μ3-Methylidyne-tricobalt nonacarbonyl
- Formula: C10HCo3O9
- Molecular weight: 441.9091
- IUPAC Standard InChI: InChI=1S/9CO.CH.3Co/c9*1-2;;;;/h;;;;;;;;;1H;;;
- IUPAC Standard InChIKey: PMIYOQAEJHXEME-UHFFFAOYSA-N
- CAS Registry Number: 15664-75-2
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 7.9 | PE | Granozzi, Tondello, et al., 1982 | LBLHLM |
| 7.5 | PE | Costa, Lloyd, et al., 1982 | LBLHLM |
| 7.8 | PE | Chesky and Hall, 1981 | LLK |
| 8.75 | PE | Granozzi, Tondello, et al., 1982 | Vertical value; LBLHLM |
| 8.12 ± 0.09 | PE | Costa, Lloyd, et al., 1982 | Vertical value; LBLHLM |
| 8.8 | PE | Chesky and Hall, 1981 | Vertical value; LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Granozzi, Tondello, et al., 1982
Granozzi, G.; Tondello, E.; Ajo, D.; Casarin, M.; Aime, S.; Osella, D.,
Gas phase helium I photoelectron spectra of methinyltricobalt enneacarbonyl clusters,
Inorg. Chem., 1982, 21, 1081. [all data]
Costa, Lloyd, et al., 1982
Costa, N.C.V.; Lloyd, D.R.; Brint, P.; Pelin, W.K.; Spalding, T.R.,
The photoelectron spectra of enneacarbonyl-η3-methylidyne- tricobalt and some derivatives,
J. Chem. Soc. Dalton Trans., 1982, 201. [all data]
Chesky and Hall, 1981
Chesky, P.T.; Hall, M.B.,
Electronic structure of metal clusters. 1. Photoelectron spectra and molecular orbital calculations on (alkylidyne)tricobalt nonacarbonyl clusters,
Inorg. Chem., 1981, 20, 4419. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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