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Water

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Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
B - John E. Bartmess
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Silver ion (1+) + Water = (Silver ion (1+) bullet Water)

By formula: Ag+ + H2O = (Ag+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar139.kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet Water) + Water = (Silver ion (1+) bullet 2Water)

By formula: (Ag+ bullet H2O) + H2O = (Ag+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar106.kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 2Water) + Water = (Silver ion (1+) bullet 3Water)

By formula: (Ag+ bullet 2H2O) + H2O = (Ag+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar62.8kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 3Water) + Water = (Silver ion (1+) bullet 4Water)

By formula: (Ag+ bullet 3H2O) + H2O = (Ag+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar62.3kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 4Water) + Water = (Silver ion (1+) bullet 5Water)

By formula: (Ag+ bullet 4H2O) + H2O = (Ag+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar57.3kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar127.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

(Silver ion (1+) bullet 5Water) + Water = (Silver ion (1+) bullet 6Water)

By formula: (Ag+ bullet 5H2O) + H2O = (Ag+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar55.6kJ/molHPMSHolland and Castleman, 1982gas phase; M
Quantity Value Units Method Reference Comment
Deltar135.J/mol*KHPMSHolland and Castleman, 1982gas phase; M

Aluminum ion (1+) + Water = (Aluminum ion (1+) bullet Water)

By formula: Al+ + H2O = (Al+ bullet H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
104. (+15.,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet Water) + Water = (Aluminum ion (1+) bullet 2Water)

By formula: (Al+ bullet H2O) + H2O = (Al+ bullet 2H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
67.4 (+5.0,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet 2Water) + Water = (Aluminum ion (1+) bullet 3Water)

By formula: (Al+ bullet 2H2O) + H2O = (Al+ bullet 3H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
63.6 (+7.5,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

(Aluminum ion (1+) bullet 3Water) + Water = (Aluminum ion (1+) bullet 4Water)

By formula: (Al+ bullet 3H2O) + H2O = (Al+ bullet 4H2O)

Enthalpy of reaction

DeltarH° (kJ/mol) T (K) Method Reference Comment
52.3 (+5.9,-0.) CIDDalleska, Tjelta, et al., 1994gas phase; guided ion beam CID, Al+ (3s2); M

Bismuth ion (1+) + Water = (Bismuth ion (1+) bullet Water)

By formula: Bi+ + H2O = (Bi+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar95.4kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet Water) + Water = (Bismuth ion (1+) bullet 2Water)

By formula: (Bi+ bullet H2O) + H2O = (Bi+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar74.1kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 2Water) + Water = (Bismuth ion (1+) bullet 3Water)

By formula: (Bi+ bullet 2H2O) + H2O = (Bi+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar58.6kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 3Water) + Water = (Bismuth ion (1+) bullet 4Water)

By formula: (Bi+ bullet 3H2O) + H2O = (Bi+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar50.2kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 4Water) + Water = (Bismuth ion (1+) bullet 5Water)

By formula: (Bi+ bullet 4H2O) + H2O = (Bi+ bullet 5H2O)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KHPMSTang and Castleman, 1974gas phase; M

(Bismuth ion (1+) bullet 5Water) + Water = (Bismuth ion (1+) bullet 6Water)

By formula: (Bi+ bullet 5H2O) + H2O = (Bi+ bullet 6H2O)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molHPMSTang and Castleman, 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KHPMSTang and Castleman, 1974gas phase; M

Bromine anion + Water = (Bromine anion bullet Water)

By formula: Br- + H2O = (Br- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar53.14kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar49.0 ± 1.7kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar52.72kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Deltar53.1kJ/molHPMSCaldwell, Masucci, et al., 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar61.5J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar77.0J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Deltar82.8J/mol*KMSBurdett and Hayhurst, 1982gas phase; FLAME SOURCE, 1600 K; M
Quantity Value Units Method Reference Comment
Deltar30.5 ± 3.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar29. ± 12.kJ/molTDAsBurdett and Hayhurst, 1982gas phase; B
Deltar29. ± 8.4kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B

(Bromine anion bullet Water) + Water = (Bromine anion bullet 2Water)

By formula: (Br- bullet H2O) + H2O = (Br- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar51.04kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar51.5 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar51.5 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar75.3J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar95.8J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar26. ± 4.2kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar23. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar22.6kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar24. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 2Water) + Water = (Bromine anion bullet 3Water)

By formula: (Br- bullet 2H2O) + H2O = (Br- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.7 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar28.9kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar48.1 ± 4.2kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar48.1 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar94.1J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar104.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar20. ± 4.6kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar17. ± 5.9kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B
Deltar17.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar18. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 3Water) + Water = (Bromine anion bullet 4Water)

By formula: (Br- bullet 3H2O) + H2O = (Br- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.02 ± 0.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Deltar45.6 ± 4.2kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Deltar112.J/mol*KHPMSArshadi, Yamdagni, et al., 1970gas phase; M
Quantity Value Units Method Reference Comment
Deltar13.0 ± 2.9kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B
Deltar12.1kJ/molTDAsArshadi, Yamdagni, et al., 1970gas phase; B
Deltar14. ± 8.4kJ/molTDAsKebarle, Arshadi, et al., 1968gas phase; B,M

(Bromine anion bullet 4Water) + Water = (Bromine anion bullet 5Water)

By formula: (Br- bullet 4H2O) + H2O = (Br- bullet 5H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.2 ± 1.3kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar26. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar119.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar9.6 ± 5.0kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 5Water) + Water = (Bromine anion bullet 6Water)

By formula: (Br- bullet 5H2O) + H2O = (Br- bullet 6H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1 ± 2.1kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B,M
Deltar25. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KPHPMSHiraoka, Mizuse, et al., 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar7.5 ± 8.8kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; B

(Bromine anion bullet 6Water) + Water = (Bromine anion bullet 7Water)

By formula: (Br- bullet 6H2O) + H2O = (Br- bullet 7H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.84kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B,M
Deltar10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; B
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KN/AHiraoka, Mizuse, et al., 1988gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar5.44kJ/molTDAsHiraoka, Mizuse, et al., 1988gas phase; Entropy estimated; B

(Bromine anion bullet 7Water) + Water = (Bromine anion bullet 8Water)

By formula: (Br- bullet 7H2O) + H2O = (Br- bullet 8H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 8Water) + Water = (Bromine anion bullet 9Water)

By formula: (Br- bullet 8H2O) + H2O = (Br- bullet 9H2O)

Quantity Value Units Method Reference Comment
Deltar3. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 9Water) + Water = (Bromine anion bullet 10Water)

By formula: (Br- bullet 9H2O) + H2O = (Br- bullet 10H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 10Water) + Water = (Bromine anion bullet 11Water)

By formula: (Br- bullet 10H2O) + H2O = (Br- bullet 11H2O)

Quantity Value Units Method Reference Comment
Deltar6.7 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 11Water) + Water = (Bromine anion bullet 12Water)

By formula: (Br- bullet 11H2O) + H2O = (Br- bullet 12H2O)

Quantity Value Units Method Reference Comment
Deltar10. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 12Water) + Water = (Bromine anion bullet 13Water)

By formula: (Br- bullet 12H2O) + H2O = (Br- bullet 13H2O)

Quantity Value Units Method Reference Comment
Deltar7.5 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 13Water) + Water = (Bromine anion bullet 14Water)

By formula: (Br- bullet 13H2O) + H2O = (Br- bullet 14H2O)

Quantity Value Units Method Reference Comment
Deltar13. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 14Water) + Water = (Bromine anion bullet 15Water)

By formula: (Br- bullet 14H2O) + H2O = (Br- bullet 15H2O)

Quantity Value Units Method Reference Comment
Deltar-2. ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

(Bromine anion bullet 15Water) + Water = (Bromine anion bullet 16Water)

By formula: (Br- bullet 15H2O) + H2O = (Br- bullet 16H2O)

Quantity Value Units Method Reference Comment
Deltar9.6 ± 9.6kJ/molN/AMarkovich, Pollack, et al., 1994gas phase; For photodissociation plus electron loss. Affinity is difference from lower solvated ion.; B

Trifluoromethyl cation + Water = (Trifluoromethyl cation bullet Water)

By formula: CF3+ + H2O = (CF3+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar19.kJ/molHPMSBennet and Field, 1972gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KHPMSBennet and Field, 1972gas phase; M

CF3O- + Water = CH2F3O2-

By formula: CF3O- + H2O = CH2F3O2-

Quantity Value Units Method Reference Comment
Deltar28. ± 4.2kJ/molN/AAmelynck, Van Bavel, et al., 2000gas phase; B

CF3O3S- + Water = (CF3O3S- bullet Water)

By formula: CF3O3S- + H2O = (CF3O3S- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

(CF3O3S- bullet Water) + Water = (CF3O3S- bullet 2Water)

By formula: (CF3O3S- bullet H2O) + H2O = (CF3O3S- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar45.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar15.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

HCO2 anion + Water = (HCO2 anion bullet Water)

By formula: CHO2- + H2O = (CHO2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar66.9 ± 4.2kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar38. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Deltar35.1 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B
Deltar38.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(HCO2 anion bullet Water) + Water = (HCO2 anion bullet 2Water)

By formula: (CHO2- bullet H2O) + H2O = (CHO2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar28.9 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(HCO2 anion bullet 2Water) + Water = (HCO2 anion bullet 3Water)

By formula: (CHO2- bullet 2H2O) + H2O = (CHO2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar50.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar21.8 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

CHO3- + Water = CH3O4-

By formula: CHO3- + H2O = CH3O4-

Quantity Value Units Method Reference Comment
Deltar65.69 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar35.6 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

(CH2N+ bullet Hydrogen cyanide) + Water = (CH2N+ bullet Water bullet Hydrogen cyanide)

By formula: (CH2N+ bullet CHN) + H2O = (CH2N+ bullet H2O bullet CHN)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar84.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CH2N+ + Water = (CH2N+ bullet Water)

By formula: CH2N+ + H2O = (CH2N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar115.kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar124.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar120.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
87.9300.ICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2N+ bullet Water bullet Hydrogen cyanide) + Water = (CH2N+ bullet 2Water bullet Hydrogen cyanide)

By formula: (CH2N+ bullet H2O bullet CHN) + H2O = (CH2N+ bullet 2H2O bullet CHN)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar70.7kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ bullet Water) + Water = (CH2N+ bullet 2Water)

By formula: (CH2N+ bullet H2O) + H2O = (CH2N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar89.5kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CH2N+ bullet 2Water) + Water = (CH2N+ bullet 3Water)

By formula: (CH2N+ bullet 2H2O) + H2O = (CH2N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar72.0kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CH2NO5- + Water + Formic acid = CH4NO6-

By formula: CH2NO5- + H2O + CH2O2 = CH4NO6-

Quantity Value Units Method Reference Comment
Deltar18.4 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

CH2O2S- + 2Water = CH4O3S-

By formula: CH2O2S- + 2H2O = CH4O3S-

Quantity Value Units Method Reference Comment
Deltar44.8 ± 8.4kJ/molN/ASurber and Sanov, 2002gas phase; Stated electron affinity is the Vertical Detachment Energy; B

CH2O4- + 2Water = CH4O5-

By formula: CH2O4- + 2H2O = CH4O5-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 2.1kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar20. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH2OH+ + Water = (CH2OH+ bullet Water)

By formula: CH3O+ + H2O = (CH3O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar119.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; switching reaction(H3O+)H2O; Davidson, Sunner J., et al., 1979, Lias, Liebman, et al., 1984; M
Deltar117.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction((CH3)2O)2H+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Yamdagni and Kebarle, 1976, Wolf, Staley, et al., 1977; M
Deltar119.kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar120.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar120.kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KN/ABerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar113.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar112.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar85.4kJ/molICRBerman and Beauchamp, 1980gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar85.8kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ bullet Water) + Water = (CH2OH+ bullet 2Water)

By formula: (CH3O+ bullet H2O) + H2O = (CH3O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar83.3kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar82.8kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar110.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar110.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar50.6kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)2H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ bullet 2Water) + Water = (CH2OH+ bullet 3Water)

By formula: (CH3O+ bullet 2H2O) + H2O = (CH3O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar73.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar70.7kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar71.1kJ/molFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar109.J/mol*KN/ABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M
Deltar109.J/mol*KFAFehsenfeld, Dotan, et al., 1978gas phase; From thermochemical cycle,switching reaction(H3O+)H2O; Lias, Liebman, et al., 1984, Meot-Ner (Mautner), 1992; M
Quantity Value Units Method Reference Comment
Deltar38.kJ/molFABohme, Mackay, et al., 1979gas phase; From thermochemical cycle,switching reaction(H3O+)3H2O, Entropy change calculated or estimated; Lias, Liebman, et al., 1984, Fehsenfeld, Dotan, et al., 1978, Meot-Ner (Mautner), 1992; M

(CH2OH+ bullet 3Water) + Water = (CH2OH+ bullet 4Water)

By formula: (CH3O+ bullet 3H2O) + H2O = (CH3O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ bullet 4Water) + Water = (CH2OH+ bullet 5Water)

By formula: (CH3O+ bullet 4H2O) + H2O = (CH3O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ bullet 5Water) + Water = (CH2OH+ bullet 6Water)

By formula: (CH3O+ bullet 5H2O) + H2O = (CH3O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH2OH+ bullet 6Water) + Water = (CH2OH+ bullet 7Water)

By formula: (CH3O+ bullet 6H2O) + H2O = (CH3O+ bullet 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH3O- bullet Methyl Alcohol) + Water = (CH3O- bullet Water bullet Methyl Alcohol)

By formula: (CH3O- bullet CH4O) + H2O = (CH3O- bullet H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar74.5kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet 2Methyl Alcohol) + Water = (CH3O- bullet Water bullet 2Methyl Alcohol)

By formula: (CH3O- bullet 2CH4O) + H2O = (CH3O- bullet H2O bullet 2CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar57.7kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH3O- + Water = (CH3O- bullet Water)

By formula: CH3O- + H2O = (CH3O- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar106. ± 9.2kJ/molCIDTDeTuri and Ervin, 1999gas phase; B
Deltar100.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M,B,M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSMeot-ner and Sieck, 1986gas phase; M
Deltar95.8J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar71.1 ± 1.3kJ/molTDAsMeot-ner and Sieck, 1986gas phase; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
64.4296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)H2O, DG>; Meot-Ner(Mautner), 1986; M

(CH3O- bullet Water bullet Methyl Alcohol) + Water = (CH3O- bullet 2Water bullet Methyl Alcohol)

By formula: (CH3O- bullet H2O bullet CH4O) + H2O = (CH3O- bullet 2H2O bullet CH4O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar63.6kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH3O- bullet Water) + Water = (CH3O- bullet 2Water)

By formula: (CH3O- bullet H2O) + H2O = (CH3O- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar80.3kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
34.296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)2H2O; Meot-Ner(Mautner), 1986; M

(CH3O- bullet 2Water) + Water = (CH3O- bullet 3Water)

By formula: (CH3O- bullet 2H2O) + H2O = (CH3O- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.9kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.296.FAMacKay and Bohme, 1978gas phase; From thermochemical cycle,switching reaction(OH-)3H2O; Meot-Ner(Mautner), 1986; M

(CH3O- bullet 3Water) + Water = (CH3O- bullet 4Water)

By formula: (CH3O- bullet 3H2O) + H2O = (CH3O- bullet 4H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar83.7J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH3O3S- + Water = (CH3O3S- bullet Water)

By formula: CH3O3S- + H2O = (CH3O3S- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar58.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar28.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

(CH3O3S- bullet Water) + Water = (CH3O3S- bullet 2Water)

By formula: (CH3O3S- bullet H2O) + H2O = (CH3O3S- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar22.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

(CH3O3S- bullet 2Water) + Water = (CH3O3S- bullet 3Water)

By formula: (CH3O3S- bullet 2H2O) + H2O = (CH3O3S- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar47.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar18.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

CH3O4- + 2Water = CH5O5-

By formula: CH3O4- + 2H2O = CH5O5-

Quantity Value Units Method Reference Comment
Deltar62.34 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar26. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

MeS anion + Water = (MeS anion bullet Water)

By formula: CH3S- + H2O = (CH3S- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar62.76 ± 0.84kJ/molTDAsSieck and Meot-ner, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar36.4 ± 2.9kJ/molTDAsSieck and Meot-ner, 1989gas phase; B

(MeS anion bullet Water) + Water = (MeS anion bullet 2Water)

By formula: (CH3S- bullet H2O) + H2O = (CH3S- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar56.5kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion bullet 2Water) + Water = (MeS anion bullet 3Water)

By formula: (CH3S- bullet 2H2O) + H2O = (CH3S- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar46.4kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar85.8J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

(MeS anion bullet 3Water) + Water = (MeS anion bullet 4Water)

By formula: (CH3S- bullet 3H2O) + H2O = (CH3S- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSSieck and Meot-ner, 1989gas phase; M
Quantity Value Units Method Reference Comment
Deltar80.3J/mol*KPHPMSSieck and Meot-ner, 1989gas phase; M

CH4NO+ + Water = (CH4NO+ bullet Water)

By formula: CH4NO+ + H2O = (CH4NO+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar88.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar89.1kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar114.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ bullet Water) + Water = (CH4NO+ bullet 2Water)

By formula: (CH4NO+ bullet H2O) + H2O = (CH4NO+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar58.6kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar58.6kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar95.0J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ bullet 2Water) + Water = (CH4NO+ bullet 3Water)

By formula: (CH4NO+ bullet 2H2O) + H2O = (CH4NO+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.4kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar49.4kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar87.9J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ bullet 3Water) + Water = (CH4NO+ bullet 4Water)

By formula: (CH4NO+ bullet 3H2O) + H2O = (CH4NO+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar41.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar84.5J/mol*KPHPMSMeot-Ner, 1984gas phase; M

(CH4NO+ bullet 4Water) + Water = (CH4NO+ bullet 5Water)

By formula: (CH4NO+ bullet 4H2O) + H2O = (CH4NO+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar41.kJ/molPHPMSMeot-Ner, 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar107.J/mol*KPHPMSMeot-Ner, 1984gas phase; M

CH4O5- + 3Water = CH6O6-

By formula: CH4O5- + 3H2O = CH6O6-

Quantity Value Units Method Reference Comment
Deltar54.8 ± 3.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

(CH5O+ bullet Methyl Alcohol) + Water = (CH5O+ bullet Water bullet Methyl Alcohol)

By formula: (CH5O+ bullet CH4O) + H2O = (CH5O+ bullet H2O bullet CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar77.0kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 3Methyl Alcohol) + Water = (CH5O+ bullet Water bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 3CH4O) + H2O = (CH5O+ bullet H2O bullet 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar50.6kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 4Methyl Alcohol) + Water = (CH5O+ bullet Water bullet 4Methyl Alcohol)

By formula: (CH5O+ bullet 4CH4O) + H2O = (CH5O+ bullet H2O bullet 4CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.8kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

CH5O+ + Water = (CH5O+ bullet Water)

By formula: CH5O+ + H2O = (CH5O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar115.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar100.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar123.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar96.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet Water bullet 2Methyl Alcohol) + Water = (CH5O+ bullet 2Water bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet H2O bullet 2CH4O) + H2O = (CH5O+ bullet 2H2O bullet 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.4kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet Water bullet 3Methyl Alcohol) + Water = (CH5O+ bullet 2Water bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet H2O bullet 3CH4O) + H2O = (CH5O+ bullet 2H2O bullet 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 2Water bullet Methyl Alcohol) + Water = (CH5O+ bullet 3Water bullet Methyl Alcohol)

By formula: (CH5O+ bullet 2H2O bullet CH4O) + H2O = (CH5O+ bullet 3H2O bullet CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.9kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 2Water bullet 2Methyl Alcohol) + Water = (CH5O+ bullet 3Water bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet 2H2O bullet 2CH4O) + H2O = (CH5O+ bullet 3H2O bullet 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 2Water bullet 3Methyl Alcohol) + Water = (CH5O+ bullet 3Water bullet 3Methyl Alcohol)

By formula: (CH5O+ bullet 2H2O bullet 3CH4O) + H2O = (CH5O+ bullet 3H2O bullet 3CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet 3Water bullet Methyl Alcohol) + Water = (CH5O+ bullet 4Water bullet Methyl Alcohol)

By formula: (CH5O+ bullet 3H2O bullet CH4O) + H2O = (CH5O+ bullet 4H2O bullet CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.5kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KPHPMSMeot-Ner(Mautner), 1986gas phase; n; M

(CH5O+ bullet 3Water bullet 2Methyl Alcohol) + Water = (CH5O+ bullet 4Water bullet 2Methyl Alcohol)

By formula: (CH5O+ bullet 3H2O bullet 2CH4O) + H2O = (CH5O+ bullet 4H2O bullet 2CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.272.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet 4Water bullet Methyl Alcohol) + Water = (CH5O+ bullet 5Water bullet Methyl Alcohol)

By formula: (CH5O+ bullet 4H2O bullet CH4O) + H2O = (CH5O+ bullet 5H2O bullet CH4O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.269.PHPMSMeot-Ner(Mautner), 1986gas phase; n, Entropy change calculated or estimated; M

(CH5O+ bullet Water) + Water = (CH5O+ bullet 2Water)

By formula: (CH5O+ bullet H2O) + H2O = (CH5O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar82.8kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar87.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar121.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet 2Water) + Water = (CH5O+ bullet 3Water)

By formula: (CH5O+ bullet 2H2O) + H2O = (CH5O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.0kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar61.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet 3Water) + Water = (CH5O+ bullet 4Water)

By formula: (CH5O+ bullet 3H2O) + H2O = (CH5O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar48.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar92.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet 4Water) + Water = (CH5O+ bullet 5Water)

By formula: (CH5O+ bullet 4H2O) + H2O = (CH5O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar77.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet 5Water) + Water = (CH5O+ bullet 6Water)

By formula: (CH5O+ bullet 5H2O) + H2O = (CH5O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar92.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH5O+ bullet 6Water) + Water = (CH5O+ bullet 7Water)

By formula: (CH5O+ bullet 6H2O) + H2O = (CH5O+ bullet 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

CH5O2- + 2Water = CH7O3-

By formula: CH5O2- + 2H2O = CH7O3-

Quantity Value Units Method Reference Comment
Deltar80.3 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar49.0 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

CH5O5- + 3Water = CH7O6-

By formula: CH5O5- + 3H2O = CH7O6-

Quantity Value Units Method Reference Comment
Deltar56.9 ± 1.3kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar19. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH5S+ + Water = (CH5S+ bullet Water)

By formula: CH5S+ + H2O = (CH5S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar64.9kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M
Deltar56.5kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/AMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
22.476.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; Entropy change calculated or estimated; M

CH6N+ + Water = (CH6N+ bullet Water)

By formula: CH6N+ + H2O = (CH6N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar70.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Deltar78.7kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Deltar110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar44.8kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ bullet Water) + Water = (CH6N+ bullet 2Water)

By formula: (CH6N+ bullet H2O) + H2O = (CH6N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Deltar61.1kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Deltar112.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar31.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ bullet 2Water) + Water = (CH6N+ bullet 3Water)

By formula: (CH6N+ bullet 2H2O) + H2O = (CH6N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Deltar51.9kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Deltar110.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar22.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(CH6N+ bullet 3Water) + Water = (CH6N+ bullet 4Water)

By formula: (CH6N+ bullet 3H2O) + H2O = (CH6N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar92.0J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(CH6N+ bullet 4Water) + Water = (CH6N+ bullet 5Water)

By formula: (CH6N+ bullet 4H2O) + H2O = (CH6N+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar38.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.269.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(CH6N+ bullet 5Water) + Water = (CH6N+ bullet 6Water)

By formula: (CH6N+ bullet 5H2O) + H2O = (CH6N+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar36.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.259.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

CH7O3- + 3Water = CH9O4-

By formula: CH7O3- + 3H2O = CH9O4-

Quantity Value Units Method Reference Comment
Deltar61.9 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar31.4 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

CH7O6- + 4Water = CH9O7-

By formula: CH7O6- + 4H2O = CH9O7-

Quantity Value Units Method Reference Comment
Deltar56.1 ± 3.8kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Quantity Value Units Method Reference Comment
Deltar14. ± 4.2kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B

CH9O4- + 4Water = CH11O5-

By formula: CH9O4- + 4H2O = CH11O5-

Quantity Value Units Method Reference Comment
Deltar46.0 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar21.3 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

(CN- bullet Hydrogen cyanide) + Water = (CN- bullet Water bullet Hydrogen cyanide)

By formula: (CN- bullet CHN) + H2O = (CN- bullet H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar51.9 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar82.4J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar27. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 2Hydrogen cyanide) + Water = (CN- bullet Water bullet 2Hydrogen cyanide)

By formula: (CN- bullet 2CHN) + H2O = (CN- bullet H2O bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar52.3J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar17. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 3Hydrogen cyanide) + Water = (CN- bullet Water bullet 3Hydrogen cyanide)

By formula: (CN- bullet 3CHN) + H2O = (CN- bullet H2O bullet 3CHN)

Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar14. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

CN- + Water = (CN- bullet Water)

By formula: CN- + H2O = (CN- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar53.1 ± 3.3kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B,M
Deltar61.1 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,B,M,M
Deltar57.74kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B,M
Deltar61.1kJ/molPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar82.0J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar75.J/mol*KPHPMSLarson, Szulejko, et al., 1988gas phase; M
Deltar82.0J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Deltar82.0J/mol*KPHPMSMeot-ner, 1988gas phase; M
Deltar82.8J/mol*KHPMSPayzant, Yamdagni, et al., 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar30.5 ± 0.84kJ/molTDAsLarson, Szulejko, et al., 1988gas phase; B
Deltar36. ± 4.2kJ/molTDAsMeot-ner, 1988, 2gas phase; B
Deltar36. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Deltar33.1kJ/molTDAsPayzant, Yamdagni, et al., 1971gas phase; B

(CN- bullet Water bullet Hydrogen cyanide) + Water = (CN- bullet 2Water bullet Hydrogen cyanide)

By formula: (CN- bullet H2O bullet CHN) + H2O = (CN- bullet 2H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.2J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar18. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet Water bullet 2Hydrogen cyanide) + Water = (CN- bullet 2Water bullet 2Hydrogen cyanide)

By formula: (CN- bullet H2O bullet 2CHN) + H2O = (CN- bullet 2H2O bullet 2CHN)

Quantity Value Units Method Reference Comment
Deltar37. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar12. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
15.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M

(CN- bullet 2Water bullet Hydrogen cyanide) + Water = (CN- bullet 3Water bullet Hydrogen cyanide)

By formula: (CN- bullet 2H2O bullet CHN) + H2O = (CN- bullet 3H2O bullet CHN)

Quantity Value Units Method Reference Comment
Deltar36. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B
Quantity Value Units Method Reference Comment
Deltar10. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

(CN- bullet Water) + Water = (CN- bullet 2Water)

By formula: (CN- bullet H2O) + H2O = (CN- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar49.0 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B,M
Deltar49.0kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar75.7J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar75.7J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar26. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; B

(CN- bullet 2Water) + Water = (CN- bullet 3Water)

By formula: (CN- bullet 2H2O) + H2O = (CN- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar44.8 ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B,M
Deltar44.8kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar82.8J/mol*KPHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n; M
Deltar82.8J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar33. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Stated EA is Vertical Detachment Energy, at 12 K. At 298 K, measured Vertical Detachment Energy = 5.50±0.10 eV; B

(CN- bullet 3Water) + Water = (CN- bullet 4Water)

By formula: (CN- bullet 3H2O) + H2O = (CN- bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B,M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar16. ± 5.9kJ/molTDAsMeot-Ner (Mautner) M. and Speller, 1989gas phase; Entropy estimated; B

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.262.PHPMSMeot-Ner (Mautner) and Speller, 1989gas phase; n, Entropy change calculated or estimated; M

CO3- + Water = CH2O4-

By formula: CO3- + H2O = CH2O4-

Quantity Value Units Method Reference Comment
Deltar58.99 ± 0.84kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Deltar48.1 ± 4.2kJ/molIMREFehsenfeld and Ferguson, 1974gas phase; B
Deltar<161.1kJ/molPDisSmith, Lee, et al., 1978gas phase; B
Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.7kJ/molTDAsKeesee, Lee, et al., 1979gas phase; B
Deltar28.0 ± 1.7kJ/molIMREFehsenfeld and Ferguson, 1974gas phase; B

CO3- + Water = (CO3- bullet Water)

By formula: CO3- + H2O = (CO3- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar59.0kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
28.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(CO3- bullet Water) + Water = (CO3- bullet 2Water)

By formula: (CO3- bullet H2O) + H2O = (CO3- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.296.FAFehsenfeld and Ferguson, 1974gas phase; M

(CO3- bullet 2Water) + Water = (CO3- bullet 3Water)

By formula: (CO3- bullet 2H2O) + H2O = (CO3- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molHPMSKeesee, Lee, et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar136.J/mol*KHPMSKeesee, Lee, et al., 1979gas phase; M

C2Cl3O2- + Water = (C2Cl3O2- bullet Water)

By formula: C2Cl3O2- + H2O = (C2Cl3O2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar24.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

CF3CO2 anion + Water = (CF3CO2 anion bullet Water)

By formula: C2F3O2- + H2O = (C2F3O2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 6.3kJ/molN/ABlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar57.3 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar27. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B

(CF3CO2 anion bullet Water) + Water = (CF3CO2 anion bullet 2Water)

By formula: (C2F3O2- bullet H2O) + H2O = (C2F3O2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar19.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

C2H- + Water = (C2H- bullet Water)

By formula: C2H- + H2O = (C2H- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar67.8 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar77.8J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar44.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

C2HCl2O2- + Water = (C2HCl2O2- bullet Water)

By formula: C2HCl2O2- + H2O = (C2HCl2O2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

(C2HCl2O2- bullet Water) + Water = (C2HCl2O2- bullet 2Water)

By formula: (C2HCl2O2- bullet H2O) + H2O = (C2HCl2O2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar49.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar20.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

C2HF2O2- + Water = (C2HF2O2- bullet Water)

By formula: C2HF2O2- + H2O = (C2HF2O2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar60.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(C2HF2O2- bullet Water) + Water = (C2HF2O2- bullet 2Water)

By formula: (C2HF2O2- bullet H2O) + H2O = (C2HF2O2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

C2HO4- + Water = (C2HO4- bullet Water)

By formula: C2HO4- + H2O = (C2HO4- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar26.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

ClCH2CO2 anion + Water = (ClCH2CO2 anion bullet Water)

By formula: C2H2ClO2- + H2O = (C2H2ClO2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar32.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

FCH2CO2 anion + Water = (FCH2CO2 anion bullet Water)

By formula: C2H2FO2- + H2O = (C2H2FO2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar34.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(FCH2CO2 anion bullet Water) + Water = (FCH2CO2 anion bullet 2Water)

By formula: (C2H2FO2- bullet H2O) + H2O = (C2H2FO2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(FCH2CO2 anion bullet 2Water) + Water = (FCH2CO2 anion bullet 3Water)

By formula: (C2H2FO2- bullet 2H2O) + H2O = (C2H2FO2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

C2H2F3O2+ + Water = (C2H2F3O2+ bullet Water)

By formula: C2H2F3O2+ + H2O = (C2H2F3O2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar118.kJ/molICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KN/ALarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
89.5309.ICRLarson and McMahon, 1982gas phase; From thermochemical cycle(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

ICH2CO2 anion + Water = (ICH2CO2 anion bullet Water)

By formula: C2H2IO2- + H2O = (C2H2IO2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar30.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(ICH2CO2 anion bullet Water) + Water = (ICH2CO2 anion bullet 2Water)

By formula: (C2H2IO2- bullet H2O) + H2O = (C2H2IO2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(ICH2CO2 anion bullet 2Water) + Water = (ICH2CO2 anion bullet 3Water)

By formula: (C2H2IO2- bullet 2H2O) + H2O = (C2H2IO2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.3 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar18.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

C2H2N- + Water = (C2H2N- bullet Water)

By formula: C2H2N- + H2O = (C2H2N- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar55.2 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar73.6J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar33. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

C2H2O+ + Water = (C2H2O+ bullet Water)

By formula: C2H2O+ + H2O = (C2H2O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molEIPostma, Ruttink, et al., 1986gas phase; based on AE(CH2CO+)H2O from (HOCH2)2CO+; M

C2H3O+ + Water = (C2H3O+ bullet Water)

By formula: C2H3O+ + H2O = (C2H3O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar103.kJ/molHPMSDavidson, Lau, et al., 1978gas phase; forms CH3COOH2+; M
Quantity Value Units Method Reference Comment
Deltar138.J/mol*KHPMSDavidson, Lau, et al., 1978gas phase; forms CH3COOH2+; M

C2H3O- + Water = (C2H3O- bullet Water)

By formula: C2H3O- + H2O = (C2H3O- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar64.4 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B,M
Quantity Value Units Method Reference Comment
Deltar81.6J/mol*KPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar40. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

(MeCO2 anion bullet CH3CONHCH(CH3)COOCH3) + Water = (MeCO2 anion bullet Water bullet CH3CONHCH(CH3)COOCH3)

By formula: (C2H3O2- bullet C6H11NO3) + H2O = (C2H3O2- bullet H2O bullet C6H11NO3)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar106.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

MeCO2 anion + Water = (MeCO2 anion bullet Water)

By formula: C2H3O2- + H2O = (C2H3O2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B
Deltar66.5 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Deltar66.9 ± 4.2kJ/molN/AMeot-Ner and Sieck, 1986gas phase; B,M
Deltar68.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar66.1kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Deltar94.1J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; ion given as C2H3COO- in paper by error; M
Quantity Value Units Method Reference Comment
Deltar38. ± 5.9kJ/molN/AWincel, 2008gas phase; B
Deltar39.8kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Deltar39. ± 6.7kJ/molTDAsMeot-Ner and Sieck, 1986gas phase; B
Deltar39.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(MeCO2 anion bullet Water) + Water = (MeCO2 anion bullet 2Water)

By formula: (C2H3O2- bullet H2O) + H2O = (C2H3O2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.0 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Deltar57.7 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar53.6kJ/molPHPMSMeot-ner, 1988, 2gas phase; M
Deltar54.0kJ/molPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar79.9J/mol*KPHPMSMeot-ner, 1988, 2gas phase; M
Deltar85.8J/mol*KPHPMSMeot-Ner and Sieck, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar29.3kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Deltar28.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(MeCO2 anion bullet 2Water) + Water = (MeCO2 anion bullet 3Water)

By formula: (C2H3O2- bullet 2H2O) + H2O = (C2H3O2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.4 ± 4.2kJ/molN/AMeot-ner, Elmore, et al., 1999gas phase; B
Deltar51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Deltar49.4kJ/molPHPMSMeot-ner, 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AMeot-ner, 1988, 2gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar24.4kJ/molTDAsMeot-ner, Elmore, et al., 1999gas phase; B
Deltar21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar25.kJ/molPHPMSMeot-ner, 1988, 2gas phase; Entropy change calculated or estimated; M

C2H4F3O+ + Water = (C2H4F3O+ bullet Water)

By formula: C2H4F3O+ + H2O = (C2H4F3O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar128.kJ/molICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KN/ALarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
97.9309.ICRLarson and McMahon, 1982gas phase; switching reaction(H3O+)H2O, Entropy change calculated or estimated; Cunningham, Payzant, et al., 1972, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(C2H4N+ bullet Acetonitrile) + Water = (C2H4N+ bullet Water bullet Acetonitrile)

By formula: (C2H4N+ bullet C2H3N) + H2O = (C2H4N+ bullet H2O bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar66.5kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

C2H4N+ + Water = (C2H4N+ bullet Water)

By formula: C2H4N+ + H2O = (C2H4N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar92.5 ± 5.9kJ/molCIDHonma, Sunderlin, et al., 1993gas phase; guided ion beam CID; M
Deltar95.4kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Deltar104.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Deltar119.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ bullet Water bullet Acetonitrile) + Water = (C2H4N+ bullet 2Water bullet Acetonitrile)

By formula: (C2H4N+ bullet H2O bullet C2H3N) + H2O = (C2H4N+ bullet 2H2O bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.0kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(C2H4N+ bullet Water bullet 2Acetonitrile) + Water = (C2H4N+ bullet 2Water bullet 2Acetonitrile)

By formula: (C2H4N+ bullet H2O bullet 2C2H3N) + H2O = (C2H4N+ bullet 2H2O bullet 2C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar92.J/mol*KN/ADeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
12.316.PHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n, Entropy change calculated or estimated; M

(C2H4N+ bullet 2Water bullet Acetonitrile) + Water = (C2H4N+ bullet 3Water bullet Acetonitrile)

By formula: (C2H4N+ bullet 2H2O bullet C2H3N) + H2O = (C2H4N+ bullet 3H2O bullet C2H3N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar93.3J/mol*KPHPMSDeakyne, Meot-Ner (Mautner), et al., 1986gas phase; n; M

(C2H4N+ bullet Water) + Water = (C2H4N+ bullet 2Water)

By formula: (C2H4N+ bullet H2O) + H2O = (C2H4N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar62.8 ± 7.1kJ/molCIDHonma, Sunderlin, et al., 1993gas phase; guided ion beam CID; M
Deltar73.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ bullet 2Water) + Water = (C2H4N+ bullet 3Water)

By formula: (C2H4N+ bullet 2H2O) + H2O = (C2H4N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar65.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar104.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ bullet 3Water) + Water = (C2H4N+ bullet 4Water)

By formula: (C2H4N+ bullet 3H2O) + H2O = (C2H4N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.2J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ bullet 4Water) + Water = (C2H4N+ bullet 5Water)

By formula: (C2H4N+ bullet 4H2O) + H2O = (C2H4N+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H4N+ bullet 5Water) + Water = (C2H4N+ bullet 6Water)

By formula: (C2H4N+ bullet 5H2O) + H2O = (C2H4N+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar42.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar107.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H4NO2- + Water = C2H6NO3-

By formula: C2H4NO2- + H2O = C2H6NO3-

Quantity Value Units Method Reference Comment
Deltar72.5 ± 2.1kJ/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Deltar66.9 ± 1.3kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Deltar39. ± 4.2kJ/molTDAsNieckarz, Atkins, et al., 2008gas phase; B
Deltar34.3 ± 1.7kJ/molTDAsWincel, 2008gas phase; B

C2H4NO5- + Water + Acetic acid = C2H6NO6-

By formula: C2H4NO5- + H2O + C2H4O2 = C2H6NO6-

Quantity Value Units Method Reference Comment
Deltar19.2 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C2H5F2O+ + Water = (C2H5F2O+ bullet Water)

By formula: C2H5F2O+ + H2O = (C2H5F2O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M

C2H5F3N+ + Water = (C2H5F3N+ bullet Water)

By formula: C2H5F3N+ + H2O = (C2H5F3N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar88.3kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar126.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H5F3N+ bullet Water) + Water = (C2H5F3N+ bullet 2Water)

By formula: (C2H5F3N+ bullet H2O) + H2O = (C2H5F3N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar72.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H5F3N+ bullet 2Water) + Water = (C2H5F3N+ bullet 3Water)

By formula: (C2H5F3N+ bullet 2H2O) + H2O = (C2H5F3N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar59.4kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar122.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

C2H5O+ + Water = (C2H5O+ bullet Water)

By formula: C2H5O+ + H2O = (C2H5O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar105.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet Water) + Water = (C2H5O+ bullet 2Water)

By formula: (C2H5O+ bullet H2O) + H2O = (C2H5O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar70.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 2Water) + Water = (C2H5O+ bullet 3Water)

By formula: (C2H5O+ bullet 2H2O) + H2O = (C2H5O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar71.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 3Water) + Water = (C2H5O+ bullet 4Water)

By formula: (C2H5O+ bullet 3H2O) + H2O = (C2H5O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 4Water) + Water = (C2H5O+ bullet 5Water)

By formula: (C2H5O+ bullet 4H2O) + H2O = (C2H5O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 5Water) + Water = (C2H5O+ bullet 6Water)

By formula: (C2H5O+ bullet 5H2O) + H2O = (C2H5O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.8J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 6Water) + Water = (C2H5O+ bullet 7Water)

By formula: (C2H5O+ bullet 6H2O) + H2O = (C2H5O+ bullet 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H5O+ + Water = (C2H5O+ bullet Water)

By formula: C2H5O+ + H2O = (C2H5O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar84.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar91.6kJ/molHPMSDavidson, Sunner J., et al., 1979gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.9J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet Water) + Water = (C2H5O+ bullet 2Water)

By formula: (C2H5O+ bullet H2O) + H2O = (C2H5O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar74.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 2Water) + Water = (C2H5O+ bullet 3Water)

By formula: (C2H5O+ bullet 2H2O) + H2O = (C2H5O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O+ bullet 3Water) + Water = (C2H5O+ bullet 4Water)

By formula: (C2H5O+ bullet 3H2O) + H2O = (C2H5O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar85.4J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C2H5O2+ + Water = (C2H5O2+ bullet Water)

By formula: C2H5O2+ + H2O = (C2H5O2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar90.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ bullet Water) + Water = (C2H5O2+ bullet 2Water)

By formula: (C2H5O2+ bullet H2O) + H2O = (C2H5O2+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar67.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar111.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ bullet 2Water) + Water = (C2H5O2+ bullet 3Water)

By formula: (C2H5O2+ bullet 2H2O) + H2O = (C2H5O2+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H5O2+ bullet 3Water) + Water = (C2H5O2+ bullet 4Water)

By formula: (C2H5O2+ bullet 3H2O) + H2O = (C2H5O2+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar90.4J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
16.334.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

(C2H5O2+ bullet 4Water) + Water = (C2H5O2+ bullet 5Water)

By formula: (C2H5O2+ bullet 4H2O) + H2O = (C2H5O2+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.280.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C2H5O4- + 2Water = C2H7O5-

By formula: C2H5O4- + 2H2O = C2H7O5-

Quantity Value Units Method Reference Comment
Deltar54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

C2H6NO2+ + Water = (C2H6NO2+ bullet Water)

By formula: C2H6NO2+ + H2O = (C2H6NO2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
41.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H6NO2+ bullet Water) + Water = (C2H6NO2+ bullet 2Water)

By formula: (C2H6NO2+ bullet H2O) + H2O = (C2H6NO2+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
30.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H6NO2+ bullet 2Water) + Water = (C2H6NO2+ bullet 3Water)

By formula: (C2H6NO2+ bullet 2H2O) + H2O = (C2H6NO2+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
23.293.ES/HPMSKlassen, Blades, et al., 1995gas phase; M

(C2H7O+ bullet Dimethyl ether) + Water = (C2H7O+ bullet Water bullet Dimethyl ether)

By formula: (C2H7O+ bullet C2H6O) + H2O = (C2H7O+ bullet H2O bullet C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.2kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M
Quantity Value Units Method Reference Comment
Deltar162.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n, Entropy change is questionable; M

C2H7O+ + Water = (C2H7O+ bullet Water)

By formula: C2H7O+ + H2O = (C2H7O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.9kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Deltar100.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar94.6kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; M
Quantity Value Units Method Reference Comment
Deltar114.J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M
Deltar121.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar111.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; M

(C2H7O+ bullet Water bullet Dimethyl ether) + Water = (C2H7O+ bullet 2Water bullet Dimethyl ether)

By formula: (C2H7O+ bullet H2O bullet C2H6O) + H2O = (C2H7O+ bullet 2H2O bullet C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Water bullet 2Dimethyl ether) + Water = (C2H7O+ bullet 2Water bullet 2Dimethyl ether)

By formula: (C2H7O+ bullet H2O bullet 2C2H6O) + H2O = (C2H7O+ bullet 2H2O bullet 2C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Water bullet 3Dimethyl ether) + Water = (C2H7O+ bullet 2Water bullet 3Dimethyl ether)

By formula: (C2H7O+ bullet H2O bullet 3C2H6O) + H2O = (C2H7O+ bullet 2H2O bullet 3C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar127.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Water bullet Dimethyl ether) + Water = (C2H7O+ bullet 3Water bullet Dimethyl ether)

By formula: (C2H7O+ bullet 2H2O bullet C2H6O) + H2O = (C2H7O+ bullet 3H2O bullet C2H6O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar112.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet Water) + Water = (C2H7O+ bullet 2Water)

By formula: (C2H7O+ bullet H2O) + H2O = (C2H7O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar64.0kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 2Water) + Water = (C2H7O+ bullet 3Water)

By formula: (C2H7O+ bullet 2H2O) + H2O = (C2H7O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.0kJ/molPHPMSTholman, Tonner, et al., 1994gas phase; M
Deltar57.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar95.0J/mol*KPHPMSTholman, Tonner, et al., 1994gas phase; M
Deltar106.J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

(C2H7O+ bullet 3Water) + Water = (C2H7O+ bullet 4Water)

By formula: (C2H7O+ bullet 3H2O) + H2O = (C2H7O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar42.7kJ/molPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M
Quantity Value Units Method Reference Comment
Deltar79.5J/mol*KPHPMSHiraoka, Grimsrud, et al., 1974gas phase; n; M

C2H7O+ + Water = (C2H7O+ bullet Water)

By formula: C2H7O+ + H2O = (C2H7O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar111.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar100.kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar128.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ bullet Water) + Water = (C2H7O+ bullet 2Water)

By formula: (C2H7O+ bullet H2O) + H2O = (C2H7O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar78.2kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar80.3kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar120.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ bullet 2Water) + Water = (C2H7O+ bullet 3Water)

By formula: (C2H7O+ bullet 2H2O) + H2O = (C2H7O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.1kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar59.4kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ bullet 3Water) + Water = (C2H7O+ bullet 4Water)

By formula: (C2H7O+ bullet 3H2O) + H2O = (C2H7O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.3kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar52.3kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar110.J/mol*KPHPMSKebarle, 1977gas phase; M

(C2H7O+ bullet 4Water) + Water = (C2H7O+ bullet 5Water)

By formula: (C2H7O+ bullet 4H2O) + H2O = (C2H7O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar41.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.4J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C2H7O+ bullet 5Water) + Water = (C2H7O+ bullet 6Water)

By formula: (C2H7O+ bullet 5H2O) + H2O = (C2H7O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8kJ/molPHPMSKebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar120.J/mol*KPHPMSKebarle, 1977gas phase; M

C2H7O2- + Water + Methyl Alcohol = C2H9O3-

By formula: C2H7O2- + H2O + CH4O = C2H9O3-

Quantity Value Units Method Reference Comment
Deltar74.5 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar42.3 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H7O5- + 3Water = C2H9O6-

By formula: C2H7O5- + 3H2O = C2H9O6-

Quantity Value Units Method Reference Comment
Deltar48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

C2H7O5S- + 2Water = C2H9O6S-

By formula: C2H7O5S- + 2H2O = C2H9O6S-

Quantity Value Units Method Reference Comment
Deltar48.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar19.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

C2H7S+ + Water = (C2H7S+ bullet Water)

By formula: C2H7S+ + H2O = (C2H7S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar50.kJ/molICRBerman and Beauchamp, 1986gas phase; bracketing; Lias, Liebman, et al., 1984; M
Deltar54.8kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

(C2H7S+ bullet Water) + Water = (C2H7S+ bullet 2Water)

By formula: (C2H7S+ bullet H2O) + H2O = (C2H7S+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar48.5kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.2J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C2H7S+ + Water = (C2H7S+ bullet Water)

By formula: C2H7S+ + H2O = (C2H7S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar61.5kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C2H8N+ + Water = (C2H8N+ bullet Water)

By formula: C2H8N+ + H2O = (C2H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar62.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar38.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ bullet Water) + Water = (C2H8N+ bullet 2Water)

By formula: (C2H8N+ bullet H2O) + H2O = (C2H8N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.5kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar103.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar26.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ bullet 2Water) + Water = (C2H8N+ bullet 3Water)

By formula: (C2H8N+ bullet 2H2O) + H2O = (C2H8N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar47.3kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar18.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C2H8N+ bullet 3Water) + Water = (C2H8N+ bullet 4Water)

By formula: (C2H8N+ bullet 3H2O) + H2O = (C2H8N+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar105.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ bullet 4Water) + Water = (C2H8N+ bullet 5Water)

By formula: (C2H8N+ bullet 4H2O) + H2O = (C2H8N+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar39.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C2H8N+ bullet 5Water) + Water = (C2H8N+ bullet 6Water)

By formula: (C2H8N+ bullet 5H2O) + H2O = (C2H8N+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar35.kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar88.7J/mol*KN/AMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
13.255.PHPMSMeot-Ner (Mautner), 1984gas phase; Entropy change calculated or estimated; M

C2H8N+ + Water = (C2H8N+ bullet Water)

By formula: C2H8N+ + H2O = (C2H8N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar73.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar108.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ bullet Water) + Water = (C2H8N+ bullet 2Water)

By formula: (C2H8N+ bullet H2O) + H2O = (C2H8N+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.5kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar124.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

(C2H8N+ bullet 2Water) + Water = (C2H8N+ bullet 3Water)

By formula: (C2H8N+ bullet 2H2O) + H2O = (C2H8N+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar55.2kJ/molPHPMSLau and Kebarle, 1981gas phase; M
Quantity Value Units Method Reference Comment
Deltar129.J/mol*KPHPMSLau and Kebarle, 1981gas phase; M

C2H8O8S2-2 + 3Water = C2H10O9S2-2

By formula: C2H8O8S2-2 + 3H2O = C2H10O9S2-2

Quantity Value Units Method Reference Comment
Deltar31.4 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H9N+ + Water = (C2H9N+ bullet Water)

By formula: C2H9N+ + H2O = (C2H9N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
33.293.ES/HPMSBlades, Klassen, et al., 1995gas phase; M

C2H9O3- + 2Water + Methyl Alcohol = C2H11O4-

By formula: C2H9O3- + 2H2O + CH4O = C2H11O4-

Quantity Value Units Method Reference Comment
Deltar63.6 ± 4.2kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B
Quantity Value Units Method Reference Comment
Deltar28.9 ± 2.1kJ/molTDAsMeot-Ner(Mautner), 1986gas phase; B

C2H10O9S2-2 + 4Water = C2H12O10S2-2

By formula: C2H10O9S2-2 + 4H2O = C2H12O10S2-2

Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H12O10S2-2 + 5Water = C2H14O11S2-2

By formula: C2H12O10S2-2 + 5H2O = C2H14O11S2-2

Quantity Value Units Method Reference Comment
Deltar24.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C2H14O11S2-2 + 6Water = C2H16O12S2-2

By formula: C2H14O11S2-2 + 6H2O = C2H16O12S2-2

Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C3H2F3O- + Water = (C3H2F3O- bullet Water)

By formula: C3H2F3O- + H2O = (C3H2F3O- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar53.6 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar32. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

C3H2F3O- + Water = (C3H2F3O- bullet Water)

By formula: C3H2F3O- + H2O = (C3H2F3O- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar53.6kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar72.4J/mol*KPHPMSMeot-ner, 1988gas phase; M

C3H2N+ + Water = (C3H2N+ bullet Water)

By formula: C3H2N+ + H2O = (C3H2N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar97.5kJ/molPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSSpeller and Meot-Ner (Mautner), 1985gas phase; M

C3H2NO2- + Water = (C3H2NO2- bullet Water)

By formula: C3H2NO2- + H2O = (C3H2NO2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar59.83kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar29.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

(C3H2NO2- bullet Water) + Water = (C3H2NO2- bullet 2Water)

By formula: (C3H2NO2- bullet H2O) + H2O = (C3H2NO2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar51.0 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar21.8 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B

imidazolide anion + Water = (imidazolide anion bullet Water)

By formula: C3H3N2- + H2O = (C3H3N2- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar63.6kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar94.6J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(imidazolide anion bullet Water) + Water = (imidazolide anion bullet 2Water)

By formula: (C3H3N2- bullet H2O) + H2O = (C3H3N2- bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar49.4kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar76.1J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(imidazolide anion bullet 2Water) + Water = (imidazolide anion bullet 3Water)

By formula: (C3H3N2- bullet 2H2O) + H2O = (C3H3N2- bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.0kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar122.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H3O4- + Water = (C3H3O4- bullet Water)

By formula: C3H3O4- + H2O = (C3H3O4- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar22.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

(C3H3O4- bullet Water) + Water = (C3H3O4- bullet 2Water)

By formula: (C3H3O4- bullet H2O) + H2O = (C3H3O4- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar17.kJ/molES/HPMSBlades, Klassen, et al., 1995gas phase; M

C3H4N2+ + Water = (C3H4N2+ bullet Water)

By formula: C3H4N2+ + H2O = (C3H4N2+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.9kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar99.6J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H4N2+ bullet Water) + Water = (C3H4N2+ bullet 2Water)

By formula: (C3H4N2+ bullet H2O) + H2O = (C3H4N2+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.5J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

(C3H4N2+ bullet 2Water) + Water = (C3H4N2+ bullet 3Water)

By formula: (C3H4N2+ bullet 2H2O) + H2O = (C3H4N2+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.0kJ/molPHPMSMeot-Ner (Mautner), 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar125.J/mol*KPHPMSMeot-Ner (Mautner), 1988gas phase; M

C3H4O5- + Water + Acetic acid = C3H6O6-

By formula: C3H4O5- + H2O + C2H4O2 = C3H6O6-

Quantity Value Units Method Reference Comment
Deltar19.2 ± 0.84kJ/molIMREViidanoja, Reiner, et al., 2000gas phase; B

C3H5O+ + Water = (C3H5O+ bullet Water)

By formula: C3H5O+ + H2O = (C3H5O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar66.1kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.9J/mol*KPHPMSMeot-ner, 1988gas phase; M

(C3H5O+ bullet Water) + Water = (C3H5O+ bullet 2Water)

By formula: (C3H5O+ bullet H2O) + H2O = (C3H5O+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar58.2kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.4J/mol*KPHPMSMeot-ner, 1988gas phase; M

(C3H5O+ bullet 2Water) + Water = (C3H5O+ bullet 3Water)

By formula: (C3H5O+ bullet 2H2O) + H2O = (C3H5O+ bullet 3H2O)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KPHPMSMeot-ner, 1988gas phase; M

(C3H5O+ bullet 3Water) + Water = (C3H5O+ bullet 4Water)

By formula: (C3H5O+ bullet 3H2O) + H2O = (C3H5O+ bullet 4H2O)

Quantity Value Units Method Reference Comment
Deltar45.2kJ/molPHPMSMeot-ner, 1988gas phase; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSMeot-ner, 1988gas phase; M

C3H5O+ + Water = (C3H5O+ bullet Water)

By formula: C3H5O+ + H2O = (C3H5O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar99.2kJ/molPHPMSDavidson, Meza-Hojer, et al., 1979gas phase; forms protonated propanoic acid; M
Quantity Value Units Method Reference Comment
Deltar147.J/mol*KPHPMSDavidson, Meza-Hojer, et al., 1979gas phase; forms protonated propanoic acid; M

(C3H5O+ bullet 2Water) + Water = (C3H5O+ bullet 3Water)

By formula: (C3H5O+ bullet 2H2O) + H2O = (C3H5O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

(C3H5O+ bullet 3Water) + Water = (C3H5O+ bullet 4Water)

By formula: (C3H5O+ bullet 3H2O) + H2O = (C3H5O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar53.1kJ/molPHPMSHiraoka and Kebarle, 1977gas phase; M
Quantity Value Units Method Reference Comment
Deltar100.J/mol*KPHPMSHiraoka and Kebarle, 1977gas phase; M

C3H5O- + Water = (C3H5O- bullet Water)

By formula: C3H5O- + H2O = (C3H5O- bullet H2O)

Quantity Value Units Method Reference Comment
Deltar66.1 ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B
Quantity Value Units Method Reference Comment
Deltar41. ± 4.2kJ/molTDAsMeot-ner, 1988gas phase; B

EtCO2 anion + Water = (EtCO2 anion bullet Water)

By formula: C3H5O2- + H2O = (C3H5O2- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.2 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar38.9 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar35.1 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(EtCO2 anion bullet Water) + Water = (EtCO2 anion bullet 2Water)

By formula: (C3H5O2- bullet H2O) + H2O = (C3H5O2- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.9 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar27.6 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar28.9 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

(EtCO2 anion bullet 2Water) + Water = (EtCO2 anion bullet 3Water)

By formula: (C3H5O2- bullet 2H2O) + H2O = (C3H5O2- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar50.6 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar21.3 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M
Deltar21.3 ± 0.84kJ/molN/AViidanoja, Reiner, et al., 2000gas phase; B

MeCH(OH)CO2 anion + Water = (MeCH(OH)CO2 anion bullet Water)

By formula: C3H5O3- + H2O = (C3H5O3- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar61.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar32.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(MeCH(OH)CO2 anion bullet Water) + Water = (MeCH(OH)CO2 anion bullet 2Water)

By formula: (C3H5O3- bullet H2O) + H2O = (C3H5O3- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar51.5 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar22.2 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

MeOCH2CO2 anion + Water = (MeOCH2CO2 anion bullet Water)

By formula: C3H5O3- + H2O = (C3H5O3- bullet H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar65.3 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar36.0 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(MeOCH2CO2 anion bullet Water) + Water = (MeOCH2CO2 anion bullet 2Water)

By formula: (C3H5O3- bullet H2O) + H2O = (C3H5O3- bullet 2H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.8 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar25.5 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

(MeOCH2CO2 anion bullet 2Water) + Water = (MeOCH2CO2 anion bullet 3Water)

By formula: (C3H5O3- bullet 2H2O) + H2O = (C3H5O3- bullet 3H2O)

Bond type: Hydrogen bond (negative ion to hydride)

Quantity Value Units Method Reference Comment
Deltar49.4 ± 6.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B
Quantity Value Units Method Reference Comment
Deltar20.1 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; T: 293 K. «DELTA»Saff approx. 24 cal/mol-K; B,M

C3H5O5- + 2Water = C3H7O6-

By formula: C3H5O5- + 2H2O = C3H7O6-

Quantity Value Units Method Reference Comment
Deltar16.7 ± 1.3kJ/molTDAsBlades, Klassen, et al., 1995gas phase; B

C3H6+ + Water = (C3H6+ bullet Water)

By formula: C3H6+ + H2O = (C3H6+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar43.5kJ/molCIDHolmes, Mommers, et al., 1984gas phase; structure confirmed as ion-dipole complex in Shao, Baer, et al., 1987; M

C3H6NO2- + Water = C3H8NO3-

By formula: C3H6NO2- + H2O = C3H8NO3-

Quantity Value Units Method Reference Comment
Deltar64.0 ± 1.7kJ/molN/AWincel, 2008gas phase; B
Quantity Value Units Method Reference Comment
Deltar32.6 ± 3.3kJ/molTDAsWincel, 2008gas phase; B

C3H7+ + Water = (C3H7+ bullet Water)

By formula: C3H7+ + H2O = (C3H7+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar73.6kJ/molHPMSBeggs and Field, 1971gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product; M
Quantity Value Units Method Reference Comment
Deltar116.J/mol*KHPMSBeggs and Field, 1971gas phase; «DELTA»rH inconsistent with (CH3)2CHOH2+ product; M

C3H7O+ + Water = (C3H7O+ bullet Water)

By formula: C3H7O+ + H2O = (C3H7O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar85.8kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar109.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ bullet Water) + Water = (C3H7O+ bullet 2Water)

By formula: (C3H7O+ bullet H2O) + H2O = (C3H7O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar56.9kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar97.1J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ bullet 2Water) + Water = (C3H7O+ bullet 3Water)

By formula: (C3H7O+ bullet 2H2O) + H2O = (C3H7O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar53.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ bullet 3Water) + Water = (C3H7O+ bullet 4Water)

By formula: (C3H7O+ bullet 3H2O) + H2O = (C3H7O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar84.5J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

(C3H7O+ bullet 4Water) + Water = (C3H7O+ bullet 5Water)

By formula: (C3H7O+ bullet 4H2O) + H2O = (C3H7O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.1kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.3J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M

C3H7O+ + Water = (C3H7O+ bullet Water)

By formula: C3H7O+ + H2O = (C3H7O+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar46.9kJ/molPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar78.7J/mol*KPHPMSMeot-Ner (Mautner), Ross, et al., 1985gas phase; M

C3H9O+ + Water = (C3H9O+ bullet Water)

By formula: C3H9O+ + H2O = (C3H9O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar100.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar117.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet Water) + Water = (C3H9O+ bullet 2Water)

By formula: (C3H9O+ bullet H2O) + H2O = (C3H9O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar74.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar110.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 2Water) + Water = (C3H9O+ bullet 3Water)

By formula: (C3H9O+ bullet 2H2O) + H2O = (C3H9O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar54.4kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 3Water) + Water = (C3H9O+ bullet 4Water)

By formula: (C3H9O+ bullet 3H2O) + H2O = (C3H9O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar46.0kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar95.8J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 4Water) + Water = (C3H9O+ bullet 5Water)

By formula: (C3H9O+ bullet 4H2O) + H2O = (C3H9O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar86.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 5Water) + Water = (C3H9O+ bullet 6Water)

By formula: (C3H9O+ bullet 5H2O) + H2O = (C3H9O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar87.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

C3H9O+ + Water = (C3H9O+ bullet Water)

By formula: C3H9O+ + H2O = (C3H9O+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.2kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; unusually small «DELTA»rH and «DELTA»rS; M
Deltar56.5kJ/molHPMSBeggs and Field, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar57.3J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; unusually small «DELTA»rH and «DELTA»rS; M
Deltar53.1J/mol*KHPMSBeggs and Field, 1971gas phase; M

(C3H9O+ bullet Water) + Water = (C3H9O+ bullet 2Water)

By formula: (C3H9O+ bullet H2O) + H2O = (C3H9O+ bullet 2H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar68.6kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar62.3kJ/molHPMSBeggs and Field, 1971gas phase; M
Quantity Value Units Method Reference Comment
Deltar101.J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Deltar90.0J/mol*KHPMSBeggs and Field, 1971gas phase; M

(C3H9O+ bullet 2Water) + Water = (C3H9O+ bullet 3Water)

By formula: (C3H9O+ bullet 2H2O) + H2O = (C3H9O+ bullet 3H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar52.3kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar98.7J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 3Water) + Water = (C3H9O+ bullet 4Water)

By formula: (C3H9O+ bullet 3H2O) + H2O = (C3H9O+ bullet 4H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar43.9kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar90.0J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 4Water) + Water = (C3H9O+ bullet 5Water)

By formula: (C3H9O+ bullet 4H2O) + H2O = (C3H9O+ bullet 5H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar40.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar91.6J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 5Water) + Water = (C3H9O+ bullet 6Water)

By formula: (C3H9O+ bullet 5H2O) + H2O = (C3H9O+ bullet 6H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar89.1J/mol*KPHPMSHiraoka, Takimoto, et al., 1986gas phase; M

(C3H9O+ bullet 6Water) + Water = (C3H9O+ bullet 7Water)

By formula: (C3H9O+ bullet 6H2O) + H2O = (C3H9O+ bullet 7H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar33.kJ/molPHPMSHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar84.J/mol*KN/AHiraoka, Takimoto, et al., 1986gas phase; Entropy change calculated or estimated; M

C3H9S+ + Water = (C3H9S+ bullet Water)

By formula: C3H9S+ + H2O = (C3H9S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar52.7kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
19.347.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9S+ + Water = (C3H9S+ bullet Water)

By formula: C3H9S+ + H2O = (C3H9S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar60.2kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
17.446.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9S+ + Water = (C3H9S+ bullet Water)

By formula: C3H9S+ + H2O = (C3H9S+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar58.2kJ/molPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M
Quantity Value Units Method Reference Comment
Deltar96.J/mol*KPHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
18.418.PHPMSMeot-Ner (Mautner) and Sieck, 1985gas phase; M

C3H9Si+ + Water = (C3H9Si+ bullet Water)

By formula: C3H9Si+ + H2O = (C3H9Si+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar126. ± 7.9kJ/molPHPMSStone and Wojtyniak, 1986gas phase; M
Quantity Value Units Method Reference Comment
Deltar113.J/mol*KPHPMSStone and Wojtyniak, 1986gas phase; M

(C3H9Si+ bullet Water) + Water = (C3H9Si+ bullet 2Water)

By formula: (C3H9Si+ bullet H2O) + H2O = (C3H9Si+ bullet 2H2O)

Quantity Value Units Method Reference Comment
Deltar83.3kJ/molPHPMSStone and Wytenberg, 1987gas phase; M
Quantity Value Units Method Reference Comment
Deltar118.J/mol*KPHPMSStone and Wytenberg, 1987gas phase; M

C3H9Sn+ + Water = (C3H9Sn+ bullet Water)

By formula: C3H9Sn+ + H2O = (C3H9Sn+ bullet H2O)

Quantity Value Units Method Reference Comment
Deltar108.kJ/molPHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Deltar115.J/mol*KN/AStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M

Free energy of reaction

DeltarG° (kJ/mol) T (K) Method Reference Comment
46.9525.PHPMSStone and Splinter, 1984gas phase; switching reaction((CH3)3Sn+)CH3OH; Entropy change calculated or estimated; M

(C3H10N+ bullet 2Methylamine, N,N-dimethyl-) + Water = (C3H10N+ bullet Water bullet 2Methylamine, N,N-dimethyl-)

By formula: (C3H10N+ bullet 2C3H9N) + H2O = (C3H10N+ bullet H2O bullet 2C3H9N)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar37.kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M

C3H10N+ + Water = (C3H10N+ bullet Water)

By formula: C3H10N+ + H2O = (C3H10N+ bullet H2O)

Bond type: Hydrogen bond (positive ion to hydride)

Quantity Value Units Method Reference Comment
Deltar60.7kJ/molPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Deltar60.7kJ/molPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar60.7kJ/molPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar102.J/mol*KPHPMSEl-Shall, Daly, et al., 1992gas phase; M
Deltar101.J/mol*KPHPMSMeot-Ner (Mautner), 1984gas phase; M
Deltar101.J/mol*KPHPMSMeot-Ner M. and Sieck, 1983gas phase; M
Quantity Value Units Method Reference Comment
Deltar32.kJ/molHPMSBanic and Iribarne, 1985gas phase; electric fields; M

(C3H10N+ bullet