Phosphorus monofluoride
- Formula: FP
- Molecular weight: 49.972165
- IUPAC Standard InChIKey: QUQSORXWLOUIIW-UHFFFAOYSA-N
- CAS Registry Number: 16027-92-2
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to FP+ (ion structure unspecified)
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.60 ± 0.01 | PE | Butcher, Dyke, et al., 1988 | LL |
≤11.4 ± 0.6 | EI | Torgerson and Westmore, 1975 | LLK |
9.74 ± 0.01 | PE | Dyke, Jonathan, et al., 1982 | Vertical value; LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Butcher, Dyke, et al., 1988
Butcher, V.; Dyke, J.M.; Lewis, A.E.; Morris, A.; Ridha, A.,
A study of the ground electronic states of the isoelectronic ions PF+ and NCl+ by vacuum ultraviolet photoelectron spectroscopy,
J. Chem. Soc. Faraday Trans. 2, 1988, 84, 299. [all data]
Torgerson and Westmore, 1975
Torgerson, D.F.; Westmore, J.B.,
Energetics of the ionization and fragmentation of phosphorus trifluoride by electron impact,
Can. J. Chem., 1975, 53, 933. [all data]
Dyke, Jonathan, et al., 1982
Dyke, J.M.; Jonathan, N.; Morris, A.,
Recent progress in the study of transient species with vacuum ultraviolet photoelectron spectroscopy,
Int. Rev. Phys. Chem., 1982, 2, 3. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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