Thiazyl trifluoride
- Formula: F3NS
- Molecular weight: 103.067
- IUPAC Standard InChI: InChI=1S/F3NS/c1-5(2,3)4
- IUPAC Standard InChIKey: UQUPGRNSXINWBS-UHFFFAOYSA-N
- CAS Registry Number: 15930-75-3
- Chemical structure:
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of vaporization
| ΔvapH (kcal/mol) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 5.52 | 199. | Dykyj, Svoboda, et al., 1999 | Based on data from 184. to 268. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.46 ± 0.03 | EI | Glemser, Muller, et al., 1968 | RDSH |
| 12.50 | PE | Cowan, Gleiter, et al., 1972 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FNS+ | 16.82 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2NS+ | 15.47 ± 0.04 | F | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2S+ | 15.70 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F3S+ | 13.46 ± 0.03 | N | EI | Glemser, Muller, et al., 1968 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Dykyj, Svoboda, et al., 1999
Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.L.; Hall, K.R.,
Vapor Pressure of Chemicals: Part A. Vapor Pressure and Antoine Constants for Hydrocarbons and Sulfur, Selenium, Tellurium and Hydrogen Containing Organic Compounds, Springer, Berlin, 1999, 373. [all data]
Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B.,
Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien,
Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]
Cowan, Gleiter, et al., 1972
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.,
The photoelectron spectra of NSCl, NSF NSF3,
Helv. Chim. Acta, 1972, 55, 2418. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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