Chlorine anion


Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion = C4HClF9-

By formula: Cl- = C4HClF9-

Quantity Value Units Method Reference Comment
Δr64.9 ± 1.3kJ/molIMREGuerrero, Herrero, et al., 2009gas phase; B

Chlorine anion = C5H10Cl-

By formula: Cl- = C5H10Cl-

Quantity Value Units Method Reference Comment
Δr35.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C5H12Cl-

By formula: Cl- = C5H12Cl-

Quantity Value Units Method Reference Comment
Δr37.5kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr10.9kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H12Cl-

By formula: Cl- = C6H12Cl-

Quantity Value Units Method Reference Comment
Δr40.0kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr12.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C6H14Cl-

By formula: Cl- = C6H14Cl-

Quantity Value Units Method Reference Comment
Δr42.59kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr13.4kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H14Cl-

By formula: Cl- = C7H14Cl-

Quantity Value Units Method Reference Comment
Δr44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr14.8kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C7H16Cl-

By formula: Cl- = C7H16Cl-

Quantity Value Units Method Reference Comment
Δr44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr15.1kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H8Cl-

By formula: Cl- = C8H8Cl-

Quantity Value Units Method Reference Comment
Δr84.1 ± 6.7kJ/molCIDTHammad and Wenthold, 2000gas phase; B

Chlorine anion = C8H16Cl-

By formula: Cl- = C8H16Cl-

Quantity Value Units Method Reference Comment
Δr44.02kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr13.6kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = C8H18Cl-

By formula: Cl- = C8H18Cl-

Quantity Value Units Method Reference Comment
Δr49.12kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B
Quantity Value Units Method Reference Comment
Δr18.7kJ/molN/AZiegler, Gamble, et al., 2013gas phase; B

Chlorine anion = ClN2O-

By formula: Cl- = ClN2O-

Quantity Value Units Method Reference Comment
Δr18.8 ± 0.42kJ/molN/ABoesl, Distelrath, et al., 2008gas phase; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion • Aluminum chloride fluoride)

By formula: Cl- + AlClF2 = (Cl- • AlClF2)

Quantity Value Units Method Reference Comment
Δr311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100K. See also AlCl2F..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum chloride fluoride = (Chlorine anion • Aluminum chloride fluoride)

By formula: Cl- + AlCl2F = (Cl- • AlCl2F)

Quantity Value Units Method Reference Comment
Δr315. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiemnts at 800-1100K. See also AlCl3..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + AlCl3 = (Chlorine anion • AlCl3)

By formula: Cl- + AlCl3 = (Cl- • AlCl3)

Quantity Value Units Method Reference Comment
Δr321. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiments at 800-1100 K; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Aluminum fluoride = (Chlorine anion • Aluminum fluoride)

By formula: Cl- + AlF3 = (Cl- • AlF3)

Quantity Value Units Method Reference Comment
Δr311. ± 12.kJ/molTDAsPervova, Korobov, et al., 1992gas phase; Thermo at 0K, experiment at 800-1100 K. See also AlClF2..F-; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Arsenic trichloride = AsCl4-

By formula: Cl- + AsCl3 = AsCl4-

Quantity Value Units Method Reference Comment
Δr115. ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + trifluoroarsine = (Chlorine anion • trifluoroarsine)

By formula: Cl- + AsF3 = (Cl- • AsF3)

Quantity Value Units Method Reference Comment
Δr108. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr77.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Boron trichloride = (Chlorine anion • Boron trichloride)

By formula: Cl- + BCl3 = (Cl- • BCl3)

Quantity Value Units Method Reference Comment
Δr289. ± 8.4kJ/molTherKrivtsov, Titova, et al., 1977gas phase; Halide affinities from this reference are too high. G3MP2B3 calculations indicate an dHaff ca. 46 kcal/mol; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Boron trifluoride = (Chlorine anion • Boron trifluoride)

By formula: Cl- + BF3 = (Cl- • BF3)

Quantity Value Units Method Reference Comment
Δr109. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr80.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + BiCl3 = BiCl4-

By formula: Cl- + BiCl3 = BiCl4-

Quantity Value Units Method Reference Comment
Δr153. ± 15.kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Bromotrifluoromethane = CBrClF3-

By formula: Cl- + CBrF3 = CBrClF3-

Quantity Value Units Method Reference Comment
Δr69.04 ± 0.84kJ/molTDAsBogdanov and McMahon, 2006gas phase; B
Quantity Value Units Method Reference Comment
Δr38.5kJ/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Phosgene = (Chlorine anion • Phosgene)

By formula: Cl- + CCl2O = (Cl- • CCl2O)

Quantity Value Units Method Reference Comment
Δr52.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr27. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Carbon Tetrachloride = (Chlorine anion • Carbon Tetrachloride)

By formula: Cl- + CCl4 = (Cl- • CCl4)

Quantity Value Units Method Reference Comment
Δr56.1 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr59.4 ± 2.9kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr116.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr21.1kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr24.7 ± 3.8kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Carbonic difluoride = (Chlorine anion • Carbonic difluoride)

By formula: Cl- + CF2O = (Cl- • CF2O)

Quantity Value Units Method Reference Comment
Δr52.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr28. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, trifluoroiodo- = CClF3I-

By formula: Cl- + CF3I = CClF3I-

Quantity Value Units Method Reference Comment
Δr98.74 ± 0.84kJ/molTDAsBogdanov and McMahon, 2006gas phase; B

Chlorine anion + Difluorochloromethane = (Chlorine anion • Difluorochloromethane)

By formula: Cl- + CHClF2 = (Cl- • CHClF2)

Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.2J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr43.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Fluorodichloromethane = (Chlorine anion • Fluorodichloromethane)

By formula: Cl- + CHCl2F = (Cl- • CHCl2F)

Quantity Value Units Method Reference Comment
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Trichloromethane = (Chlorine anion • Trichloromethane)

By formula: Cl- + CHCl3 = (Cl- • CHCl3)

Quantity Value Units Method Reference Comment
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr81.6 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr75.73kJ/molMoblGiles and Grimsrud, 1993gas phase; B
Δr75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr79.9 ± 2.9kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KN/ALarson and McMahon, 1984gas phase; From thermochemical cycle(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Δr103.J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Δr61.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr47. ± 5.kJ/molAVGN/AAverage of 6 values; Individual data points

Chlorine anion + Fluoroform = (Chlorine anion • Fluoroform)

By formula: Cl- + CHF3 = (Cl- • CHF3)

Quantity Value Units Method Reference Comment
Δr70. ± 10.kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr41. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Hydrogen cyanide = (Chlorine anion • Hydrogen cyanide)

By formula: Cl- + CHN = (Cl- • CHN)

Quantity Value Units Method Reference Comment
Δr91.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,B,M
Δr87.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr79.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Δr99.2J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr67.8 ± 6.7kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B
Δr67.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Δr58.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion • Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 2Hydrogen cyanide)

By formula: (Cl- • CHN) + CHN = (Cl- • 2CHN)

Quantity Value Units Method Reference Comment
Δr74.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr46.44kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 2Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 3Hydrogen cyanide)

By formula: (Cl- • 2CHN) + CHN = (Cl- • 3CHN)

Quantity Value Units Method Reference Comment
Δr56.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr30.1kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 3Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 4Hydrogen cyanide)

By formula: (Cl- • 3CHN) + CHN = (Cl- • 4CHN)

Quantity Value Units Method Reference Comment
Δr46.9 ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.9J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr17.6kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 4Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 5Hydrogen cyanide)

By formula: (Cl- • 4CHN) + CHN = (Cl- • 5CHN)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr10.5kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 5Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 6Hydrogen cyanide)

By formula: (Cl- • 5CHN) + CHN = (Cl- • 6CHN)

Quantity Value Units Method Reference Comment
Δr36. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr102.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr6.28kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 6Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 7Hydrogen cyanide)

By formula: (Cl- • 6CHN) + CHN = (Cl- • 7CHN)

Quantity Value Units Method Reference Comment
Δr33. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.7J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr4.18kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 7Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 8Hydrogen cyanide)

By formula: (Cl- • 7CHN) + CHN = (Cl- • 8CHN)

Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSMeot-ner, Cybulski, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.1 ± 9.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; B

(Chlorine anion • 8Hydrogen cyanide) + Hydrogen cyanide = (Chlorine anion • 9Hydrogen cyanide)

By formula: (Cl- • 8CHN) + CHN = (Cl- • 9CHN)

Quantity Value Units Method Reference Comment
Δr31. ± 4.2kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr0.42kJ/molTDAsMeot-ner, Cybulski, et al., 1988gas phase; Entropy estimated; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
13.171.PHPMSMeot-ner, Cybulski, et al., 1988gas phase; Entropy change calculated or estimated; M

Chlorine anion + Methylene chloride = (Chlorine anion • Methylene chloride)

By formula: Cl- + CH2Cl2 = (Cl- • CH2Cl2)

Quantity Value Units Method Reference Comment
Δr66.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr61.9 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr64.9 ± 1.3kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Kebarle, 1977; M
Δr92.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr37.0kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr37.2 ± 2.5kJ/molTDEqDougherty, Dalton, et al., 1974gas phase; B

Chlorine anion + Formic acid = (Chlorine anion • Formic acid)

By formula: Cl- + CH2O2 = (Cl- • CH2O2)

Quantity Value Units Method Reference Comment
Δr115. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr116. ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Δr107. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr156. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr101.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr166.J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr84.1 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr106. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; In serious disagreement with other's values. Source of error not obvious.; B

(Chlorine anion • Formic acid) + Formic acid = (Chlorine anion • 2Formic acid)

By formula: (Cl- • CH2O2) + CH2O2 = (Cl- • 2CH2O2)

Quantity Value Units Method Reference Comment
Δr46.9 ± 8.8kJ/molCIDTWalker and Sunderlin, 1999gas phase; B
Δr143. ± 13.kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Δr230.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion • 2Formic acid) + Formic acid = (Chlorine anion • 3Formic acid)

By formula: (Cl- • 2CH2O2) + CH2O2 = (Cl- • 3CH2O2)

Quantity Value Units Method Reference Comment
Δr93. ± 11.kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Δr150.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

(Chlorine anion • 3Formic acid) + Formic acid = (Chlorine anion • 4Formic acid)

By formula: (Cl- • 3CH2O2) + CH2O2 = (Cl- • 4CH2O2)

Quantity Value Units Method Reference Comment
Δr59.0 ± 9.2kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; M

(Chlorine anion • 4Formic acid) + Formic acid = (Chlorine anion • 5Formic acid)

By formula: (Cl- • 4CH2O2) + CH2O2 = (Cl- • 5CH2O2)

Quantity Value Units Method Reference Comment
Δr42.3 ± 8.4kJ/molN/ALuczynski, Wlodek, et al., 1978gas phase; Buffer gas: H2. Value too bound based on French, Ikuta, et al., 1982, by Grimsrud fractionation factor ( Williamson, Knighton, et al., 1996).; B,M
Quantity Value Units Method Reference Comment
Δr48.1J/mol*KHPMSLuczynski, Wlodek, et al., 1978gas phase; Entropy change is questionable; M

Chlorine anion + Methane, bromo- = (Chlorine anion • Methane, bromo-)

By formula: Cl- + CH3Br = (Cl- • CH3Br)

Quantity Value Units Method Reference Comment
Δr52.3 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr45.6 ± 2.1kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Δr51. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Δr53.6J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr30. ± 5.0kJ/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Chloromethane = (Chlorine anion • Chloromethane)

By formula: Cl- + CH3Cl = (Cl- • CH3Cl)

Quantity Value Units Method Reference Comment
Δr43.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr51.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr36.0 ± 0.84kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B,M
Δr63.6 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Quantity Value Units Method Reference Comment
Δr85.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr64.0J/mol*KHPMSDougherty, Dalton, et al., 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr24.3 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr20.3kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B
Δr26. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr17.2 ± 2.1kJ/molTDAsDougherty, Dalton, et al., 1974gas phase; B
Δr45.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Chlorine anion + Methyl fluoride = (Chlorine anion • Methyl fluoride)

By formula: Cl- + CH3F = (Cl- • CH3F)

Quantity Value Units Method Reference Comment
Δr48.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr23.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3Cl, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Silane, trifluoromethyl- = (Chlorine anion • Silane, trifluoromethyl-)

By formula: Cl- + CH3F3Si = (Cl- • CH3F3Si)

Quantity Value Units Method Reference Comment
Δr67.4 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr40. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Methane, iodo- = (Chlorine anion • Methane, iodo-)

By formula: Cl- + CH3I = (Cl- • CH3I)

Quantity Value Units Method Reference Comment
Δr41.0 ± 0.84kJ/molTDAsDougherty and Roberts, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr31.J/mol*KHPMSDougherty and Roberts, 1974gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr29. ± 5.4kJ/molTDAsDougherty and Roberts, 1974gas phase; B

Chlorine anion + Methane, nitro- = (Chlorine anion • Methane, nitro-)

By formula: Cl- + CH3NO2 = (Cl- • CH3NO2)

Quantity Value Units Method Reference Comment
Δr65.3 ± 2.5kJ/molTDAsWincel, 2003gas phase; B
Δr69.87 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Δr68. ± 13.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Δr71.5J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr38.5kJ/molTDAsWincel, 2003gas phase; B
Δr48.53 ± 0.42kJ/molTDAsSieck, 1985gas phase; B

(Chlorine anion • Methane, nitro-) + Methane, nitro- = (Chlorine anion • 2Methane, nitro-)

By formula: (Cl- • CH3NO2) + CH3NO2 = (Cl- • 2CH3NO2)

Quantity Value Units Method Reference Comment
Δr54.4 ± 2.1kJ/molTDAsWincel, 2003gas phase; B
Δr54.81 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr76.6J/mol*KPHPMSSieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr23.8kJ/molTDAsWincel, 2003gas phase; B
Δr31.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B

Chlorine anion + Methyl Alcohol = (Chlorine anion • Methyl Alcohol)

By formula: Cl- + CH4O = (Cl- • CH4O)

Quantity Value Units Method Reference Comment
Δr69. ± 10.kJ/molAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr95.8J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr61.9J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr42. ± 3.kJ/molAVGN/AAverage of 10 values; Individual data points

(Chlorine anion • Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 2Methyl Alcohol)

By formula: (Cl- • CH4O) + CH4O = (Cl- • 2CH4O)

Quantity Value Units Method Reference Comment
Δr59.0 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr57.32 ± 0.84kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr59.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr54.4 ± 2.9kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr101.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr92.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr81.2J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr30.5kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr29.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr30.1 ± 1.7kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 2Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 3Methyl Alcohol)

By formula: (Cl- • 2CH4O) + CH4O = (Cl- • 3CH4O)

Quantity Value Units Method Reference Comment
Δr48.12 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.2 ± 1.3kJ/molTDAsEvans and Keesee, 1991gas phase; B,M
Δr49.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr51.5 ± 2.5kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr95.0J/mol*KHPMSEvans and Keesee, 1991gas phase; M
Δr98.7J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr16.7kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr21.8 ± 1.3kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 3Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 4Methyl Alcohol)

By formula: (Cl- • 3CH4O) + CH4O = (Cl- • 4CH4O)

Quantity Value Units Method Reference Comment
Δr43.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr43.93kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr46.9 ± 2.5kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr110.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr15.5kJ/molTDAsEvans and Keesee, 1991gas phase; B
Δr13.8 ± 0.84kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 4Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 5Methyl Alcohol)

By formula: (Cl- • 4CH4O) + CH4O = (Cl- • 5CH4O)

Quantity Value Units Method Reference Comment
Δr38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr43.9 ± 2.1kJ/molN/AYamdagni, Payzant, et al., 1973gas phase; B,M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr107.J/mol*KPHPMSYamdagni, Payzant, et al., 1973gas phase; M
Quantity Value Units Method Reference Comment
Δr11. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr12.1 ± 0.42kJ/molTDAsYamdagni, Payzant, et al., 1973gas phase; B

(Chlorine anion • 5Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 6Methyl Alcohol)

By formula: (Cl- • 5CH4O) + CH4O = (Cl- • 6CH4O)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.9J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 6Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 7Methyl Alcohol)

By formula: (Cl- • 6CH4O) + CH4O = (Cl- • 7CH4O)

Quantity Value Units Method Reference Comment
Δr33. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 7Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 8Methyl Alcohol)

By formula: (Cl- • 7CH4O) + CH4O = (Cl- • 8CH4O)

Quantity Value Units Method Reference Comment
Δr32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 8Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 9Methyl Alcohol)

By formula: (Cl- • 8CH4O) + CH4O = (Cl- • 9CH4O)

Quantity Value Units Method Reference Comment
Δr32. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr86.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 9Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 10Methyl Alcohol)

By formula: (Cl- • 9CH4O) + CH4O = (Cl- • 10CH4O)

Quantity Value Units Method Reference Comment
Δr31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.1J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 10Methyl Alcohol) + Methyl Alcohol = (Chlorine anion • 11Methyl Alcohol)

By formula: (Cl- • 10CH4O) + CH4O = (Cl- • 11CH4O)

Quantity Value Units Method Reference Comment
Δr31. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr5.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion • Methyl Alcohol) + Water = (Chlorine anion • Water • Methyl Alcohol)

By formula: (Cl- • CH4O) + H2O = (Cl- • H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr45.6kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr70.7J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • 2Methyl Alcohol) + Water = (Chlorine anion • Water • 2Methyl Alcohol)

By formula: (Cl- • 2CH4O) + H2O = (Cl- • H2O • 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr46.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • Methyl Alcohol • Water) + Methyl Alcohol = (Chlorine anion • 2Methyl Alcohol • Water)

By formula: (Cl- • CH4O • H2O) + CH4O = (Cl- • 2CH4O • H2O)

Quantity Value Units Method Reference Comment
Δr45.2kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr79.J/mol*KHPMSEvans and Keesee, 1991gas phase; M

Chlorine anion + Methanethiol = (Chlorine anion • Methanethiol)

By formula: Cl- + CH4S = (Cl- • CH4S)

Quantity Value Units Method Reference Comment
Δr65. ± 13.kJ/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B
Quantity Value Units Method Reference Comment
Δr45. ± 13.kJ/molIMRBStaneke, Groothuis, et al., 1995gas phase; Chloride affinity comparable to that of CHCl3; B

Chlorine anion + Methane = CH4Cl-

By formula: Cl- + CH4 = CH4Cl-

Quantity Value Units Method Reference Comment
Δr15.9kJ/molN/AHiraoka, Mizuno, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr-9.04kJ/molTDAsHiraoka, Mizuno, et al., 2001gas phase; B

Chlorine anion + Carbon dioxide = (Chlorine anion • Carbon dioxide)

By formula: Cl- + CO2 = (Cl- • CO2)

Quantity Value Units Method Reference Comment
Δr28.5 ± 2.1kJ/molPDisArnold, Bradforth, et al., 1995gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr31.8kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B,M
Δr33.5 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B,M
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Δr82.0J/mol*KHPMSKeesee, Lee, et al., 1980gas phase; M
Quantity Value Units Method Reference Comment
Δr8.79kJ/molTDEqHiraoka, Shoda, et al., 1986gas phase; B
Δr8.79 ± 0.42kJ/molTDAsKeesee, Lee, et al., 1980gas phase; B

(Chlorine anion • Carbon dioxide) + Carbon dioxide = (Chlorine anion • 2Carbon dioxide)

By formula: (Cl- • CO2) + CO2 = (Cl- • 2CO2)

Quantity Value Units Method Reference Comment
Δr30. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Δr30.1kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr-5.9 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Δr4.18kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion • 2Carbon dioxide) + Carbon dioxide = (Chlorine anion • 3Carbon dioxide)

By formula: (Cl- • 2CO2) + CO2 = (Cl- • 3CO2)

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Δr28.5kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr93.7J/mol*KPHPMSHiraoka, Shoda, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr0.4 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1987gas phase; B
Δr0.42kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; B

(Chlorine anion • 3Carbon dioxide) + Carbon dioxide = (Chlorine anion • 4Carbon dioxide)

By formula: (Cl- • 3CO2) + CO2 = (Cl- • 4CO2)

Quantity Value Units Method Reference Comment
Δr26.8kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AHiraoka, Shoda, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr-3.3kJ/molTDAsHiraoka, Shoda, et al., 1986gas phase; entropy estimated.; B

Chlorine anion + Carbon disulfide = (Chlorine anion • Carbon disulfide)

By formula: Cl- + CS2 = (Cl- • CS2)

Quantity Value Units Method Reference Comment
Δr36.8 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Δr49.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr58.2J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Δr84.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr19. ± 9.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B
Δr24. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

(Chlorine anion • Carbon disulfide) + Carbon disulfide = (Chlorine anion • 2Carbon disulfide)

By formula: (Cl- • CS2) + CS2 = (Cl- • 2CS2)

Quantity Value Units Method Reference Comment
Δr32.2 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Δr66.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion • 2Carbon disulfide) + Carbon disulfide = (Chlorine anion • 3Carbon disulfide)

By formula: (Cl- • 2CS2) + CS2 = (Cl- • 3CS2)

Quantity Value Units Method Reference Comment
Δr30.1 ± 0.84kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B,M
Quantity Value Units Method Reference Comment
Δr89.1J/mol*KPHPMSHiraoka, Fujimaki, et al., 1993gas phase; M
Quantity Value Units Method Reference Comment
Δr3. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; B

(Chlorine anion • 3Carbon disulfide) + Carbon disulfide = (Chlorine anion • 4Carbon disulfide)

By formula: (Cl- • 3CS2) + CS2 = (Cl- • 4CS2)

Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B
Quantity Value Units Method Reference Comment
Δr-0.4 ± 4.2kJ/molTDAsHiraoka, Fujimaki, et al., 1993gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C2ClF3O = (Chlorine anion • C2ClF3O)

By formula: Cl- + C2ClF3O = (Cl- • C2ClF3O)

Quantity Value Units Method Reference Comment
Δr74.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr46.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + C2F4O = (Chlorine anion • C2F4O)

By formula: Cl- + C2F4O = (Cl- • C2F4O)

Quantity Value Units Method Reference Comment
Δr69.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr42.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Ethene, tetrafluoro- = C2ClF4-

By formula: Cl- + C2F4 = C2ClF4-

Quantity Value Units Method Reference Comment
Δr>41.84kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B
Quantity Value Units Method Reference Comment
Δr10.7kJ/molTDAsHiraoka, Mochizuki, et al., 2008gas phase; Entropy estimated. The experimental HOF of C2F4 has been quiestioned as being too positive: Curtiss, Raghavachari, et al., 7374, 11CHA/DEN; B

Chlorine anion + Pentafluorodimethyl ether = (Chlorine anion • Pentafluorodimethyl ether)

By formula: Cl- + C2HF5O = (Cl- • C2HF5O)

Quantity Value Units Method Reference Comment
Δr73.2 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr47.3 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Δr50.6 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Ethane, pentafluoro- = (Chlorine anion • Ethane, pentafluoro-)

By formula: Cl- + C2HF5 = (Cl- • C2HF5)

Quantity Value Units Method Reference Comment
Δr78.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr49.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,1',1'-Tetrafluorodimethyl ether = (Chlorine anion • 1,1,1',1'-Tetrafluorodimethyl ether)

By formula: Cl- + C2H2F4O = (Cl- • C2H2F4O)

Quantity Value Units Method Reference Comment
Δr118.0 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr78.7 ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Δr71.1 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + Acetic acid, chloro- = (Chlorine anion • Acetic acid, chloro-)

By formula: Cl- + C2H3ClO2 = (Cl- • C2H3ClO2)

Quantity Value Units Method Reference Comment
Δr59.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Δr33. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + C2H3ClO2 = (Chlorine anion • C2H3ClO2)

By formula: Cl- + C2H3ClO2 = (Cl- • C2H3ClO2)

Quantity Value Units Method Reference Comment
Δr59.0kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Ethanol, 2,2,2-trifluoro- = (Chlorine anion • Ethanol, 2,2,2-trifluoro-)

By formula: Cl- + C2H3F3O = (Cl- • C2H3F3O)

Quantity Value Units Method Reference Comment
Δr100. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr69.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 1,1,2-Trifluoroethane = (Chlorine anion • 1,1,2-Trifluoroethane)

By formula: Cl- + C2H3F3 = (Cl- • C2H3F3)

Quantity Value Units Method Reference Comment
Δr79.1kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr47.7kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetonitrile = (Chlorine anion • Acetonitrile)

By formula: Cl- + C2H3N = (Cl- • C2H3N)

Quantity Value Units Method Reference Comment
Δr61. ± 10.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr65.7J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr65.7J/mol*KPHPMSYamabe, Furumiya, et al., 1986gas phase; M
Δr59.8J/mol*KPHPMSSieck, 1985gas phase; M
Δr59.8J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Δr89.5J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr42.68 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr38. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr37. ± 11.kJ/molTDAsYamabe, Furumiya, et al., 1986gas phase; B
Δr42.26 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr38. ± 8.4kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • Acetonitrile) + Acetonitrile = (Chlorine anion • 2Acetonitrile)

By formula: (Cl- • C2H3N) + C2H3N = (Cl- • 2C2H3N)

Quantity Value Units Method Reference Comment
Δr52.3 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr51.04kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr68.2J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr79.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr32. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr27.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • 2Acetonitrile) + Acetonitrile = (Chlorine anion • 3Acetonitrile)

By formula: (Cl- • 2C2H3N) + C2H3N = (Cl- • 3C2H3N)

Quantity Value Units Method Reference Comment
Δr46.9 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr50.2 ± 2.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr44.35kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr84.1J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; M
Quantity Value Units Method Reference Comment
Δr22. ± 5.4kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr19.2kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • 3Acetonitrile) + Acetonitrile = (Chlorine anion • 4Acetonitrile)

By formula: (Cl- • 3C2H3N) + C2H3N = (Cl- • 4C2H3N)

Quantity Value Units Method Reference Comment
Δr45.6 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr37.7 ± 3.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Δr25.9kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B,M
Quantity Value Units Method Reference Comment
Δr111.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr45.2J/mol*KPHPMSYamdagni and Kebarle, 1972gas phase; Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Δr12. ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Δr12.6kJ/molTDAsYamdagni and Kebarle, 1972gas phase; B

(Chlorine anion • 4Acetonitrile) + Acetonitrile = (Chlorine anion • 5Acetonitrile)

By formula: (Cl- • 4C2H3N) + C2H3N = (Cl- • 5C2H3N)

Quantity Value Units Method Reference Comment
Δr41.0 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr24.3 ± 3.8kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr7.1 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion • 5Acetonitrile) + Acetonitrile = (Chlorine anion • 6Acetonitrile)

By formula: (Cl- • 5C2H3N) + C2H3N = (Cl- • 6C2H3N)

Quantity Value Units Method Reference Comment
Δr39.7 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr24. ± 4.2kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr122.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr3.3 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion • 6Acetonitrile) + Acetonitrile = (Chlorine anion • 7Acetonitrile)

By formula: (Cl- • 6C2H3N) + C2H3N = (Cl- • 7C2H3N)

Quantity Value Units Method Reference Comment
Δr39.3 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Δr16. ± 4.6kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr128.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr0.8 ± 5.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Chlorine anion • 7Acetonitrile) + Acetonitrile = (Chlorine anion • 8Acetonitrile)

By formula: (Cl- • 7C2H3N) + C2H3N = (Cl- • 8C2H3N)

Quantity Value Units Method Reference Comment
Δr38.5kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Δr12. ± 5.0kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr130.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr-1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Chlorine anion • 8Acetonitrile) + Acetonitrile = (Chlorine anion • 9Acetonitrile)

By formula: (Cl- • 8C2H3N) + C2H3N = (Cl- • 9C2H3N)

Quantity Value Units Method Reference Comment
Δr18. ± 5.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion • 9Acetonitrile) + Acetonitrile = (Chlorine anion • 10Acetonitrile)

By formula: (Cl- • 9C2H3N) + C2H3N = (Cl- • 10C2H3N)

Quantity Value Units Method Reference Comment
Δr8.8 ± 6.3kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion • 10Acetonitrile) + Acetonitrile = (Chlorine anion • 11Acetonitrile)

By formula: (Cl- • 10C2H3N) + C2H3N = (Cl- • 11C2H3N)

Quantity Value Units Method Reference Comment
Δr7.5 ± 6.7kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion • 11Acetonitrile) + Acetonitrile = (Chlorine anion • 12Acetonitrile)

By formula: (Cl- • 11C2H3N) + C2H3N = (Cl- • 12C2H3N)

Quantity Value Units Method Reference Comment
Δr-2. ± 7.1kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion • 12Acetonitrile) + Acetonitrile = (Chlorine anion • 13Acetonitrile)

By formula: (Cl- • 12C2H3N) + C2H3N = (Cl- • 13C2H3N)

Quantity Value Units Method Reference Comment
Δr4. ± 7.5kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

(Chlorine anion • 13Acetonitrile) + Acetonitrile = (Chlorine anion • 14Acetonitrile)

By formula: (Cl- • 13C2H3N) + C2H3N = (Cl- • 14C2H3N)

Quantity Value Units Method Reference Comment
Δr-2. ± 7.9kJ/molN/AMarkovich, Perera, et al., 1996gas phase; B

Chlorine anion + Ethane, 1,1-difluoro- = (Chlorine anion • Ethane, 1,1-difluoro-)

By formula: Cl- + C2H4F2 = (Cl- • C2H4F2)

Quantity Value Units Method Reference Comment
Δr62.3 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2,2,2-Trifluoroethylamine = (Chlorine anion • 2,2,2-Trifluoroethylamine)

By formula: Cl- + C2H4F3N = (Cl- • C2H4F3N)

Quantity Value Units Method Reference Comment
Δr75.3 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetaldehyde = (Chlorine anion • Acetaldehyde)

By formula: Cl- + C2H4O = (Cl- • C2H4O)

Quantity Value Units Method Reference Comment
Δr60.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Acetic acid = (Chlorine anion • Acetic acid)

By formula: Cl- + C2H4O2 = (Cl- • C2H4O2)

Quantity Value Units Method Reference Comment
Δr102.1 ± 0.84kJ/molTDAsSieck, 1985gas phase; B,M
Δr90.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Δr100. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr100.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr80.8J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr77.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr66.1 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B
Δr69.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl bromide = (Chlorine anion • Ethyl bromide)

By formula: Cl- + C2H5Br = (Cl- • C2H5Br)

Quantity Value Units Method Reference Comment
Δr56.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr29.0 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 2-Chloroethanol = (Chlorine anion • 2-Chloroethanol)

By formula: Cl- + C2H5ClO = (Cl- • C2H5ClO)

Quantity Value Units Method Reference Comment
Δr90.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)FCH2CH2OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr58.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl Chloride = (Chlorine anion • Ethyl Chloride)

By formula: Cl- + C2H5Cl = (Cl- • C2H5Cl)

Quantity Value Units Method Reference Comment
Δr51.9 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr61. ± 19.kJ/molIMRBRiveros, Breda, et al., 1973gas phase; Anchored: Larson and McMahon, 1984, 3; B
Quantity Value Units Method Reference Comment
Δr28.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Ethanol, 2-fluoro- = (Chlorine anion • Ethanol, 2-fluoro-)

By formula: Cl- + C2H5FO = (Cl- • C2H5FO)

Quantity Value Units Method Reference Comment
Δr85.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr54.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Dimethyl Sulfoxide = (Chlorine anion • Dimethyl Sulfoxide)

By formula: Cl- + C2H6OS = (Cl- • C2H6OS)

Quantity Value Units Method Reference Comment
Δr77.82kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr52.30kJ/molTDAsMagnera, Caldwell, et al., 1984gas phase; B

(Chlorine anion • Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion • 2Dimethyl Sulfoxide)

By formula: (Cl- • C2H6OS) + C2H6OS = (Cl- • 2C2H6OS)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr99.6J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion • 2Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion • 3Dimethyl Sulfoxide)

By formula: (Cl- • 2C2H6OS) + C2H6OS = (Cl- • 3C2H6OS)

Quantity Value Units Method Reference Comment
Δr62.3kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr125.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion • 3Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion • 4Dimethyl Sulfoxide)

By formula: (Cl- • 3C2H6OS) + C2H6OS = (Cl- • 4C2H6OS)

Quantity Value Units Method Reference Comment
Δr61.1kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr156.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

(Chlorine anion • 4Dimethyl Sulfoxide) + Dimethyl Sulfoxide = (Chlorine anion • 5Dimethyl Sulfoxide)

By formula: (Cl- • 4C2H6OS) + C2H6OS = (Cl- • 5C2H6OS)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPHPMSMagnera, Caldwell, et al., 1984gas phase; M
Quantity Value Units Method Reference Comment
Δr168.J/mol*KPHPMSMagnera, Caldwell, et al., 1984gas phase; M

Chlorine anion + Ethanol = (Chlorine anion • Ethanol)

By formula: Cl- + C2H6O = (Cl- • C2H6O)

Quantity Value Units Method Reference Comment
Δr74.9 ± 1.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr73.6 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr72.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr99.2J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr96.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr44.56kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr43.9 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr43.5 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8295.ICRRiveros, 1974gas phase; switching reaction(Cl-)CH3OH; Riveros, Breda, et al., 1973; M

(Chlorine anion • Ethanol) + Ethanol = (Chlorine anion • 2Ethanol)

By formula: (Cl- • C2H6O) + C2H6O = (Cl- • 2C2H6O)

Quantity Value Units Method Reference Comment
Δr64.02 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr67.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr30.7kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr35. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 2Ethanol) + Ethanol = (Chlorine anion • 3Ethanol)

By formula: (Cl- • 2C2H6O) + C2H6O = (Cl- • 3C2H6O)

Quantity Value Units Method Reference Comment
Δr58.2 ± 2.9kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr53.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr21.6kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr21. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 3Ethanol) + Ethanol = (Chlorine anion • 4Ethanol)

By formula: (Cl- • 3C2H6O) + C2H6O = (Cl- • 4C2H6O)

Quantity Value Units Method Reference Comment
Δr50.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr123.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr13. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 4Ethanol) + Ethanol = (Chlorine anion • 5Ethanol)

By formula: (Cl- • 4C2H6O) + C2H6O = (Cl- • 5C2H6O)

Quantity Value Units Method Reference Comment
Δr48.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 5Ethanol) + Ethanol = (Chlorine anion • 6Ethanol)

By formula: (Cl- • 5C2H6O) + C2H6O = (Cl- • 6C2H6O)

Quantity Value Units Method Reference Comment
Δr46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 6Ethanol) + Ethanol = (Chlorine anion • 7Ethanol)

By formula: (Cl- • 6C2H6O) + C2H6O = (Cl- • 7C2H6O)

Quantity Value Units Method Reference Comment
Δr41. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 7Ethanol) + Ethanol = (Chlorine anion • 8Ethanol)

By formula: (Cl- • 7C2H6O) + C2H6O = (Cl- • 8C2H6O)

Quantity Value Units Method Reference Comment
Δr38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 8Ethanol) + Ethanol = (Chlorine anion • 9Ethanol)

By formula: (Cl- • 8C2H6O) + C2H6O = (Cl- • 9C2H6O)

Quantity Value Units Method Reference Comment
Δr38. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr6.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

(Chlorine anion • 9Ethanol) + Ethanol = (Chlorine anion • 10Ethanol)

By formula: (Cl- • 9C2H6O) + C2H6O = (Cl- • 10C2H6O)

Quantity Value Units Method Reference Comment
Δr37. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr5.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + Dimethyl ether = C2H6ClO-

By formula: Cl- + C2H6O = C2H6ClO-

Quantity Value Units Method Reference Comment
Δr31.4 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr12. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1,2-Ethanediol = (Chlorine anion • 1,2-Ethanediol)

By formula: Cl- + C2H6O2 = (Cl- • C2H6O2)

Quantity Value Units Method Reference Comment
Δr106. ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr69.5 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion • 1,2-Ethanediol) + 1,2-Ethanediol = (Chlorine anion • 21,2-Ethanediol)

By formula: (Cl- • C2H6O2) + C2H6O2 = (Cl- • 2C2H6O2)

Quantity Value Units Method Reference Comment
Δr66.5 ± 5.0kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr39. ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3F6O = (Cl- • C3F6O)

Quantity Value Units Method Reference Comment
Δr120. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr95.8 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr68.2kJ/molICRLarson and McMahon, 1984, 3gas phase; switching reaction(Cl-)(C2H5)3B; M

Chlorine anion + Propene, hexafluoro- = C3ClF6-

By formula: Cl- + C3F6 = C3ClF6-

Quantity Value Units Method Reference Comment
Δr52.7 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr21.5 ± 1.3kJ/molTDAsHiraoka, Takao, et al., 2002gas phase; B

Chlorine anion + 2-Propanone, 1,1,1,3,3-pentafluoro- = (Chlorine anion • 2-Propanone, 1,1,1,3,3-pentafluoro-)

By formula: Cl- + C3HF5O = (Cl- • C3HF5O)

Quantity Value Units Method Reference Comment
Δr109. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr97.9kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M,M

Chlorine anion + 1,1,3,3-tetrafluoroacetone = (Chlorine anion • 1,1,3,3-tetrafluoroacetone)

By formula: Cl- + C3H2F4O = (Cl- • C3H2F4O)

Quantity Value Units Method Reference Comment
Δr75.7 ± 8.4kJ/molIMRELarson and McMahon, 1984, 3gas phase; B,M

Chlorine anion + 2-Propanol, 1,1,1,3,3,3-hexafluoro- = (Chlorine anion • 2-Propanol, 1,1,1,3,3,3-hexafluoro-)

By formula: Cl- + C3H2F6O = (Cl- • C3H2F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)(CF3)2CH3COH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M

Chlorine anion + C3H3F3O- = C2H3ClF3O-

By formula: Cl- + C3H3F3O- = C2H3ClF3O-

Quantity Value Units Method Reference Comment
Δr56.9 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr32. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 2-Propanone, 1,1,1-trifluoro- = C3H3ClF3O-

By formula: Cl- + C3H3F3O = C3H3ClF3O-

Quantity Value Units Method Reference Comment
Δr57.3 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 2-Propanone, 1-fluoro- = C3H5ClFO-

By formula: Cl- + C3H5FO = C3H5ClFO-

Quantity Value Units Method Reference Comment
Δr77.0 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Quantity Value Units Method Reference Comment
Δr46.4 ± 4.2kJ/molTDAsBofdanov and McMahon, 2002gas phase; B

Chlorine anion + 1,3-Difluoro-2-propanol = (Chlorine anion • 1,3-Difluoro-2-propanol)

By formula: Cl- + C3H6F2O = (Cl- • C3H6F2O)

Quantity Value Units Method Reference Comment
Δr98.7kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr67.4kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3COOH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M

Chlorine anion + Acetone = (Chlorine anion • Acetone)

By formula: Cl- + C3H6O = (Cl- • C3H6O)

Quantity Value Units Method Reference Comment
Δr56. ± 6.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr76.1J/mol*KPHPMSSieck, 1985gas phase; M
Δr82.0J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr71.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Δr82.4J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr33.8 ± 0.84kJ/molTDAsBofdanov and McMahon, 2002gas phase; B
Δr30.5kJ/molTDAsHiraoka, Morise, et al., 1986gas phase; B
Δr36.8 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr33. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B

(Chlorine anion • Acetone) + Acetone = (Chlorine anion • 2Acetone)

By formula: (Cl- • C3H6O) + C3H6O = (Cl- • 2C3H6O)

Quantity Value Units Method Reference Comment
Δr48.1 ± 4.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr84.9J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr23. ± 9.2kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; B

(Chlorine anion • 2Acetone) + Acetone = (Chlorine anion • 3Acetone)

By formula: (Cl- • 2C3H6O) + C3H6O = (Cl- • 3C3H6O)

Quantity Value Units Method Reference Comment
Δr43.5 ± 8.4kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/AHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr16. ± 19.kJ/molTDAsHiraoka, Takimoto, et al., 1986gas phase; Entropy estimated; B

Chlorine anion + Propane, 2-bromo- = (Chlorine anion • Propane, 2-bromo-)

By formula: Cl- + C3H7Br = (Cl- • C3H7Br)

Quantity Value Units Method Reference Comment
Δr63.6 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr35.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 1-bromo- = (Chlorine anion • Propane, 1-bromo-)

By formula: Cl- + C3H7Br = (Cl- • C3H7Br)

Quantity Value Units Method Reference Comment
Δr59.4 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr34.5 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro- = (Chlorine anion • Propane, 2-chloro-)

By formula: Cl- + C3H7Cl = (Cl- • C3H7Cl)

Quantity Value Units Method Reference Comment
Δr61.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr32.6 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Isopropyl Alcohol = (Chlorine anion • Isopropyl Alcohol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr81.17 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr76.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr103.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr47.36kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr45.61kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion • Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 2Isopropyl Alcohol)

By formula: (Cl- • C3H8O) + C3H8O = (Cl- • 2C3H8O)

Quantity Value Units Method Reference Comment
Δr69.9 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr65.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr32.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 2Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 3Isopropyl Alcohol)

By formula: (Cl- • 2C3H8O) + C3H8O = (Cl- • 3C3H8O)

Quantity Value Units Method Reference Comment
Δr62.3 ± 2.1kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr52.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr22.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 3Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 4Isopropyl Alcohol)

By formula: (Cl- • 3C3H8O) + C3H8O = (Cl- • 4C3H8O)

Quantity Value Units Method Reference Comment
Δr49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 4Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 5Isopropyl Alcohol)

By formula: (Cl- • 4C3H8O) + C3H8O = (Cl- • 5C3H8O)

Quantity Value Units Method Reference Comment
Δr48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr128.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr10. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 5Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 6Isopropyl Alcohol)

By formula: (Cl- • 5C3H8O) + C3H8O = (Cl- • 6C3H8O)

Quantity Value Units Method Reference Comment
Δr47.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr8.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 6Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 7Isopropyl Alcohol)

By formula: (Cl- • 6C3H8O) + C3H8O = (Cl- • 7C3H8O)

Quantity Value Units Method Reference Comment
Δr46.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr7.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 7Isopropyl Alcohol) + Isopropyl Alcohol = (Chlorine anion • 8Isopropyl Alcohol)

By formula: (Cl- • 7C3H8O) + C3H8O = (Cl- • 8C3H8O)

Quantity Value Units Method Reference Comment
Δr45.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr6.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1-Propanol = (Chlorine anion • 1-Propanol)

By formula: Cl- + C3H8O = (Cl- • C3H8O)

Quantity Value Units Method Reference Comment
Δr85.4 ± 2.1kJ/molTDAsHiraoka, 1987gas phase; B,B,M
Δr74.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr121.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr48.95kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr49.0 ± 8.4kJ/molTDAsHiraoka, 1987gas phase; B
Δr45.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

(Chlorine anion • 1-Propanol) + 1-Propanol = (Chlorine anion • 21-Propanol)

By formula: (Cl- • C3H8O) + C3H8O = (Cl- • 2C3H8O)

Quantity Value Units Method Reference Comment
Δr66.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr106.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr34. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 21-Propanol) + 1-Propanol = (Chlorine anion • 31-Propanol)

By formula: (Cl- • 2C3H8O) + C3H8O = (Cl- • 3C3H8O)

Quantity Value Units Method Reference Comment
Δr59.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr20. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 31-Propanol) + 1-Propanol = (Chlorine anion • 41-Propanol)

By formula: (Cl- • 3C3H8O) + C3H8O = (Cl- • 4C3H8O)

Quantity Value Units Method Reference Comment
Δr55.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr134.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr15. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 41-Propanol) + 1-Propanol = (Chlorine anion • 51-Propanol)

By formula: (Cl- • 4C3H8O) + C3H8O = (Cl- • 5C3H8O)

Quantity Value Units Method Reference Comment
Δr52.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr138.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr11. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 51-Propanol) + 1-Propanol = (Chlorine anion • 61-Propanol)

By formula: (Cl- • 5C3H8O) + C3H8O = (Cl- • 6C3H8O)

Quantity Value Units Method Reference Comment
Δr48.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 61-Propanol) + 1-Propanol = (Chlorine anion • 71-Propanol)

By formula: (Cl- • 6C3H8O) + C3H8O = (Cl- • 7C3H8O)

Quantity Value Units Method Reference Comment
Δr46.0 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr126.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr7.9 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 71-Propanol) + 1-Propanol = (Chlorine anion • 81-Propanol)

By formula: (Cl- • 7C3H8O) + C3H8O = (Cl- • 8C3H8O)

Quantity Value Units Method Reference Comment
Δr45.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + C3H9ClGe = C3H9Cl2Ge-

By formula: Cl- + C3H9ClGe = C3H9Cl2Ge-

Quantity Value Units Method Reference Comment
Δr92.9 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silane, chlorotrimethyl- = C3H9Cl2Si-

By formula: Cl- + C3H9ClSi = C3H9Cl2Si-

Quantity Value Units Method Reference Comment
Δr59.8 ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Stannane, chlorotrimethyl- = C3H9Cl2Sn-

By formula: Cl- + C3H9ClSn = C3H9Cl2Sn-

Quantity Value Units Method Reference Comment
Δr131. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + C4H4F6O = (Chlorine anion • C4H4F6O)

By formula: Cl- + C4H4F6O = (Cl- • C4H4F6O)

Quantity Value Units Method Reference Comment
Δr111.kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr105.J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr79.5kJ/molICRLarson and McMahon, 1984gas phase; switching reaction(Cl-)HCOOH, Entropy change calculated or estimated, DG>, ΔrH>; Larson and McMahon, 1984, 2; M

Chlorine anion + Pyrrole = (Chlorine anion • Pyrrole)

By formula: Cl- + C4H5N = (Cl- • C4H5N)

Quantity Value Units Method Reference Comment
Δr78.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B
Quantity Value Units Method Reference Comment
Δr49.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B
Δr58.58kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
48.5421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 2-Butyne-1,4-diol = (Chlorine anion • 2-Butyne-1,4-diol)

By formula: Cl- + C4H6O2 = (Cl- • C4H6O2)

Quantity Value Units Method Reference Comment
Δr121. ± 4.6kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr75.3 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion • 2-Butyne-1,4-diol) + 2-Butyne-1,4-diol = (Chlorine anion • 22-Butyne-1,4-diol)

By formula: (Cl- • C4H6O2) + C4H6O2 = (Cl- • 2C4H6O2)

Quantity Value Units Method Reference Comment
Δr93.3 ± 2.9kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr49.8 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + 2-Butanone = (Chlorine anion • 2-Butanone)

By formula: Cl- + C4H8O = (Cl- • C4H8O)

Quantity Value Units Method Reference Comment
Δr61.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr36. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Butene-1,4-diol, (Z)- = (Chlorine anion • 2-Butene-1,4-diol, (Z)-)

By formula: Cl- + C4H8O2 = (Cl- • C4H8O2)

Quantity Value Units Method Reference Comment
Δr138. ± 6.3kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr82.4 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion • 2-Butene-1,4-diol, (Z)-) + 2-Butene-1,4-diol, (Z)- = (Chlorine anion • 22-Butene-1,4-diol, (Z)-)

By formula: (Cl- • C4H8O2) + C4H8O2 = (Cl- • 2C4H8O2)

Quantity Value Units Method Reference Comment
Δr95.8 ± 1.7kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr49.0 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Propane, 2-bromo-2-methyl- = (Chlorine anion • Propane, 2-bromo-2-methyl-)

By formula: Cl- + C4H9Br = (Cl- • C4H9Br)

Quantity Value Units Method Reference Comment
Δr74.1 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr37.2 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + Propane, 2-chloro-2-methyl- = (Chlorine anion • Propane, 2-chloro-2-methyl-)

By formula: Cl- + C4H9Cl = (Cl- • C4H9Cl)

Quantity Value Units Method Reference Comment
Δr69.5 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr59.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)t-C4H9F, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr34.7 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Δr33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propane, 2-fluoro-2-methyl- = (Chlorine anion • Propane, 2-fluoro-2-methyl-)

By formula: Cl- + C4H9F = (Cl- • C4H9F)

Quantity Value Units Method Reference Comment
Δr55.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr87.0J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr30. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Ethyl ether = C4H10ClO-

By formula: Cl- + C4H10O = C4H10ClO-

Quantity Value Units Method Reference Comment
Δr37.7 ± 1.7kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B
Quantity Value Units Method Reference Comment
Δr14. ± 4.2kJ/molTDAsBogdanov, Lee, et al., 2001gas phase; B

Chlorine anion + 1-Butanol = (Chlorine anion • 1-Butanol)

By formula: Cl- + C4H10O = (Cl- • C4H10O)

Quantity Value Units Method Reference Comment
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CH3OH, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr44.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + 2-Propanol, 2-methyl- = (Chlorine anion • 2-Propanol, 2-methyl-)

By formula: Cl- + C4H10O = (Cl- • C4H10O)

Quantity Value Units Method Reference Comment
Δr77. ± 20.kJ/molAVGN/AAverage of 6 values; Individual data points
Quantity Value Units Method Reference Comment
Δr115.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Δr100.J/mol*KPHPMSSieck, 1985gas phase; M
Δr97.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr43.1J/mol*KN/AYamdagni and Kebarle, 1971gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr48.45kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr51.5 ± 1.3kJ/molTDAsSieck, 1985gas phase; B
Δr48.53kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr46.4 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr46.4 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

(Chlorine anion • 2-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion • 22-Propanol, 2-methyl-)

By formula: (Cl- • C4H10O) + C4H10O = (Cl- • 2C4H10O)

Quantity Value Units Method Reference Comment
Δr70.71 ± 0.84kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr62.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr108.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr30.8kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr30. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 22-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion • 32-Propanol, 2-methyl-)

By formula: (Cl- • 2C4H10O) + C4H10O = (Cl- • 3C4H10O)

Quantity Value Units Method Reference Comment
Δr66.1 ± 1.3kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr57.3 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr21.2kJ/molTDAsBogdanov, Peschke, et al., 1999gas phase; B
Δr18. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 32-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion • 42-Propanol, 2-methyl-)

By formula: (Cl- • 3C4H10O) + C4H10O = (Cl- • 4C4H10O)

Quantity Value Units Method Reference Comment
Δr53.1 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr131.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr14. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 42-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion • 52-Propanol, 2-methyl-)

By formula: (Cl- • 4C4H10O) + C4H10O = (Cl- • 5C4H10O)

Quantity Value Units Method Reference Comment
Δr49.8 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B,M
Quantity Value Units Method Reference Comment
Δr135.J/mol*KPHPMSHiraoka and Mizuse, 1987gas phase; M
Quantity Value Units Method Reference Comment
Δr9.2 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B

(Chlorine anion • 52-Propanol, 2-methyl-) + 2-Propanol, 2-methyl- = (Chlorine anion • 62-Propanol, 2-methyl-)

By formula: (Cl- • 5C4H10O) + C4H10O = (Cl- • 6C4H10O)

Quantity Value Units Method Reference Comment
Δr47.7 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B,M
Quantity Value Units Method Reference Comment
Δr130.J/mol*KN/AHiraoka and Mizuse, 1987gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr7.5 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; Estimated entropy; single temperature measurement; B

Chlorine anion + 1,4-Butanediol = (Chlorine anion • 1,4-Butanediol)

By formula: Cl- + C4H10O2 = (Cl- • C4H10O2)

Quantity Value Units Method Reference Comment
Δr126. ± 7.1kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr73.2 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

(Chlorine anion • 1,4-Butanediol) + 1,4-Butanediol = (Chlorine anion • 21,4-Butanediol)

By formula: (Cl- • C4H10O2) + C4H10O2 = (Cl- • 2C4H10O2)

Quantity Value Units Method Reference Comment
Δr88.7 ± 3.3kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B
Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsZhang, Beglinger, et al., 1995gas phase; B

Chlorine anion + Cyclopentene, octafluoro- = C5ClF8-

By formula: Cl- + C5F8 = C5ClF8-

Quantity Value Units Method Reference Comment
Δr57.74 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B
Quantity Value Units Method Reference Comment
Δr34.1 ± 0.84kJ/molTDAsHiraoka, Fujita, et al., 1905gas phase; B

Chlorine anion + Iron pentacarbonyl = (Chlorine anion • Iron pentacarbonyl)

By formula: Cl- + C5FeO5 = (Cl- • C5FeO5)

Quantity Value Units Method Reference Comment
Δr58. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase; B
Quantity Value Units Method Reference Comment
Δr33. ± 13.kJ/molIMRBLane, Sallans, et al., 1985gas phase; B

Chlorine anion + Pyridine = (Chlorine anion • Pyridine)

By formula: Cl- + C5H5N = (Cl- • C5H5N)

Quantity Value Units Method Reference Comment
Δr53.1 ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.4J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B

(Chlorine anion • Pyridine) + Pyridine = (Chlorine anion • 2Pyridine)

By formula: (Cl- • C5H5N) + C5H5N = (Cl- • 2C5H5N)

Quantity Value Units Method Reference Comment
Δr49.0kJ/molPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M

Chlorine anion + 1,3-Cyclopentadiene = (Chlorine anion • 1,3-Cyclopentadiene)

By formula: Cl- + C5H6 = (Cl- • C5H6)

Quantity Value Units Method Reference Comment
Δr<10.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
10.300.PHPMSFrench, Ikuta, et al., 1982gas phase; DG<; M

Chlorine anion + Acetylacetone = (Chlorine anion • Acetylacetone)

By formula: Cl- + C5H8O2 = (Cl- • C5H8O2)

Quantity Value Units Method Reference Comment
Δr56.07kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
46.0421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,4-Pentadiene = (Chlorine anion • 1,4-Pentadiene)

By formula: Cl- + C5H8 = (Cl- • C5H8)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + 1,3-Pentadiene, (E)- = (Chlorine anion • 1,3-Pentadiene, (E)-)

By formula: Cl- + C5H8 = (Cl- • C5H8)

Quantity Value Units Method Reference Comment
Δr15.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Propanenitrile, 2,2-dimethyl- = (Chlorine anion • Propanenitrile, 2,2-dimethyl-)

By formula: Cl- + C5H9N = (Cl- • C5H9N)

Quantity Value Units Method Reference Comment
Δr77.4 ± 4.2kJ/molTDAsLi, Ross, et al., 1996gas phase; B
Quantity Value Units Method Reference Comment
Δr46.23 ± 0.84kJ/molTDAsLi, Ross, et al., 1996gas phase; B

Chlorine anion + 3-Pentanone = (Chlorine anion • 3-Pentanone)

By formula: Cl- + C5H10O = (Cl- • C5H10O)

Quantity Value Units Method Reference Comment
Δr59.0 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr82.0J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)(CH3)2CO, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr34. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Propanal, 2,2-dimethyl- = (Chlorine anion • Propanal, 2,2-dimethyl-)

By formula: Cl- + C5H10O = (Cl- • C5H10O)

Quantity Value Units Method Reference Comment
Δr62.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr91.6J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)CF3H, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr35. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + p-Benzoquinone, 2,3,5,6-tetrafluoro- = (Chlorine anion • p-Benzoquinone, 2,3,5,6-tetrafluoro-)

By formula: Cl- + C6F4O2 = (Cl- • C6F4O2)

Quantity Value Units Method Reference Comment
Δr113. ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr84.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, hexafluoro- = (Chlorine anion • Benzene, hexafluoro-)

By formula: Cl- + C6F6 = (Cl- • C6F6)

Quantity Value Units Method Reference Comment
Δr70.3 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Δr64.9 ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Δr113.J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr37. ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Δr36. ± 6.7kJ/molTDAsHiraoka, Mizuse, et al., 1987, 2gas phase; B

(Chlorine anion • Benzene, hexafluoro-) + Benzene, hexafluoro- = (Chlorine anion • 2Benzene, hexafluoro-)

By formula: (Cl- • C6F6) + C6F6 = (Cl- • 2C6F6)

Quantity Value Units Method Reference Comment
Δr57.7kJ/molPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M
Quantity Value Units Method Reference Comment
Δr110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1987, 2gas phase; M

Chlorine anion + Benzene, 1-fluoro-3-nitro- = (Chlorine anion • Benzene, 1-fluoro-3-nitro-)

By formula: Cl- + C6H4FNO2 = (Cl- • C6H4FNO2)

Quantity Value Units Method Reference Comment
Δr78.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr88.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr51.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzene, 1,2-difluoro- = (Chlorine anion • Benzene, 1,2-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- • C6H4F2)

Quantity Value Units Method Reference Comment
Δr59.8 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, 1,3-difluoro- = (Chlorine anion • Benzene, 1,3-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- • C6H4F2)

Quantity Value Units Method Reference Comment
Δr61.1 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.6J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr33. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr32. ± 4.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Chlorine anion + Benzene, 1,4-difluoro- = (Chlorine anion • Benzene, 1,4-difluoro-)

By formula: Cl- + C6H4F2 = (Cl- • C6H4F2)

Quantity Value Units Method Reference Comment
Δr57.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr90.4J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)ClCOOCH3, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr31. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Benzene, bromo- = (Chlorine anion • Benzene, bromo-)

By formula: Cl- + C6H5Br = (Cl- • C6H5Br)

Quantity Value Units Method Reference Comment
Δr28.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B,M

Chlorine anion + Phenol, 4-chloro- = (Chlorine anion • Phenol, 4-chloro-)

By formula: Cl- + C6H5ClO = (Cl- • C6H5ClO)

Quantity Value Units Method Reference Comment
Δr124. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr126.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.5 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
81.6423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
87.9300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, chloro- = (Chlorine anion • Benzene, chloro-)

By formula: Cl- + C6H5Cl = (Cl- • C6H5Cl)

Quantity Value Units Method Reference Comment
Δr50.21 ± 0.42kJ/molTDAsSieck, 1985gas phase; B,M
Δr56.9 ± 4.2kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Δr52.7kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr69.0J/mol*KPHPMSSieck, 1985gas phase; M
Δr93.7J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr29.7 ± 0.84kJ/molTDAsSieck, 1985gas phase; B
Δr29. ± 4.2kJ/molIMRELarson and McMahon, 1984, 2gas phase; B,B,M
Δr27.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
28.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
27.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol, 4-fluoro- = (Chlorine anion • Phenol, 4-fluoro-)

By formula: Cl- + C6H5FO = (Cl- • C6H5FO)

Quantity Value Units Method Reference Comment
Δr117. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr120.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr106.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr86.2 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
75.3423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
80.8300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)C6H5OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzene, fluoro- = (Chlorine anion • Benzene, fluoro-)

By formula: Cl- + C6H5F = (Cl- • C6H5F)

Quantity Value Units Method Reference Comment
Δr24.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
25.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, iodo- = (Chlorine anion • Benzene, iodo-)

By formula: Cl- + C6H5I = (Cl- • C6H5I)

Quantity Value Units Method Reference Comment
Δr30.1kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, nitro- = (Chlorine anion • Benzene, nitro-)

By formula: Cl- + C6H5NO2 = (Cl- • C6H5NO2)

Quantity Value Units Method Reference Comment
Δr68.2 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Δr69.0kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr81.2J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr43.9 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B
Δr29.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
43.9300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
32.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phenol = (Chlorine anion • Phenol)

By formula: Cl- + C6H6O = (Cl- • C6H6O)

Quantity Value Units Method Reference Comment
Δr109. ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B,M
Δr109. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr115.kJ/molPHPMSKebarle, 1977gas phase; M
Δr111.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr81.2 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B,M
Quantity Value Units Method Reference Comment
Δr109.J/mol*KPHPMSFrench, Ikuta, et al., 1982gas phase; M
Δr100.J/mol*KPHPMSKebarle, 1977gas phase; M
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr64.9J/mol*KPHPMSYamdagni and Kebarle, 1971gas phase; M
Quantity Value Units Method Reference Comment
Δr80.3 ± 8.4kJ/molTDAsFrench, Ikuta, et al., 1982gas phase; B
Δr77.4 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B
Δr61.9 ± 8.4kJ/molTDAsYamdagni and Kebarle, 1971gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
66.5423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M

Chlorine anion + Benzene = (Chlorine anion • Benzene)

By formula: Cl- + C6H6 = (Cl- • C6H6)

Quantity Value Units Method Reference Comment
Δr25.1 ± 1.9kJ/molN/ATschurl, Ueberfluss, et al., 2007gas phase; B
Δr39. ± 8.4kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B,M
Δr41.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr36.kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr43.5kJ/molPHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSHiraoka, Mizuse, et al., 1988, 2gas phase; M
Δr71.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Δr71.5J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr92.J/mol*KN/ASunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr17. ± 11.kJ/molTDAsHiraoka, Mizuse, et al., 1988, 2gas phase; B
Δr16. ± 6.7kJ/molIMREChowdhury and Kebarle, 1986gas phase; B
Δr20. ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr15.9kJ/molIMREFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
15.300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
16.300.PHPMSChowdhury and Kebarle, 1986gas phase; M
16.300.PHPMSSunner, Nishizawa, et al., 1981gas phase; Entropy change calculated or estimated; M

Chlorine anion + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion • L-Alanine, N-acetyl-, methyl ester)

By formula: Cl- + C6H11NO3 = (Cl- • C6H11NO3)

Quantity Value Units Method Reference Comment
Δr123.kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Δr123.kJ/molPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M
Quantity Value Units Method Reference Comment
Δr118.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Δr118.J/mol*KPHPMSMeot-ner, 1988gas phase; CH3CO-Ala-OCH3; M

(Chlorine anion • L-Alanine, N-acetyl-, methyl ester) + L-Alanine, N-acetyl-, methyl ester = (Chlorine anion • 2L-Alanine, N-acetyl-, methyl ester)

By formula: (Cl- • C6H11NO3) + C6H11NO3 = (Cl- • 2C6H11NO3)

Quantity Value Units Method Reference Comment
Δr82.8kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Δr82.8kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr113.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M
Δr113.J/mol*KPHPMSMeot-ner, 1988gas phase; M

Chlorine anion + CH3CONHCH(CH3)COOCH3 = (Chlorine anion • CH3CONHCH(CH3)COOCH3)

By formula: Cl- + C6H11NO3 = (Cl- • C6H11NO3)

Quantity Value Units Method Reference Comment
Δr123. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Δr87.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

Chlorine anion + Borane, triethyl- = (Chlorine anion • Borane, triethyl-)

By formula: Cl- + C6H15B = (Cl- • C6H15B)

Quantity Value Units Method Reference Comment
Δr99.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr99.6kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Δr92.0J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr72.0 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Δr72.0kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile, pentafluoro- = (Chlorine anion • Benzonitrile, pentafluoro-)

By formula: Cl- + C7F5N = (Cl- • C7F5N)

Quantity Value Units Method Reference Comment
Δr83.3J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr56.5 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Perfluoro(methylcyclohexane) = (Chlorine anion • Perfluoro(methylcyclohexane))

By formula: Cl- + C7F14 = (Cl- • C7F14)

Quantity Value Units Method Reference Comment
Δr<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Benzene, 1-nitro-3-(trifluoromethyl)- = (Chlorine anion • Benzene, 1-nitro-3-(trifluoromethyl)-)

By formula: Cl- + C7H4F3NO2 = (Cl- • C7H4F3NO2)

Quantity Value Units Method Reference Comment
Δr81.6 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr74.9J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr59.0 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-nitro- = (Chlorine anion • Benzonitrile, 4-nitro-)

By formula: Cl- + C7H4N2O2 = (Cl- • C7H4N2O2)

Quantity Value Units Method Reference Comment
Δr83.7 ± 4.2kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Δr83.7J/mol*KPHPMSChowdhury and Kebarle, 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr58.6 ± 6.7kJ/molTDAsChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Benzonitrile, 4-hydroxy- = (Chlorine anion • Benzonitrile, 4-hydroxy-)

By formula: Cl- + C7H5NO = (Cl- • C7H5NO)

Quantity Value Units Method Reference Comment
Δr147. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M,M
Δr148.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr120.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr110.J/mol*KN/ACummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr114. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
103.423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
110.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-Cl-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
108.300.PHPMSCummings, French, et al., 1977gas phase; switching reaction(Cl-)4-F-phenol, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Benzonitrile = (Chlorine anion • Benzonitrile)

By formula: Cl- + C7H5N = (Cl- • C7H5N)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molPHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr84.J/mol*KN/APaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
41.8300.PHPMSPaul and Kebarle, 1991gas phase; from Ph. D. thesis of S. Chowdhury, Entropy change calculated or estimated; M

Chlorine anion + Benzene, 1-methyl-4-nitro- = (Chlorine anion • Benzene, 1-methyl-4-nitro-)

By formula: Cl- + C7H7NO2 = (Cl- • C7H7NO2)

Quantity Value Units Method Reference Comment
Δr31.4kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Anisole = (Chlorine anion • Anisole)

By formula: Cl- + C7H8O = (Cl- • C7H8O)

Quantity Value Units Method Reference Comment
Δr30.5kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Cresol = (Chlorine anion • p-Cresol)

By formula: Cl- + C7H8O = (Cl- • C7H8O)

Quantity Value Units Method Reference Comment
Δr107. ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B,M
Δr108.kJ/molPHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr100.J/mol*KN/APaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
Δr112.J/mol*KPHPMSCummings, French, et al., 1977gas phase; M
Quantity Value Units Method Reference Comment
Δr74.9 ± 8.4kJ/molTDEqCummings, French, et al., 1977gas phase; Re-anchored to data in French, Ikuta, et al., 1982.; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
64.0423.PHPMSPaul and Kebarle, 1990gas phase; Entropy change calculated or estimated; M
69.5300.PHPMSCummings, French, et al., 1977gas phase; M

Chlorine anion + Toluene = (Chlorine anion • Toluene)

By formula: Cl- + C7H8 = (Cl- • C7H8)

Quantity Value Units Method Reference Comment
Δr16.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Acetophenone = (Chlorine anion • Acetophenone)

By formula: Cl- + C8H8O = (Cl- • C8H8O)

Quantity Value Units Method Reference Comment
Δr39.7kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
30.421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Ethylbenzene = (Chlorine anion • Ethylbenzene)

By formula: Cl- + C8H10 = (Cl- • C8H10)

Quantity Value Units Method Reference Comment
Δr20.9kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + p-Xylene = (Chlorine anion • p-Xylene)

By formula: Cl- + C8H10 = (Cl- • C8H10)

Quantity Value Units Method Reference Comment
Δr16.3kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
16.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, 1,3-dimethyl- = (Chlorine anion • Benzene, 1,3-dimethyl-)

By formula: Cl- + C8H10 = (Cl- • C8H10)

Quantity Value Units Method Reference Comment
Δr16.3kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
18.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzyl methyl ketone = (Chlorine anion • Benzyl methyl ketone)

By formula: Cl- + C9H10O = (Cl- • C9H10O)

Quantity Value Units Method Reference Comment
Δr44.77kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
35.421.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, (1-methylethyl)- = (Chlorine anion • Benzene, (1-methylethyl)-)

By formula: Cl- + C9H12 = (Cl- • C9H12)

Quantity Value Units Method Reference Comment
Δr23.0kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
21.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Benzene, propyl- = (Chlorine anion • Benzene, propyl-)

By formula: Cl- + C9H12 = (Cl- • C9H12)

Quantity Value Units Method Reference Comment
Δr20.9kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Mesitylene = (Chlorine anion • Mesitylene)

By formula: Cl- + C9H12 = (Cl- • C9H12)

Quantity Value Units Method Reference Comment
Δr18.8kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
19.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Diphenylmethane = (Chlorine anion • Diphenylmethane)

By formula: Cl- + C13H12 = (Cl- • C13H12)

Quantity Value Units Method Reference Comment
Δr31.0kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
31.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Triphenylmethane = (Chlorine anion • Triphenylmethane)

By formula: Cl- + C19H16 = (Cl- • C19H16)

Quantity Value Units Method Reference Comment
Δr17.2kJ/molTDEqFrench, Ikuta, et al., 1982gas phase; B

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
17.300.PHPMSFrench, Ikuta, et al., 1982gas phase; M

Chlorine anion + Phosphorus difluoride monochloride = Cl2F2P-

By formula: Cl- + ClF2P = Cl2F2P-

Quantity Value Units Method Reference Comment
Δr98.99kJ/molN/ACheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Cl2Nd = (Chlorine anion • Cl2Nd)

By formula: Cl- + Cl2Nd = (Cl- • Cl2Nd)

Quantity Value Units Method Reference Comment
Δr274. ± 15.kJ/molTDAsKudin, Pogrebnoi, et al., 1993gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Thionyl chloride = Cl3OS-

By formula: Cl- + Cl2OS = Cl3OS-

Quantity Value Units Method Reference Comment
Δr85.4 ± 7.5kJ/molCIDTBachrach, Hayes, et al., 2001gas phase; B

Chlorine anion + seleninyl dichloride = Cl3OSe-

By formula: Cl- + Cl2OSe = Cl3OSe-

Quantity Value Units Method Reference Comment
Δr149.8kJ/molN/ALobring, Hao, et al., 2003gas phase; B

Chlorine anion + Sulfur dichloride = Cl3S-

By formula: Cl- + Cl2S = Cl3S-

Quantity Value Units Method Reference Comment
Δr84.9 ± 7.9kJ/molCIDTGailbreath, Pommerening, et al., 2000gas phase; B

Chlorine anion + Selenium dichloride = Cl3Se-

By formula: Cl- + Cl2Se = Cl3Se-

Quantity Value Units Method Reference Comment
Δr133. ± 9.2kJ/molCIDTLobring, Hao, et al., 2003gas phase; B

Chlorine anion + Cl2Yb = (Chlorine anion • Cl2Yb)

By formula: Cl- + Cl2Yb = (Cl- • Cl2Yb)

Quantity Value Units Method Reference Comment
Δr>236.0kJ/molN/AKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Chlorine = (Chlorine anion • Chlorine)

By formula: Cl- + Cl2 = (Cl- • Cl2)

Quantity Value Units Method Reference Comment
Δr71.1kJ/molSAMSRobbiani and Franklin, 1979gas phase; based on Cl- + SO2Cl2 <--> Cl3- + SO2; National Bureau of Standards, 1968; M

Chlorine anion + Chlorine = Cl3-

By formula: Cl- + Cl2 = Cl3-

Quantity Value Units Method Reference Comment
Δr99.2 ± 5.0kJ/molCIDTNizzi, Pommerening, et al., 1998gas phase; B
Δr69.87kJ/molTherRobbiani and Franklin, 1979, 2gas phase; ΔG≈+1 kcal for Cl- + SO2Cl2 <=> Cl3- + SO2; B
Δr<182.4kJ/molPDisLee, Smith, et al., 1979gas phase; B

Chlorine anion + Cl3Er = Cl4Er-

By formula: Cl- + Cl3Er = Cl4Er-

Quantity Value Units Method Reference Comment
Δr344. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr327. ± 16.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl7Er2-

By formula: Cl- + Cl3Er = Cl7Er2-

Quantity Value Units Method Reference Comment
Δr239. ± 37.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr340. ± 37.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Cl3Er = Cl10Er3-

By formula: Cl- + Cl3Er = Cl10Er3-

Quantity Value Units Method Reference Comment
Δr330. ± 59.kJ/molTDAsPogrebnoi, Motalov, et al., 2002gas phase; value altered from reference due to change in acidity scale; B

Chlorine anion + Trichlorofluorosilane = Cl4FSi-

By formula: Cl- + Cl3FSi = Cl4FSi-

Quantity Value Units Method Reference Comment
Δr115. ± 7.1kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl3La = (Chlorine anion • Cl3La)

By formula: Cl- + Cl3La = (Cl- • Cl3La)

Quantity Value Units Method Reference Comment
Δr332. ± 17.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

(Chlorine anion • Cl3La) + Cl3La = (Chlorine anion • 2Cl3La)

By formula: (Cl- • Cl3La) + Cl3La = (Cl- • 2Cl3La)

Quantity Value Units Method Reference Comment
Δr136. ± 15.kJ/molMSButman, Kudin, et al., 1987gas phase; Knudsen cell; M

Chlorine anion + Cl3Lu = (Chlorine anion • Cl3Lu)

By formula: Cl- + Cl3Lu = (Cl- • Cl3Lu)

Quantity Value Units Method Reference Comment
Δr297. ± 15.kJ/molTDAsPogrebnoi, Kudion, et al., 1997gas phase; EA estimated as 3.7±1.0 eV; value altered from reference due to conversion from electron convention to ion convention; B
Δr359. ± 10.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Phosphorus oxychloride = Cl4OP-

By formula: Cl- + Cl3OP = Cl4OP-

Quantity Value Units Method Reference Comment
Δr43.1 ± 5.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Thiophosphoryl chloride = Cl4PS-

By formula: Cl- + Cl3PS = Cl4PS-

Quantity Value Units Method Reference Comment
Δr41.0 ± 4.0kJ/molCIDTCheck, Lobring, et al., 2003gas phase; B

Chlorine anion + Phosphorus trichloride = Cl4P-

By formula: Cl- + Cl3P = Cl4P-

Quantity Value Units Method Reference Comment
Δr90.0 ± 7.1kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sb = Cl4Sb-

By formula: Cl- + Cl3Sb = Cl4Sb-

Quantity Value Units Method Reference Comment
Δr160. ± 7.9kJ/molCIDTWalker, Check, et al., 2002gas phase; B

Chlorine anion + Cl3Sm = Cl4Sm-

By formula: Cl- + Cl3Sm = Cl4Sm-

Quantity Value Units Method Reference Comment
Δr289. ± 16.kJ/molTDEqKhasanshin, Pogrebnoi, et al., 1998gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr362. ± 21.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Tb = Cl4Tb-

By formula: Cl- + Cl3Tb = Cl4Tb-

Quantity Value Units Method Reference Comment
Δr353. ± 18.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr304. ± 6.7kJ/molTDEqKhasanshin, Kudin, et al., 1999gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Cl3Yb = (Chlorine anion • Cl3Yb)

By formula: Cl- + Cl3Yb = (Cl- • Cl3Yb)

Quantity Value Units Method Reference Comment
Δr311. ± 30.kJ/molTDAsKuznetsov, Kudin, et al., 1997gas phase; value altered from reference due to conversion from electron convention to ion convention; B
Δr348. ± 19.kJ/molTDEqKudin, Vorob'ev, et al., 2007gas phase; value altered from reference due to conversion from electron convention to ion convention; B

Chlorine anion + Germanium tetrachloride = Cl5Ge-

By formula: Cl- + Cl4Ge = Cl5Ge-

Quantity Value Units Method Reference Comment
Δr141. ± 5.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Silicon tetrachloride = (Chlorine anion • Silicon tetrachloride)

By formula: Cl- + Cl4Si = (Cl- • Cl4Si)

Quantity Value Units Method Reference Comment
Δr105. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B
Δr101. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Quantity Value Units Method Reference Comment
Δr73.6 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B

Chlorine anion + Tin(IV) chloride = Cl5Sn-

By formula: Cl- + Cl4Sn = Cl5Sn-

Quantity Value Units Method Reference Comment
Δr235. ± 7.9kJ/molCIDTHao, Kaspar, et al., 2005gas phase; B

Chlorine anion + Cl4Th = (Chlorine anion • Cl4Th)

By formula: Cl- + Cl4Th = (Cl- • Cl4Th)

Quantity Value Units Method Reference Comment
Δr101.kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr73.6kJ/molICRLarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(t-C4H9OH), Entropy change calculated or estimated; M

Chlorine anion + Hydrochloric acid-d = (Chlorine anion • Hydrochloric acid-d)

By formula: Cl- + DCl = (Cl- • DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
70.3300.ICRLarson and McMahon, 1987gas phase; switching reaction(Cl-)HCl; Caldwell and Kebarle, 1985; M

Chlorine anion + Deuterium oxide = (Chlorine anion • Deuterium oxide)

By formula: Cl- + D2O = (Cl- • D2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr61.50 ± 0.84kJ/molIMRELarson and McMahon, 1988gas phase; Anchored to Keesee and Castleman, 19802: HOH..Cl- + DOD <=> DOD..Cl- + HOH, Keq=0.77; B

Chlorine anion + Thionyl fluoride = (Chlorine anion • Thionyl fluoride)

By formula: Cl- + F2OS = (Cl- • F2OS)

Quantity Value Units Method Reference Comment
Δr71.5 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr96.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr42.7 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphoryl fluoride = (Chlorine anion • Phosphoryl fluoride)

By formula: Cl- + F3OP = (Cl- • F3OP)

Quantity Value Units Method Reference Comment
Δr58.2 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr88.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr32. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + Phosphorus trifluoride = (Chlorine anion • Phosphorus trifluoride)

By formula: Cl- + F3P = (Cl- • F3P)

Quantity Value Units Method Reference Comment
Δr64.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr64.9kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr87.9J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Quantity Value Units Method Reference Comment
Δr38. ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B
Δr38.kJ/molICRLarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M

Chlorine anion + Silicon tetrafluoride = (Chlorine anion • Silicon tetrafluoride)

By formula: Cl- + F4Si = (Cl- • F4Si)

Quantity Value Units Method Reference Comment
Δr97.9 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M
Quantity Value Units Method Reference Comment
Δr92.J/mol*KN/ALarson and McMahon, 1985gas phase; switching reaction,Thermochemical ladder(Cl-)t-C4H9OH, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr70.3 ± 8.4kJ/molIMRELarson and McMahon, 1985gas phase; B,M

Chlorine anion + F6S- = (Chlorine anion • F6S-)

By formula: Cl- + F6S- = (Cl- • F6S-)

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
7.5300.PHPMSChowdhury and Kebarle, 1986gas phase; DG<; M

Chlorine anion + Sulfur hexafluoride = (Chlorine anion • Sulfur hexafluoride)

By formula: Cl- + F6S = (Cl- • F6S)

Quantity Value Units Method Reference Comment
Δr<7.53kJ/molIMRBChowdhury and Kebarle, 1986gas phase; B

Chlorine anion + Hydrogen chloride = (Chlorine anion • Hydrogen chloride)

By formula: Cl- + HCl = (Cl- • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr124. ± 4.2kJ/molN/AMetz, Kitsopoulos, et al., 1988gas phase; Affinity: shift in apparent EA from lesser-solvated ion. Ignores any neutral-neutral bond.; B
Δr99.6 ± 8.4kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B,M
Δr96.7 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr99.16 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr85.4kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl-)SO2; M
Δr98.3J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Δr98.3J/mol*KN/ALarson and McMahon, 1984, 2gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δr95.4J/mol*KN/AUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Δr68.2 ± 8.4kJ/molIMRELarson and McMahon, 1987gas phase; K = 0.60 for HCl..Cl- + DCL <=> DCl..Cl- + HCl, anchored to Larson and McMahon, 1984, 32; B
Δr72. ± 11.kJ/molTDEqCaldwell and Kebarle, 1985gas phase; B
Δr66.9 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Δr69.9 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B
Δr56.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl-)H2O/HCl, Entropy change calculated or estimated; Keesee and Castleman, 1980, 2; M

(Chlorine anion • Hydrogen chloride) + Hydrogen chloride = (Chlorine anion • 2Hydrogen chloride)

By formula: (Cl- • HCl) + HCl = (Cl- • 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr63.60 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Δr58.6kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; switching reaction(Cl- HCl)SO2; M
Δr102.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr33.1 ± 0.84kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion • 2Hydrogen chloride) + Hydrogen chloride = (Chlorine anion • 3Hydrogen chloride)

By formula: (Cl- • 2HCl) + HCl = (Cl- • 3HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr49.0 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr97.9J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr19.7 ± 1.3kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion • 3Hydrogen chloride) + Hydrogen chloride = (Chlorine anion • 4Hydrogen chloride)

By formula: (Cl- • 3HCl) + HCl = (Cl- • 4HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.1 ± 2.9kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B,M
Quantity Value Units Method Reference Comment
Δr112.J/mol*KPHPMSYamdagni and Kebarle, 1974gas phase; M
Quantity Value Units Method Reference Comment
Δr9.6 ± 4.2kJ/molTDAsYamdagni and Kebarle, 1974gas phase; B

(Chlorine anion • Hydrogen chloride) + Water = (Chlorine anion • Water • Hydrogen chloride)

By formula: (Cl- • HCl) + H2O = (Cl- • H2O • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr78.2J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion • 2Hydrogen chloride) + Water = (Chlorine anion • Water • 2Hydrogen chloride)

By formula: (Cl- • 2HCl) + H2O = (Cl- • H2O • 2HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr32.kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Δr63.6J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in Keesee and Castleman, 1986; M

(Chlorine anion • Hydrogen chloride • Water) + Hydrogen chloride = (Chlorine anion • 2Hydrogen chloride • Water)

By formula: (Cl- • HCl • H2O) + HCl = (Cl- • 2HCl • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle,switching reaction(Cl- H2O) HCl, deuterated; Yamdagni and Kebarle, 1974; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle,switching reaction(Cl- H2O) HCl, deuterated; Yamdagni and Kebarle, 1974; M

(Chlorine anion • Hydrogen chloride) + Sulfur dioxide = (Chlorine anion • Sulfur dioxide • Hydrogen chloride)

By formula: (Cl- • HCl) + O2S = (Cl- • O2S • HCl)

Quantity Value Units Method Reference Comment
Δr51.5kJ/molPHPMSCaldwell and Kebarle, 1985gas phase; M
Quantity Value Units Method Reference Comment
Δr77.4J/mol*KPHPMSCaldwell and Kebarle, 1985gas phase; M

Chlorine anion + hydrogen fluoride = (Chlorine anion • hydrogen fluoride)

By formula: Cl- + HF = (Cl- • HF)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr91.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M
Quantity Value Units Method Reference Comment
Δr94.1J/mol*KN/ALarson and McMahon, 1984gas phase; switching reaction(Cl-)SO2, Entropy change calculated or estimated; Larson and McMahon, 1984, 2; M
Quantity Value Units Method Reference Comment
Δr63.2 ± 8.4kJ/molIMRELarson and McMahon, 1984gas phase; B,M

Chlorine anion + Water = (Chlorine anion • Water)

By formula: Cl- + H2O = (Cl- • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr60. ± 20.kJ/molAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δr81. ± 10.J/mol*KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Δr40. ± 20.kJ/molAVGN/AAverage of 9 values; Individual data points

(Chlorine anion • Water) + Methyl Alcohol = (Chlorine anion • Methyl Alcohol • Water)

By formula: (Cl- • H2O) + CH4O = (Cl- • CH4O • H2O)

Quantity Value Units Method Reference Comment
Δr55.2kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr87.4J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • 2Water) + Methyl Alcohol = (Chlorine anion • Methyl Alcohol • 2Water)

By formula: (Cl- • 2H2O) + CH4O = (Cl- • CH4O • 2H2O)

Quantity Value Units Method Reference Comment
Δr47.7kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr75.7J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • Water • Methyl Alcohol) + Water = (Chlorine anion • 2Water • Methyl Alcohol)

By formula: (Cl- • H2O • CH4O) + H2O = (Cl- • 2H2O • CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr43.5kJ/molHPMSEvans and Keesee, 1991gas phase; M
Quantity Value Units Method Reference Comment
Δr64.9J/mol*KHPMSEvans and Keesee, 1991gas phase; M

(Chlorine anion • Water) + Hydrogen chloride = (Chlorine anion • Hydrogen chloride • Water)

By formula: (Cl- • H2O) + HCl = (Cl- • HCl • H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr66.9kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Δr91.2J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; M

(Chlorine anion • 2Water) + Hydrogen chloride = (Chlorine anion • Hydrogen chloride • 2Water)

By formula: (Cl- • 2H2O) + HCl = (Cl- • HCl • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr54.4kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl- 2H2O)H2O, deuterated; Keesee and Castleman, 1980, 2; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; From thermochemical cycle(Cl- 2H2O)H2O, deuterated; Keesee and Castleman, 1980, 2; M

(Chlorine anion • Water • Hydrogen chloride) + Water = (Chlorine anion • 2Water • Hydrogen chloride)

By formula: (Cl- • H2O • HCl) + H2O = (Cl- • 2H2O • HCl)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40.kJ/molHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in 86 KEE/CAS; M
Quantity Value Units Method Reference Comment
Δr85.4J/mol*KHPMSUpschulte, Evans, et al., 1986gas phase; deuterated, quoted in 86 KEE/CAS; M

(Chlorine anion • Water) + Water = (Chlorine anion • 2Water)

By formula: (Cl- • H2O) + H2O = (Cl- • 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr53. ± 5.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr89.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr85.8J/mol*KHPMSKeesee and Castleman, 1980, 2gas phase; M
Δr87.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr28. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr27.2kJ/molTDAsKeesee and Castleman, 1980, 2gas phase; B
Δr27. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Δr27.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr28.kJ/molFAFehsenfeld and Ferguson, 1974gas phase; M

(Chlorine anion • 2Water) + Water = (Chlorine anion • 3Water)

By formula: (Cl- • 2H2O) + H2O = (Cl- • 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr48. ± 7.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δr93.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr93.7J/mol*KHPMSKeesee and Castleman, 1980, 2gas phase; M
Δr97.1J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr21. ± 2.kJ/molAVGN/AAverage of 6 values; Individual data points

(Chlorine anion • 3Water) + Water = (Chlorine anion • 4Water)

By formula: (Cl- • 3H2O) + H2O = (Cl- • 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr44.4 ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr40.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr44. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr45.6 ± 2.9kJ/molTDAsKeesee and Castleman, 1980, 2gas phase; B,M
Δr46.4 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Δr95.0J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Δr104.J/mol*KHPMSKeesee and Castleman, 1980, 2gas phase; M
Δr108.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Δr16. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr14.6kJ/molTDAsKeesee and Castleman, 1980, 2gas phase; B
Δr14.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Δr17. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Chlorine anion • 4Water) + Water = (Chlorine anion • 5Water)

By formula: (Cl- • 4H2O) + H2O = (Cl- • 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Δr40. ± 4.2kJ/molTDAsHiraoka and Mizuse, 1987gas phase; B
Δr28.0kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Δr40. ± 1.kJ/molPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Δr90.8J/mol*K