chlorotrimethylgermane


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δvap8.01kcal/molRSCBaldwin, Lappert, et al., 1972MS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
8.68308.N/ADitsent, Skorokhodov, et al., 1972Based on data from 293. to 363. K.; AC
8.22307.SGGriffiths and Onyszchuk, 1961Based on data from 273. to 341. K.; AC

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
~10.1PEDrake, Glavincevski, et al., 1979 
9.62 ± 0.04EITamas, Czira, et al., 1972 
~10.5PEDrake, Glavincevski, et al., 1979Vertical value
10.35PEFlamini, Semprini, et al., 1976Vertical value

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C2H6ClGe+10.44 ± 0.04CH3EITamas, Czira, et al., 1972 
C3H9Ge+11.75 ± 0.04ClEITamas, Czira, et al., 1972 

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Baldwin, Lappert, et al., 1972
Baldwin, J.C.; Lappert, M.F.; Pedley, J.B.; Poland, J.S., J. Chem. Soc., Dalton Trans., 1972, 1943.. [all data]

Ditsent, Skorokhodov, et al., 1972
Ditsent, V.E.; Skorokhodov, I.I.; Terent'eva, N.A.; Zolotareva, M.N., Zh. Fiz. Khim., 1972, 46, 7, 1888. [all data]

Griffiths and Onyszchuk, 1961
Griffiths, J.E.; Onyszchuk, M., ORGANOGERMANIUM COMPOUNDS: PART I. THE INTERACTION OF HEXAMETHYLDIGERMOXANE AND TRIMETHYLMETHOXYGERMANE WITH BORON TRIFLUORIDE, Can. J. Chem., 1961, 39, 2, 339-347, https://doi.org/10.1139/v61-040 . [all data]

Drake, Glavincevski, et al., 1979
Drake, J.E.; Glavincevski, B.M.; Gorzelska, K., The photoelectron spectra of trimethylgermane, chloro- and fluoro-trimethylgermane, J. Electron Spectrosc. Relat. Phenom., 1979, 16, 331. [all data]

Tamas, Czira, et al., 1972
Tamas, J.; Czira, G.; Maltsev, A.K.; Nefedov, O.M., Electron impact studies on some organochlorogermanes: mass spectra and bond dissociation energies, J. Organomet. Chem., 1972, 40, 311. [all data]

Flamini, Semprini, et al., 1976
Flamini, A.; Semprini, E.; Stefani, F.; Sorriso, S.; Cardaci, G., He(I) photoelectron spectra and semiempirical molecular-orbital calculations on methylmetal halides of group 4A elements, J. Chem. Soc. Dalton Trans., 1976, 731. [all data]


Notes

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