Tungsten, pentacarbonyl(tributylphosphine)-
- Formula: C17H27O5PW
- Molecular weight: 526.21
- CAS Registry Number: 17000-19-0
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.63 ± 0.05 | EI | Distefano, Innorta, et al., 1968 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C16H27O4PW+ | 9.4 | CO | EI | Torroni, Innorta, et al., 1974 | LLK |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Distefano, Innorta, et al., 1968
Distefano, G.; Innorta, G.; Pignataro, S.; Foffani, A.,
Correlation between the ionization potentials of transition metal complexes and of the corresponding ligands,
J. Organometal. Chem., 1968, 14, 165. [all data]
Torroni, Innorta, et al., 1974
Torroni, S.; Innorta, G.; Foffani, A.; Distefano, G.,
Interpretation of the mass spectra of substituted chromium and tungsten carbonyls by means of appearance potential measurements,
J. Organomet. Chem., 1974, 65, 209. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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