Iodotrimethylsilane
- Formula: C3H9ISi
- Molecular weight: 200.0935
- IUPAC Standard InChI: InChI=1S/C3H9ISi/c1-5(2,3)4/h1-3H3
- IUPAC Standard InChIKey: CSRZQMIRAZTJOY-UHFFFAOYSA-N
- CAS Registry Number: 16029-98-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Trimethylsilyl iodide; Silane, iodotrimethyl-; CT3610; Trimethyliodosilane
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.9 ± 0.1 | EI | Band, Davidson, et al., 1968 | RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C2H6SiI+ | 10.3 ± 0.1 | CH3 | EI | Band, Davidson, et al., 1968 | RDSH |
| C3H9Si+ | 9.68 ± 0.01 | I | PIPECO | Szepes and Baer, 1984 | T = 298K; LBLHLM |
| C3H9Si+ | 9.87 ± 0.01 | I | PIPECO | Szepes and Baer, 1984 | T = 0K; LBLHLM |
| C3H9Si+ | 9.87 ± 0.01 | I | PIPECO | Szepes and Baer, 1984, 2 | T = 0K; LBLHLM |
| C3H9Si+ | 10.1 ± 0.1 | I | EI | Band, Davidson, et al., Commun. 1967 | RDSH |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Band, Davidson, et al., 1968
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.,
Bond dissociation energies: electron impact studies on some trimethylsilyl compounds,
J. Chem. Soc. A, 1968, 2068. [all data]
Szepes and Baer, 1984
Szepes, L.; Baer, T.,
Dissociation dynamics of energy selected hexamethyldisilane ions and the heats of formation of (CH3)3Si+ and (CH3)3Si,
J. Am. Chem. Soc., 1984, 106, 273. [all data]
Szepes and Baer, 1984, 2
Szepes, L.; Baer, T.,
(CH3)3SiX tipusu vegyuletek vizsgalata fotoelectron-fotoion koincidenciaval,I. Meghatarozott belso energiaju hexametil-diszilan-ionok disszociaciojanak dinamikaja,
Magy. Kem. Foly., 1984, 90, 104. [all data]
Band, Davidson, et al., Commun. 1967
Band, S.J.; Davidson, I.M.T.; Lambert, C.A.; Stephenson, I.L.,
Bond dissociation energies and heats of formation of trimethylsilyl compounds,
Chem., Commun. 1967, 723. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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