Thiazyl trifluoride
- Formula: F3NS
- Molecular weight: 103.067
- IUPAC Standard InChI: InChI=1S/F3NS/c1-5(2,3)4
- IUPAC Standard InChIKey: UQUPGRNSXINWBS-UHFFFAOYSA-N
- CAS Registry Number: 15930-75-3
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, Vibrational and/or electronic energy levels, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 12.46 ± 0.03 | EI | Glemser, Muller, et al., 1968 | RDSH |
| 12.50 | PE | Cowan, Gleiter, et al., 1972 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| FNS+ | 16.82 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2NS+ | 15.47 ± 0.04 | F | EI | Glemser, Muller, et al., 1968 | RDSH |
| F2S+ | 15.70 ± 0.05 | ? | EI | Glemser, Muller, et al., 1968 | RDSH |
| F3S+ | 13.46 ± 0.03 | N | EI | Glemser, Muller, et al., 1968 | RDSH |
Vibrational and/or electronic energy levels
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Takehiko Shimanouchi
Symmetry: C3ν Symmetry Number σ = 3
| Sym. | No | Approximate | Selected Freq. | Infrared | Raman | Comments | ||||
|---|---|---|---|---|---|---|---|---|---|---|
| Species | type of mode | Value | Rating | Value | Phase | Value | Phase | |||
| a1 | 1 | NS str | 1515 | B | 1515 | gas | 1512 p | liq. | ||
| a1 | 2 | NF3 s-str | 775 | B | 775 | gas | 768 p | liq. | ||
| a1 | 3 | NF3 s-deform | 521 | B | 521 | gas | 520 dp | liq. | ||
| e | 4 | NF3 d-str | 811 | B | 811 | gas | 812 dp | liq. | ||
| e | 5 | NF3 d-deform | 429 | B | 429 | gas | 430 dp | liq. | ||
| e | 6 | NF3 rock | 342 | B | 342 | gas | 340 dp | liq. | ||
Source: Shimanouchi, 1972
Notes
| p | Polarized |
| dp | Depolarized |
| B | 1~3 cm-1 uncertainty |
References
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Glemser, Muller, et al., 1968
Glemser, O.; Muller, A.; Bohler, D.; Krebs, B.,
Die N-S-Bindung: Bindungslangen Kraftkonstanten, Bindungsgrade und Bindungsenergien,
Z. Anorg. Allgem. Chem., 1968, 357, 184. [all data]
Cowan, Gleiter, et al., 1972
Cowan, D.O.; Gleiter, R.; Glemser, O.; Heilbronner, E.,
The photoelectron spectra of NSCl, NSF NSF3,
Helv. Chim. Acta, 1972, 55, 2418. [all data]
Shimanouchi, 1972
Shimanouchi, T.,
Tables of Molecular Vibrational Frequencies Consolidated Volume II,
J. Phys. Chem. Ref. Data, 1972, 6, 3, 993-1102. [all data]
Notes
Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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