1,3,5,2,4,6-Triazatriphosphorine,2,2,4,4,6,6-hexafluoro-2,2,4,4,6,6,-hexahydro-
- Formula: F6N3P3
- Molecular weight: 248.9318
- IUPAC Standard InChI: InChI=1S/F6N3P3/c1-10(2)7-11(3,4)9-12(5,6)8-10
- IUPAC Standard InChIKey: DKQPXAWBVGCNHG-UHFFFAOYSA-N
- CAS Registry Number: 15599-91-4
- Chemical structure:
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Gas phase ion energetics data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 11.59 ± 0.03 | EI | Clare and Sowerby, 1981 | LLK |
| 11.4 | PE | Noodleman, Westwood, et al., 1978 | LLK |
| 11.64 ± 0.05 | EI | Brion, Oldfield, et al., 1966 | RDSH |
| 11.4 ± 0.1 | PE | Branton, Brion, et al., 1970 | Vertical value; RDSH |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| F5N3P3+ | 16.23 | F | EI | Clare and Sowerby, 1981 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Clare and Sowerby, 1981
Clare, P.; Sowerby, D.B.,
Electron impact ionisation energies of some halo-cyclotriphosphazenes,
J. Inorg. Nucl. Chem., 1981, 43, 477. [all data]
Noodleman, Westwood, et al., 1978
Noodleman, L.; Westwood, N.P.C.; Mitchell, K.A.R.,
Ionization energies and electronic structure of N3P3Cl6 as determined by UV photoelectron and spectroscopy the Xα scattered wave method,
Chem. Phys. Lett., 1978, 58, 252. [all data]
Brion, Oldfield, et al., 1966
Brion, C.E.; Oldfield, D.J.; Paddock, N.L.,
Huckel type interactions in phosphonitrilic derivatives,
Chem. Commun., 1966, 226. [all data]
Branton, Brion, et al., 1970
Branton, G.R.; Brion, C.E.; Frost, D.C.; Mitchell, K.A.R.; Paddock, N.L.,
Phosphonitrilic derivatives. Part XVIII.lonisation potentials, orbital symmetry, and π-electron interactions,
J. Chem. Soc., 1970, (A), 151. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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