Tungsten, pentacarbonyl(triphenylphosphine)-, (OC-6-22)-

• Formula: C₂₃H₁₅O₅PW
• Molecular weight: 586.18
• IUPAC Standard InChI: InChI=1S/C18H15P.5CO.W/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;5*1-2;/h1-15H;;;;;; Copy

  
• IUPAC Standard InChIKey: LCHJMKIEZQLWKI-UHFFFAOYSA-N Copy
• CAS Registry Number: 15444-65-2
• Chemical structure:
  This structure is also available as a 2d Mol file
• Other names: Tungsten, pentacarbonyl(triphenylphosphine)-
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• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Mass spectrum (electron ionization)
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Gas phase ion energetics data

Go To: Top, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

Appearance energy determinations

References

Go To: Top, Phase change data, Gas phase ion energetics data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Al-Takhin, Connor, et al., 1984
Al-Takhin, G.; Connor, J.A.; Pilcher, G.; Skinner, H.A., J. Organomet. Chem., 1984, 265, 263. [all data]

Paetzold and Abd-el-Mottaleb, 1975
Paetzold, R.; Abd-el-Mottaleb, S., Correlative studies of some spectroscopic and bonding parameters in octahedrally coordinated metal carbonyl complexes, J. Mol. Struct., 1975, 24, 357. [all data]

Daamen, Oskam, et al., 1980
Daamen, H.; Oskam, A.; Stufkens, D.J., U.V. photoelectron (He I and He II) studies of M(CO)₅PR₃ (M = Cr, W and R = C₆H₁₁, C₆H₅, O-i-C₃H₇, OC₆H₅) and W(CO)₅As(C₆H₅)₃, Inorg. Chim. Acta, 1980, 38, 71. [all data]

Torroni, Innorta, et al., 1974
Torroni, S.; Innorta, G.; Foffani, A.; Distefano, G., Interpretation of the mass spectra of substituted chromium and tungsten carbonyls by means of appearance potential measurements, J. Organomet. Chem., 1974, 65, 209. [all data]

Notes

Go To: Top, Phase change data, Gas phase ion energetics data, References

• Symbols used in this document:
  

  AE	Appearance energy
  ΔsubH°	Enthalpy of sublimation at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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