Chlorodifluoromethyl radical


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to CClF2+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Δf(+) ion556.kJ/molN/AN/A 

Electron affinity determinations

EA (eV) Method Reference Comment
>1.86999EIAEIllenberger, Baumgartel, et al., 1979From CF3Cl. G3MP2B3 calculations indicate an EA of ca. 2.05 eV.; B
<1.75581D-EAPaulino and Squires, 1991Probably CF2..Cl-, non-covalent.; B
1.60 ± 0.30NBAEDispert and Lacmann, 1978From CF2Cl2; B

Ionization energy determinations

IE (eV) Method Reference Comment
13. ± 1.DERLangford and Harris, 1990LL
9.0 ± 0.5CIELGriffiths, Harris, et al., 1989LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Illenberger, Baumgartel, et al., 1979
Illenberger, T.; Baumgartel, H.; Scheunemann, H., Negative Ion Formation in CF2Cl2, CF3Cl, and CFCl3 Following Low Energy (0-10eV) Impact with Near Monoenergetic Electrons, Chem. Phys., 1979, 37, 1, 21, https://doi.org/10.1016/0301-0104(79)80003-8 . [all data]

Paulino and Squires, 1991
Paulino, J.A.; Squires, R.R., Carbene Anion Complexes - Unusual Structural and Thermochemical Features of alpha-Halocarbanions in the Gas Phase, J. Am. Chem. Soc., 1991, 113, 5, 1845, https://doi.org/10.1021/ja00005a067 . [all data]

Dispert and Lacmann, 1978
Dispert, H.; Lacmann, K., Negative ion formation in collisions between potassium and fluoro- and chloromethanes: Electron affinities and bond dissociation energies, Int. J. Mass Spectrom. Ion Phys., 1978, 28, 49. [all data]

Langford and Harris, 1990
Langford, M.L.; Harris, F.M., Experimental determination of the energies required to ionize the ions CFCl+, CFBr+, CClBr+, CF2Cl+, CF2Br+, CCl2F+, CBr2F+, and CBr2Cl+, Int. J. Mass Spectrom. Ion Phys., 1990, 96, 111. [all data]

Griffiths, Harris, et al., 1989
Griffiths, W.J.; Harris, F.M.; Barton, J.D., Experimental determination of the single-ionization energies of two environmentally important free radicals, CF2Cl and CFCl2, Rapid Commun. Mass Spectrom., 1989, 3, 283. [all data]


Notes

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