Reaction data
+
= (
•
)
- Reaction by formula: Cl- + H2O = (Cl- • H2O)
- Comments:
- Bond type: Hydrogen bond (negative ion to hydride)
- Information on this page:
- Other data available:
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Entropy of reaction at standard conditions (nominally 298.15 K, 1 atm.)
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
ΔrS° (J/mol*K) | Method | Reference | Comment |
---|---|---|---|
82.4 | PHPMS | Hiraoka, Mizuse, et al., 1988 | gas phase; M |
84.1 | MS | Burdett and Hayhurst, 1982 | gas phase; flame source, about 1600 K; M |
82.4 | HPMS | Keesee and Castleman, 1980 | gas phase; M |
82.4 | PHPMS | Yamabe, Furumiya, et al., 1986 | gas phase; M |
74.9 | PHPMS | Sieck, 1985 | gas phase; ΔrS smaller than other sources; M |
89.5 | N/A | Bohringer, Fahey, et al., 1984 | gas phase; switching reaction(Cl-)H2O, Entropy change calculated or estimated; Keesee and Castleman, 1980; M |
84.1 | N/A | Larson and McMahon, 1984 | gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M |
69.0 | HPMS | Arshadi, Yamdagni, et al., 1970 | gas phase; M |
References
Go To: Top, Entropy of reaction at standard conditions (nominally 298.15 K, 1 atm.), Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hiraoka, Mizuse, et al., 1988
Hiraoka, K.; Mizuse, S.; Yamabe, S.,
Solvation of Halide Ions with H2O and CH3CN in the Gas Phase,
J. Phys. Chem., 1988, 92, 13, 3943, https://doi.org/10.1021/j100324a051
. [all data]
Burdett and Hayhurst, 1982
Burdett, N.A.; Hayhurst, A.N.,
Hydration of gas phase ions and the measurement of boundary layer cooling during flame sampling into a mass spectrometer.,
J. Chem. Soc. Faraday Trans. 1, 1982, 78, 2997. [all data]
Keesee and Castleman, 1980
Keesee, R.G.; Castleman, A.W., Jr.,
Gas phase studies of hydration complexes of Cl- and I- and comparison to electrostatic calculations in the gas phase,
Chem. Phys. Lett., 1980, 74, 139. [all data]
Yamabe, Furumiya, et al., 1986
Yamabe, S.; Furumiya, Y.; Hiraoka, K.; Morise, K.,
Theoretical Van't Hoff plots of gas phase ion equilibria of Cl- ion in water, methanol and acetonitrile,
Chem. Phys. Lett., 1986, 131, 261. [all data]
Sieck, 1985
Sieck, L.W.,
Thermochemistry of Solvation of NO2- and C6H5NO2- by Polar Molecules in the Vapor Phase. Comparison with Cl- and Variation with Ligand Structure.,
J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049
. [all data]
Bohringer, Fahey, et al., 1984
Bohringer, H.; Fahey, D.W.; Fehsenfeld, F.C.; Ferguson, E.E.,
Bond energies of the molecules H2O, SO2, H2O2, and HCl to various atmospheric negative ions,
J. Chem. Phys., 1984, 81, 2805. [all data]
Larson and McMahon, 1984
Larson, J.W.; McMahon, T.B.,
Gas phase negative ion chemistry of alkylchloroformates,
Can. J. Chem., 1984, 62, 675. [all data]
French, Ikuta, et al., 1982
French, M.A.; Ikuta, S.; Kebarle, P.,
Hydrogen bonding of O-H and C-H hydrogen donors to Cl-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl- = RHCl-,
Can. J. Chem., 1982, 60, 1907. [all data]
Arshadi, Yamdagni, et al., 1970
Arshadi, M.; Yamdagni, R.; Kebarle, P.,
Hydration of Halide Negative Ions in the Gas Phase. II. Comparison of Hydration Energies for the Alkali Positive and Halide Negative Ions,
J. Phys. Chem., 1970, 74, 7, 1475, https://doi.org/10.1021/j100702a014
. [all data]
Notes
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- Symbols used in this document:
ΔrS° Entropy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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