tris(1,1,1,5,5,5-hexafluoropentane-2,4-dionato-O,O')ruthenium


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub114.5 ± 1.0kJ/molMERibeiro da Silva, Monte, et al., 2001 

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
114.1 ± 1.0306.MERibeiro da Silva, Monte, et al., 2001Based on data from 299. to 313. K.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
8.85 ± 0.07PEEvans, Hamnett, et al., 1972Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Ribeiro da Silva, Monte, et al., 2001
Ribeiro da Silva, Manuel A.V.; Monte, Manuel J.S.; Giera, Edward, Thermodynamic study of the sublimation of crystalline tris(1,1,1-trifluoro-2,4-pentanedionate)ruthenium(III) and tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionate)ruthenium(III), The Journal of Chemical Thermodynamics, 2001, 33, 4, 369-376, https://doi.org/10.1006/jcht.2000.0734 . [all data]

Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R., Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy, Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]


Notes

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