Stannane, trimethyl-(trimethylsilyl)-
- Formula: C6H18SiSn
- Molecular weight: 237.003
- CAS Registry Number: 16393-88-7
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to C6H18SiSn+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
8.39 | PE | Mochida, Worley, et al., 1985 | LBLHLM |
8.0 | PE | Szepes, Koranyi, et al., 1981 | LLK |
8.18 ± 0.14 | EI | Lappert, Pedley, et al., 1971 | LLK |
8.32 ± 0.05 | PE | Szepes, Koranyi, et al., 1981 | Vertical value; LLK |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
C3H9Si+ | 10.18 ± 0.26 | (CH3)3Sn | EI | Lappert, Pedley, et al., 1971 | LLK |
C3H9Si+ | 10.18 ± 0.26 | ? | EI | Lappert, Simpson, et al., 1969 | RDSH |
C3H9Sn+ | 9.80 ± 0.24 | (CH3)3Si | EI | Lappert, Pedley, et al., 1971 | LLK |
C3H9Sn+ | 9.80 ± 0.24 | ? | EI | Lappert, Simpson, et al., 1969 | RDSH |
C6H18SiSn+ | 8.18 ± 0.14 | ? | EI | Lappert, Simpson, et al., 1969 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Mochida, Worley, et al., 1985
Mochida, K.; Worley, S.; Kochi, J.,
UV photoelectron spectra of peralkylated catenates of Group 4B elements (silicon, germanium, and tin),
Bull. Chem. Soc. Jpn., 1985, 58, 3389. [all data]
Szepes, Koranyi, et al., 1981
Szepes, L.; Koranyi, T.; Naray-Szabo, G.; Modelli, A.; Distefano, G.,
Ultraviolet photoelectron spectra of group IV hexamethyl derivatives containing a metal-metal bond,
J. Organomet. Chem., 1981, 217, 35. [all data]
Lappert, Pedley, et al., 1971
Lappert, M.F.; Pedley, J.B.; Simpson, J.; Spalding, T.R.,
Bonding studies of compounds of boron and the Group IV elements. VI. Mass spectrometric studies on compounds Me4M and Me3M-M'Me3 (M and M'=C, Si, Ge, Sn, and Pb): thermochemical data,
J. Organomet. Chem., 1971, 29, 195. [all data]
Lappert, Simpson, et al., 1969
Lappert, M.F.; Simpson, J.; Spalding, T.R.,
Bonding studies of compounds of the group IV elements: ionisation potentials of the Me3M radicals,
J.Organometal. Chem., 1969, 17, PI. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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