1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro-

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference
12.8273. to 300.THaber and Uenishi, 1958

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
11.59 ± 0.03EIClare and Sowerby, 1981LLK
11.4PENoodleman, Westwood, et al., 1978LLK
11.64 ± 0.05EIBrion, Oldfield, et al., 1966RDSH
11.4 ± 0.1PEBranton, Brion, et al., 1970Vertical value; RDSH

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
F5N3P3+16.23FEIClare and Sowerby, 1981LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Haber and Uenishi, 1958
Haber, C.; Uenishi, R., Some Physical Properties of the Trimeric and Tetrameric Phosphonitrilic Fluorides., Ind. Eng. Chem. Chem. Eng. Data Series, 1958, 3, 2, 323-324, https://doi.org/10.1021/i460004a031 . [all data]

Clare and Sowerby, 1981
Clare, P.; Sowerby, D.B., Electron impact ionisation energies of some halo-cyclotriphosphazenes, J. Inorg. Nucl. Chem., 1981, 43, 477. [all data]

Noodleman, Westwood, et al., 1978
Noodleman, L.; Westwood, N.P.C.; Mitchell, K.A.R., Ionization energies and electronic structure of N3P3Cl6 as determined by UV photoelectron and spectroscopy the Xα scattered wave method, Chem. Phys. Lett., 1978, 58, 252. [all data]

Brion, Oldfield, et al., 1966
Brion, C.E.; Oldfield, D.J.; Paddock, N.L., Huckel type interactions in phosphonitrilic derivatives, Chem. Commun., 1966, 226. [all data]

Branton, Brion, et al., 1970
Branton, G.R.; Brion, C.E.; Frost, D.C.; Mitchell, K.A.R.; Paddock, N.L., Phosphonitrilic derivatives. Part XVIII.lonisation potentials, orbital symmetry, and π-electron interactions, J. Chem. Soc., 1970, (A), 151. [all data]


Notes

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