Osmium, dodecacarbonyltri-, triangulo
- Formula: C12O12Os3
- Molecular weight: 906.81
- IUPAC Standard InChI: InChI=1S/12CO.3Os/c12*1-2;;;
- IUPAC Standard InChIKey: VUBLMKVEIPBYME-UHFFFAOYSA-N
- CAS Registry Number: 15696-40-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Dodecacarbonyl-triangulo-triosmium; Dodecacarbonyltriosmium; Osmium carbonyl (Os3(CO)12); Osmium dodecacarbonyl; Triosmium dodecacarbonyl; Os3(CO)12; Osmium carbonyl; Triangulo-dodecacarbonyltriosmium
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.8 | PE | Sherwood and Hall, 1982 | LBLHLM |
| 7.83 | PE | Green, Mingos, et al., 1981 | Vertical value; LLK |
| 7.83 | PE | Mingos, 1980 | Vertical value; LLK |
| 7.83 | PE | Green, Mingos, et al., 1980 | Vertical value; LLK |
| 7.8 ± 0.2 | PE | Green, Seddon, et al., 1979 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sherwood and Hall, 1982
Sherwood, D.E., Jr.; Hall, M.B.,
Electronic structure of metal clusters. 2. Photoelectron spectrum and molecular orbital calculations of decacarbonyldihydridotriosmium,
Inorg. Chem., 1982, 21, 3458. [all data]
Green, Mingos, et al., 1981
Green, J.C.; Mingos, D.M.P.; Seddon, E.A.,
Ultraviolet photoelectron studies on bonding in some metal carbonyl and metal hydrido carbonyl clusters,
Inorg. Chem., 1981, 20, 2595. [all data]
Mingos, 1980
Mingos, D.M.P.,
Theoretical structural studies on organometallic cluster molecules,
Pure Appl. Chem., 1980, 52, 705. [all data]
Green, Mingos, et al., 1980
Green, J.C.; Mingos, D.M.P.; Seddon, E.A.,
UV photoelectron spectral studies of carbonylhydrido-clusters and the development of a topological bonding model,
J. Organomet. Chem., 1980, 185, 20. [all data]
Green, Seddon, et al., 1979
Green, J.C.; Seddon, E.A.; Mingos, D.M.P.,
U.V. photoelectron spectral studies on the metal carbonyl cluster compounds Os3(CO)12, Ru3(CO)12, and Os6(CO)18,
J. Chem. Soc., Chem. Commun., 1979, 94. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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