Vanadium,tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-o,o')-,(oc-6-11)-
- Formula: C15H3F18O6V
- Molecular weight: 672.0935
- CAS Registry Number: 15695-77-9
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
Electron affinity determinations
| EA (eV) | Method | Reference | Comment |
|---|---|---|---|
| 3.166 ± 0.087 | IMRE | Sharpe, Eyler, et al., 1990 | EA given is actually -ΔGea(350 K); B |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.68 | PE | Evans, Hamnett, et al., 1972 | Vertical value; LLK |
| 8.68 ± 0.07 | PE | Evans, Hamnett, et al., 1972, 2 | Vertical value; LLK |
References
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Sharpe, Eyler, et al., 1990
Sharpe, P.; Eyler, J.R.; Richardson, D.E.,
Free Energies of Electron Attachment to Tris(acetylacetonate) and Tris(hexafluoroacetylacetonate) Transition-Metal Complexes in the Gas Phase: Experimental Results and Ligand Field Analysis,
Inorg. Chem., 1990, 29, 15, 2779, https://doi.org/10.1021/ic00340a014
. [all data]
Evans, Hamnett, et al., 1972
Evans, S.; Hamnett, A.; Orchard, A.F.,
The relative orbital energies of metal ligand electrons in some tris(hexafluoroacetylacetonato) transition-metal complexes,
J. Coord. Chem., 1972, 2, 57. [all data]
Evans, Hamnett, et al., 1972, 2
Evans, S.; Hamnett, A.; Orchard, A.F.; Lloyd, D.R.,
Study of the metal-oxygen bond in simple tris-chelate complexes by He(I) photoelectron spectroscopy,
Faraday Discuss. Chem. Soc., 1972, 54, 227. [all data]
Notes
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- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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