Equilibrium Structures of Li+[O(CH3)2]x, x=1-4, J. Phys. Chem., 1996, 100, 5, 1605, https://doi.org/10.1021/jp9523175 . [all data]

Amunugama and Rodgers, 2000
Amunugama, R.; Rodgers, M.T., Absolute Alkali Metal Ion Binding Affinities of Several Azines Determined by Threshold Collision-Induced Dissociation and Ab Initio Theory, Int. J. Mass Spectrom., 2000, 195/196, 439, https://doi.org/10.1016/S1387-3806(99)00145-1 . [all data]

Huang and Rodgers, 2002
Huang, H.; Rodgers, M.T., Sigma versus Pi interactions in alkali metal ion binding to azoles: Threshold collision-induced dissociation and ab initio theory studies, J. Phys. Chem. A, 2002, 106, 16, 4277, https://doi.org/10.1021/jp013630b . [all data]

Rodgers, 2001
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Aminopyridines, J. Phys. Chem. A, 2001, 105, 35, 8145, https://doi.org/10.1021/jp011555z . [all data]

Amunugama and Rodgers, 2002
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 2. Absolute binding energies of alkali metal cation-fluorobenzene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 39, 9092, https://doi.org/10.1021/jp020459a . [all data]

Amunugama and Rodgers, 2002, 2
Amunugama, R.; Rodgers, M.T., The influence of substituents on cation-pi interactions. 4. Absolute binding energies of alkali metal cation - Phenol complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 42, 9718, https://doi.org/10.1021/jp0211584 . [all data]

Amicangelo and Armentrout, 2000
Amicangelo, J.C.; Armentrout, P.B., Absolute Binding Energies of Alkali-Metal Cation Complexes with Benzene Determined by Threshold Collision-Induced Dissociation Experiments and Ab Initio Theory, J. Phys. Chem. A, 2000, 104, 48, 11420, https://doi.org/10.1021/jp002652f . [all data]

Rodgers, 2001, 2
Rodgers, M.T., Substituent Effects in the Binding of Alkali Metal Ions to Pyridines, Studied by Threshold Collision-Induced Dissociation and ab Initio Theory: The Methylpyridines, J. Phys. Chem. A, 2001, 105, 11, 2374, https://doi.org/10.1021/jp004055z . [all data]

Amunugama and Rodgers, 2003
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions - 5. Absolute binding energies of alkali metal cation-anisole complexes determined by threshold collision-induced dissociation and theoretical studies, Int. J. Mass Spectrom., 2003, 222, 1-3, 431, https://doi.org/10.1016/S1387-3806(02)00945-4 . [all data]

Amunugama and Rodgers, 2002, 3
Amunugama, R.; Rodgers, M.T., Influence of substituents on cation-pi interactions. 1. Absolute binding energies of alkali metal cation-toluene complexes determined by threshold collision-induced dissociation and theoretical studies, J. Phys. Chem. A, 2002, 106, 22, 5529, https://doi.org/10.1021/jp014307b . [all data]

Blades, Jayaweera, et al., 1990
Blades, A.T.; Jayaweera, P.; Ikonomou, M.G.; Kebarle, P., Studies of Alkaline - Earth and Transition - Metal M++ Gas - Phase Ion Chemistry, J. Chem. Phys., 1990, 92, 10, 5900, https://doi.org/10.1063/1.458360 . [all data]

Wu, 1979
Wu, C.H., Binding Energies of LiH2 and LiH2+ and the Ionization Potential of LiH2, J. Chem. Phys., 1979, 71, 2, 783, https://doi.org/10.1063/1.438367 . [all data]

Castleman, Holland, et al., 1978
Castleman, A.W.; Holland, P.M.; Lindsay, D.M.; Peterson, K.I., The Properties of Clusters in the Gas Phase. 2. Ammonia about Metal Ions, J. Am. Chem. Soc., 1978, 100, 19, 6039, https://doi.org/10.1021/ja00487a011 . [all data]

Gatland, 1984
Gatland, I.R., Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Gislason, 1984
Gislason, E.A., Quoted in I. R. Gatland in Swarms of Ions and Electrons in Gases, W. Lindinger, T. D. Mark and F. Howorka, eds. (Springer, New York, 1984, 1984, 44. [all data]

Viehland, 1984
Viehland, L.A., Interaction Potentials for Li+ - Rare - Gas Systems, Chem. Phys., 1984, 78, 2, 279, https://doi.org/10.1016/0301-0104(83)85114-3 . [all data]

Mason and Sharp, 1958
Mason, E.A.; Sharp, H.W., Mobility of gaseous lons in weak electric fields, Ann. Phys., 1958, 4, 3, 233, https://doi.org/10.1016/0003-4916(58)90049-6 . [all data]

Takebe, 1983
Takebe, M., The Generalized Mobility Curve for Alkali Ions in Rare Gases: Clustering Reactions and Mobility Curves, J. Chem. Phys., 1983, 78, 12, 7223, https://doi.org/10.1063/1.444763 . [all data]

Colonna-Romano and Keller, 1976
Colonna-Romano, L.M.; Keller, G.E., The Clustering of O2 and He to Li+, J. Chem. Phys., 1976, 64, 6, 2684, https://doi.org/10.1063/1.432522 . [all data]

Gatland, Colonna-Romano, et al., 1975
Gatland, I.R.; Colonna-Romano, L.M.; Keller, G.E., Single and Double Clustering of Nitrogen to Li+, Phys. Rev. A, 1975, 12, 5, 1885, https://doi.org/10.1103/PhysRevA.12.1885 . [all data]

Notes

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